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Part 13

Experiments and Considerations Touching Colours (1664) · Robert Boyle — chapter 13 of 23 · ~4,207 words · public domain

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But this brings into my mind, that having sometimes for Curiosity sake, brought a round Vial with a long Neck fill'd with the Tincture of Lignum Nephriticum into the Darken'd Room already often mention'd, and holding it sometimes in, sometimes near the Sun-beams that enter'd at the hole, and sometimes partly in them, and partly out of them, the Glass being held in several postures, and look'd upon from several Neighbouring parts of the Room, disclos'd a much greater Variety of Colours than in ordinary inlightn'd Rooms it is wont to do; exhibiting, besides the usual Colours, a Red in some parts, and a Green in others, besides Intermediate Colours produc'd by the differing Degrees, and odd mixtures of Light and Shade.

By all this You may see, Pyrophilus, the reasonableness of what we elsewhere had occasion to mention, when we have divers times told you, that it is usefull to have New Experiments try'd over again, though they were, at first, made by Knowing and Candid Men, such Reiterations of Experiments commonly exhibiting some New Phænomena, detecting some Mistake or hinting some Truth, in reference to them, that was not formerly taken notice of. And some of our friends have been pleas'd to think, that we have made no unusefull addition to this Experiment, by shewing a way, how in a moment our Liquor may be depriv'd of its Blewness, and restor'd to it again by the affusion of a very few drops of Liquors, which have neither of them any Colour at all of their own. And that which deserves some particular wonder, is, that the Cæruleous Tincture of our Wood is subject by the former Method to be Destroy'd or Restor'd, the Yellowish or Reddish Tincture continuing what it was. And that you may see, that Salts are of a considerable use in the striking of Colours, let me add to the many Experiments which may be afforded us to this purpose by the Dyers Trade, this Observation; That as far as we have hitherto try'd, those Liquors in general that are strong of Acid Salts have the Power of Destroying the Blewness of the Infusion of our Wood, and those Liquors indiscriminatly that abound with Sulphureous Salts, (under which I comprehend the Urinous and Volatile Salts of Animal Substances, and the Alcalisate or fixed Salts that are made by Incineration) have the vertue of Restoring it.

A Corollary of the Tenth Experiment.

