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Part 420

Henley's Twentieth Century Formulas, Recipes and Processes · Gardner Dexter Hiscox — chapter 420 of 563 · ~830 words · public domain

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«Aluminum Bronze.»—I.—Strong solder: Gold, 89 parts; fine silver, 5 parts; copper, 6 parts.

II.—Medium solder: Gold, 54 parts; fine silver, 27 parts; copper, 19 parts.

III.—Weak solder: Gold, 14 parts; silver, 57 parts; copper, 15 parts; brass, 14 parts.

«BRASS SOLDERS.»

Brass solder consists of brass fusible at a low temperature, and is made by melting together copper and zinc, the latter being in excess. A small quantity of tin is often added to render the solder more fusible. Hard solders are usually sold in the form of granules. Although many workers in metals make their own solder, it is advisable to use hard solder made in factories, as complete uniformity of quality is more easily secured where large quantities are manufactured.

In making hard solder the melted metal is poured through birch twigs in order to granulate it. The granules are afterwards sorted by passing them through sieves.

When brass articles are soft-soldered, the white color of the solder contrasts unpleasantly with the brass. If this is objected to, the soldered part can be colored yellow in the following manner:

Dissolve 10 parts of copper sulphate in 35 parts of water; apply the solution to the solder, and stir with a clean iron wire. This gives the part the appearance of copper. To produce the yellow color, paint the part with a mixture consisting of 1 part of a solution of equal parts of zinc and water (1 part each) and 2 parts of a solution of 10 to 35 parts respectively of copper sulphate and water and rub on with a zinc rod. The resulting yellow color can, if desired, be improved by careful polishing.

The quality of soft solder is always judged in the trade from the appearance of the surface of the castings, and it is considered important that this surface should be radiant and crystalline, showing the so-called “flowers.” These should be more brilliant than the dull background, the latter being like mat silver in appearance. If the casting has a uniform whitish-gray color, this is an indication that the alloy contains an insufficient quantity of tin. In this case {658} the alloy should be remelted and tin added, solder too poor in tin being extremely viscid.

Most of the varieties of brass used in the arts are composed of from 68 to 70 per cent copper and from 32 to 30 per cent zinc. Furthermore, there are some kinds of brass which contain from 24 to 40 per cent zinc. The greater the quantity of zinc the greater will be the resemblance of the alloy to copper. Consequently, the more crystalline will the structure become. For hard soldering only alloys can be employed which, as a general rule, contain no more than 34 per cent of zinc. With an increase in copper there follows a rise in the melting point of the brass. An alloy containing 90 per cent of copper will melt at 1,940° F.; 80 per cent copper, at 1,868° F.; 70 per cent copper, at 1,796° F.; 60 per cent copper, at 1,742° F. Because an increase in zinc causes a change in color, it is sometimes advisable to use tin for zinc, at least in part, so that the alloy becomes more bronze-like in its properties. The durability of the solder is not seriously affected, but its fusibility is lowered. If more than a certain proportion of tin be added, thin and very fluid solders are obtained of grayish-white color, and very brittle—indeed, so brittle that the soldering joints are apt to open if the object is bent. Because too great an addition of tin is injurious, the utmost caution must be exercised. If very refractory metals are to be soldered, brass alone can be used. In some cases, a solder can be produced merely by melting brass and adding copper. The following hard solders have been practically tested and found of value.

«YELLOW HARD SOLDERS:»

Applebaum’s Compositions.—

I.—Copper 58 parts Zinc 42 parts

II.—Sheet brass 85.42 parts Zinc 13.58 parts

Karmarsch’s Composition.—

III.—Brass 7 parts Zinc 1 part

IV.—Zinc 49 parts Copper 44 parts Tin 4 parts Lead 2 parts

Prechtl’s Composition.—

V.—Copper 53.3 parts Zinc 43.1 parts Tin 1.3 parts Lead 0.3 parts

All these hard-solder compositions have the fine yellow color of brass, are very hard, and can be fused only at high temperatures. They are well adapted for all kinds of iron, steel, copper, and bronze.

Solders which fuse at somewhat lower temperatures and, therefore, well adapted for the working of brass, are the following:

VI.—Sheet brass 81.12 parts Zinc 18.88 parts

VII.—Copper 54.08 parts Zinc 45.29 parts

VIII.—Brass 3 to 4 parts Zinc 1 part

A solder which is valuable because it can be wrought with the hammer, rolled out, or drawn into wire, and because it is tough and ductile, is the following:

IX.—Brass 78.26 parts Zinc 17.41 parts Silver 4.33 parts

Fusible White Solder.—

X.—Copper 57.4 parts Zinc 28 parts Tin 14.6 parts

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