Part 408

«Preservatives for Shoe Soles.»—I.—This preparation, destined for impregnating leather shoe soles, is produced as follows: Grind 50 parts of linseed oil with 1 part of litharge; next heat for 2 hours to the boiling point with 1⁠/⁠4 part of zinc vitriol, which is previously calcined (dehydrated). The composition obtained in this manner, when perfectly cold, is mixed with 8 parts of benzine and filled in bottles or other receptacles. To render this preservative effective, the soles must be coated with it until the leather absorbs it.

II.—Dissolve ordinary household soap in water; on the other hand, dissolve an aluminum salt—the cheapest is the commercial aluminum sulphate—in water and allow both solutions to cool. Now pour the aluminum salt solution, with constant stirring, into the soap solution, thereby obtaining a very fine precipitate of aluminum oleate. The washed-out residue is dried with moderate heat. By adding 10 to 30 per cent to petroleum with slight heating, a solid petroleum of vaseline-like consistency is received, which may be still further solidified by additional admixture. A 10 per cent solution of aluminum oleate in petroleum is a very excellent agent for preserving the soles, a single saturation of the soles sufficing forever. The sole will last about 1 year.

III.—The following mixture is prepared by melting together over the fire in an enameled iron vessel: Vaseline, 400 parts; ceresine, 100 parts. The melted mass, which is used as a grease, is filled in wooden boxes or tin cans.

IV.—The oleic acid of the stearine factories is heated with strong alcohol and sulphuric acid. Take 16 parts of oleic acid, 2 parts of alcohol (90 per cent), and 1 part of concentrated sulphuric acid. The oleic-acid ether formed separates as a thin brownish oil. It is liberated from free sulphuric acid and the alcohol in excess by agitation with warm water and allowing to settle. This oleic-acid ether is mixed with the same weight of fish oil, and 4 to 8 parts of nitro-benzol are added per 1,000 parts to disguise the odor.

«TAN AND RUSSET SHOE POLISHES:»

«To Renovate and Brighten Russet and Yellow Shoes.»—First, clean off all dirt and dust with a good stiff brush, then with a sponge dipped in benzine go over the leather, repeating the process as soon as the benzine evaporates. A few wipings will bring back the original color. Then use a light-yellow dressing and brush well.

The liquid application consists usually of a solution of yellow wax and soap in oil of turpentine, and it should be a matter of no difficulty whatever to compound a mixture of this character at least equal {634} to the preparations on the market. As a type of the mixture occasionally recommended we may quote the following:

I.—Yellow wax 4 ounces Pearl ash 4 drachms Yellow soap 1 drachm Spirit of turpentine 7 ounces Phosphine (aniline) 4 grains Alcohol 4 drachms Water, a sufficient quantity.

Scrape the wax fine and add it, together with the ash and soap, to 12 ounces of water. Boil all together until a smooth, creamy mass is obtained; remove the heat and add the turpentine and the aniline (previously dissolved in the alcohol). Mix thoroughly, and add sufficient water to bring the finished product up to 1 1⁠/⁠2 pints.

II.—Water 18 parts Rosin oil 4 1⁠/⁠2 parts Spirit of sal ammoniac, concentrated 1 1⁠/⁠5 parts White grain soap 1.93 parts Russian glue 1.59 parts Brown rock candy 0.57 parts Bismarck brown 0.07 parts

Boil all the ingredients together, excepting the pigment; after all has been dissolved, add the Bismarck brown and filter. The dressing is applied with a sponge.

III.—Beeswax, yellow 2 ounces Linseed oil 3 ounces Oil turpentine 10 ounces

Dissolve by heat of a water bath, and add 1 1⁠/⁠4 ounces soap shavings, hard yellow. Dissolve this in 14 ounces of hot water.

IV.—A simpler form of liquid mixture consists of equal parts of yellow wax and palm oil dissolved with the aid of heat in 3 parts of oil of turpentine.

V.—Soft or green soap 1 ounce Linseed oil, raw 2 ounces Annatto solution (in oil) 7 ounces Yellow wax 2 ounces Gum turpentine 7 ounces Water 7 ounces

Dissolve the soap in the water and add the solution of annatto; melt the wax in the oil of turpentine, and gradually stir in the soap solution, stirring until cold.

The paste to accompany the foregoing mixtures is composed of yellow wax and rosin thinned with petrolatum, say 4 parts of wax, 1 part of rosin, and 12 parts of petrolatum.

«Paste Dressings for Russet Shoes.»—The paste dressings used on russet leather consist of mixtures of wax with oil and other vehicles which give a mixture of proper working quality.

A simple formula is:

I.—Yellow wax 9 parts Oil of turpentine 20 parts Soap 1 part Boiling water 20 parts

Dissolve the wax in the turpentine on a water bath and the soap in the water and stir the two liquids together until the mixture becomes sufficiently cold to remain homogeneous.

Another formula in which stearine is used is appended:

II.—Wax 1 part Stearine 2 parts Linseed oil 1 part Oil of turpentine 6 parts Soap 1 part Water 10 parts

Proceed as above.

Carnauba wax is often used by manufacturers of such dressings instead of beeswax, as it is harder and takes a higher polish. These dressings are sometimes colored with finely ground yellow ocher or burnt umber. If the leather be badly worn, however, it is best to apply a stain first, and afterwards the waxy dressing.

Suitable stains are made by boiling safflower in water, and annatto is also used in the same way, the two being sometimes mixed together. Oxalic acid darkens the color of the safflower. Aniline colors would also doubtless yield good results with less trouble and expense. By adding finely ground lampblack to the waxy mixture instead of ocher, it would answer as a dressing for black leather.

«WATERPROOF SHOE DRESSINGS.»

I.—Caoutchouc 10 parts Petroleum 10 parts Carbon disulphide 10 parts Shellac 40 parts Lampblack 20 parts Oil lavender 1 part Alcohol 200 parts