That this Experiment, Pyrophilus, may be as well Usefull as Delightfull to You, I must mind You, Pyrophilus, that in the newly mention'd Observation, I have hinted to You a New and Easie way of Discovering in many Liquors (for I dare not say in all) whether it be an Acid or Sulphureous Salt, that is Predominant; and that such a Discovery is oftentimes of great Difficulty, and may frequently be of great Use, he that is not a Stranger to the various Properties and Effects of Salts, and of how great moment it is to be able to distinguish their Tribes, may readily conceive. But to proceed to the way of trying other Liquors by an Infusion of our Wood, take it briefly thus. Suppose I have a mind to try whether I conjecture aright, when I imagine that Allom, though it be plainly a Mixt Body, does abound rather with Acid than Sulphureous Salt. To satisfie my self herein, I turn my back to the Light, and holding a small Vial full of the Tincture of Lignum Nephriticum, which look'd upon in that Position, appears Cæruleous, I drop into it a little of a strong Solution of Allom made in Fair Water, and finding upon the Affusion and shaking of this New liquor, that the Blewness formerly conspicuous in our Tincture does presently vanish, I am thereby incited to suppose, that the Salt Prædominant in Allom belongs to the Family of Sour Salts; but if on the other side I have a mind to examine whether or no I rightly conceive that Salt of Urine, or of Harts-horn is rather of a Saline Sulphureous (if I may so speak) than of an Acid Nature, I drop a little of the Saline Spirit of either into the Nephritick Tincture, and finding that the Cæruleous Colour is rather thereby Deepned than Destroy'd, I collect that the Salts, which constitute these Spirits, are rather Sulphureous than Acid. And to satisfie my self yet farther in this particular, I take a small Vial of fresh Tincture, and placing both it and my self in reference to the Light as formerly, I drop into the Infusion just as much Distill'd Vinegar, or other Acid liquor as will serve to Deprive it of its Blewness (which a few drops, if the Sour Liquor be strong, and the Vial small will suffice to do) then without changing my Posture, I drop and shake into the same Vial a small proportion of Spirit of Hartshorn or Urine, and finding that upon this affusion, the Tincture immediately recovers its Cæruleous Colour, I am thereby confirm'd firm'd in my former Opinion, of the Sulphureous Nature of these Salts. And so, whereas it is much doubted by Some Modern Chymists to what sort of Salt, that which is Prædominant in Quick-lime belongs, we have been perswaded to referr it rather to Lixiviate than Acid Salts, by having observ'd, that though an Evaporated Infusion of it will scarce yield such a Salt, as Ashes and other Alcalizate Bodyes are wont to do, yet if we deprive our Nephritick Tincture of its Blewness by just so much Distill'd Vinegar as is requisite to make that Colour Vanish, the Lixivium of Quick-lime will immediately upon its Affusion recall the Banished Colour; but not so Powerfully as either of the Sulphureous Liquors formerly mention'd. And therefore I allow my self to guess at the Strength of the Liquors examin'd by this Experiment, by the Quantity of them which is sufficient to Destroy or Restore the Cæruleous Colour of our Tincture. But whether concerning Liquors, wherein neither Acid nor Alcalisate Salts are Eminently Prædominant, our Tincture will enable us to conjecture any thing more than that such Salts are not Prædominant in them, I take not upon me to determine here, but leave to further Tryal; For I find not that Spirit of Wine, Spirit of Tartar freed from Acidity, or Chymical Oyl of Turpentine, (although Liquors which must be conceiv'd very Saline, if Chymists have, which is here no place to Dispute, rightly ascrib'd tasts to the Saline Principle of Bodyes,) have any Remarkable Power either to deprive our Tincture of its Cæruleous Colour, or restore it, when upon the Affusion of Spirit of Vinegar it has disappear'd.

EXPERIMENT XI.

And here I must not omit, Pyrophilus, to inform You, that we can shew You even in a Mineral Body something that may seem very near of Kin to the Changeable Quality of the Tincture of Lignum Nephriticum, for we have several flat pieces of Glass, of the thickness of ordinary Panes for Windows one of which being interposed betwixt the Eye and a clear Light, appears of a Golden Colour, not much unlike that of the moderate Tincture of our Wood, but being so look'd upon as that the Beams of light are not so much Trajected thorough it as Reflected from it to the Eye, that Yellow seems to degenerate into a pale Blew, somewhat like that of a Turquoise. And what which may also appear strange, is this, that if in a certain posture you hold one of these Plates Perpendicular to the Horizon, so that the Sun-beams shine upon half of it, the other half being Shaded, You may see that the part Shin'd upon will be of a much Diluter Yellow than the Shaded part which will appear much more Richly Colour'd; and if You alter the Posture of the Glass, so that it be not held Perpendicular, but Parallel in reference to the Horizon, You may see, (which perhaps you will admire) the Shaded part look of a Golden Colour, but the other that the Sun shines freely on, will appear considerably Blew, and as you remove any part of the Glass thus held Horizontally into the Sun-beams or Shade, it will in the twinkling of an Eye seem to pass from one of the above mention'd Colours to the other, the Sun-beams Trajected through it upon a sheet of White Paper held near it, do colour it with a Yellow, somewhat bordering upon a Red, but yet the Glass may be so oppos'd to the Sun, that it may upon Paper project a mix'd Colour here and there more inclin'd to Yellow, and here and there more to Blew. The other Phænomena of this odd Glass, I fear it would be scarce worth while to Record, and therefore I shall rather advertise You, First that in the trying of these Experiments with it, you must take notice that one of the sides has either alone, or at least principally its Superficial parts dispos'd to the Reflection of the Blew Colour above nam'd, and that therefore you must have a care to keep that side nearest to the Eye. And next, that we have our selves made Glasses not unfit to exhibit an Experiment not unlike that I have been speaking of, by laying upon pieces of Glass some very finely foliated Silver, and giving it by degrees a much stronger Fire than is requisite or usual for the Tinging of Glasses of other Colours. And this Experiment, not to mention that it was made without a Furnace in which Artificers that Paint Glass are wont to be very Curious, is the more considerable, because, that though a Skilfull Painter could not deny to me that 'twas with Silver he Colour'd his Glasses Yellow; yet he told me, that when to Burn them (as they speak) he layes on the plates of Glass nothing but a Calx of Silver Calcin'd without Corrosive Liquors, and Temper'd with Fair Water, the Plates are Ting'd of a fine Yellow that looks of a Golden Colour, which part soever of it you turn to or from the Light; whereas (whether it be what an Artificer would call Over-doing, or Burning, or else the imploying the Silver Crude that makes the Difference,) we have found more than once, that some Pieces of Glass prepar'd as we have related, though held against the Light they appear'd of a Transparent Yellow, yet look'd on with ones back turn'd to the Light they exhibited an Untransparent Blew.

EXPERIMENT XII.

If you will allow me, Pyrophilus, for the avoiding of Ambiguity, to imploy the Word Pigments, to signifie such prepared materials (as Cochinele, Vermilion, Orpiment,) as Painters, Dyers and other Artificers make use of to impart or imitate particular Colours, I shall be the better understood in divers passages of the following papers, and particularly when I tell you, That the mixing of Pigments being no inconsiderable part of the Painters Art, it may seem an Incroachment in me to meddle with it. But I think I may easily be excus'd (though I do not altogether pass it by) if I restrain my self to the making of a Transient mention of some few of their Practices about this matter; and that only so far forth, as may warrant me to observe to you, that there are but few Simple and Primary Colours (if I may so call them) from whose Various Compositions all the rest do as it were Result. For though Painters can imitate the Hues (though not always the Splendor) of those almost Numberless differing Colours that are to be met with in the Works of Nature, and of Art, I have not yet found, that to exhibit this strange Variety they need imploy any more than White, and Black, and Red, and Blew, and Yellow; these five, Variously Compounded, and (if I may so speak) Decompounded, being sufficient to exhibit a Variety and Number of Colours, such, as those that are altogether Strangers to the Painters Pallets, can hardly imagine.

Thus (for Instance) Black and White differingly mix'd, make a Vast company of Lighter and Darker Grays.

Blew and Yellow make a huge Variety of Greens.

Red and Yellow make Orange Tawny.

Red with a little White makes a Carnation.

Red with an Eye of Blew, makes a Purple; and by these simple Compositions again Compounded among themselves, the Skilfull Painter can produce what kind of Colour he pleases, and a great many more than we have yet Names for. But, as I intimated above, 'tis not my Design to prosecute this Subject, though I thought it not unfit to take some Notice of it, because we may hereafter have occasion to make use of what has been now deliver'd, to illustrate the Generation of Intermediate Colours; concerning which we must yet subjoyn this Caution, that to make the Rules about the Emergency of Colours, fit to be Relied upon, the Corpuscles whereof the Pigments consist must be such as do not Destroy one anothers Texture, for in case they do, the produced Colour may be very Different from that which would Result from the Mixture of other harmless Pigments of the same Colours, as I shall have Occasion to shew ere long.

EXPERIMENT XIII.

It may also give much light to an Enquirer into the Nature of Colours, to know that not only in Green, but in many (if not all) other Colours, the Light of the Sun passing through Diaphanous Bodies of differing Hues may be tinged of the same Compound Colour, as if it came from some Painters Colours of the same Denomination, though this later be exhibited by Reflection, and be (as the former Experiment declares) manifestly Compounded of material Pigments. Wherefore to try the Composition of Colours by Trajection, we provided several Plates of Tinged Glass, which being laid two at a time one on the top of another, the Object look'd upon through them both, appear'd of a Compounded Colour, which agrees well with what we have observ'd in the second Experiment, of Looking against the Light through differingly Colour'd Papers. But we thought the Experiment would be more Satisfactory, if we procur'd the Sun-beams to be so Ting'd in their passage through Plates of Glass, as to exhibit the Compounded Colour upon a Sheet of White Paper. And though by reason of the Thickness of the Glasses, the Effect was but Faint, even when the Sun was High and Shin'd forth clear, yet, we easily remedied that by Contracting the Beams we cast on them by means of a Convex Burning-glass, which where it made the Beams much converge Increas'd the Light enough to make the Compounded Colour very manifest upon the Paper. By this means we observ'd, that the Beams trajected through Blew and Yellow compos'd a Green, that an intense and moderate Red did with Yellow make differing degrees of Saffron, and Orange Tawny Colours, that Green and Blew made a Colour partaking of both, such as that which some Latin Writers call Pavonaceus, that Red and Blew made a Purple, to which we might add other Colours, that we produc'd by the Combinations of Glasses differingly Ting'd, but that I want proper Words to express them in our Language, and had not when we made the Tryals, the Opportunity of consulting with a Painter, who perchance might have Suppli'd me with some of the terms I wanted.

I know not whether it will be requisite to subjoyn on this Occasion, what I tried concerning Reflections from Colour'd Glasses, and other Transparent Bodies, namely, that having expos'd four or five sorts of them to the Sun, and cast the Reflected Beams upon White Paper held near at hand, the Light appear'd not manifestly Ting'd, but as if it had been Reflected from the Impervious parts of a Colourless Glass, only that Reflected from the Yellow was here and there stain'd with the same Colour, as if those Beams were not all Reflected from the Superficial, but some from the Internal parts of the Glass; upon which Occasion you may take notice, that a Skilfull Tradesman, who makes such Colour'd Glass told me, that where as the Red Pigment was but Superficial, the Yellow penetrated to the very midst of the Plate. But for further Satisfaction, not having the Opportunity to Foliate those Plates, and so turn them into Looking-glasses, we Foliated a Plate of Muscovy Glass, and then laying on it a little Transparent Varnish of a Gold Colour, we expos'd it to the Sun-beams, so as to cast them upon a Body fit to receive them, on which the Reflected Light, appearing, as we expected, Yellow, manifested that Rebounding from the Specular part of the Selenitis, it was Ting'd in its return with the Colour of the Transparent Varnish through which it pass'd.

EXPERIMENT XIV.

After what we have said of the Composition of Colours, it will now be seasonable to annex some Experiments that we made in favour of those Colours, that are taught in the Schools not to be Real, but only Apparent and Phantastical; For we found by Tryals, that these Colours might be Compounded, both with True and Stable Colours, and with one another, as well as unquestionably Genuine and Lasting Colours, and that the Colours resulting from such Compositions, would respectively deserve the same Denominations.

For first, having by the Trajection of the Sun-beams through a Glass-prism thrown an Iris on the Floor, I found that by placing a Blew Glass at a convenient distance betwixt the Prism and the Iris, that part of the Iris that was before Yellow, might be made to appear Green, though not of a Grass Green, but of one more Dilute and Yellowish. And it seems not improbable, that the narrow Greenish List (if I may so call it) that is wont to be seen between the Yellow and Blew parts of the Iris, is made by the Confusion of those two Bordering Colours.

Next, I found, that though the want of a sufficient Liveliness in either of the Compounding Colours, or a light Error in the manner of making the following Tryals, was enough to render some of them Unsuccessfull, yet when all necessary Circumstances were duely observ'd, the Event was answerable to our Expectation and Desire.

And (as I formerly Noted) that Red and Blew compound a Purple, so I could produce this last nam'd Colour, by casting at some Distance from the Glass the Blew part of the Prismatical Iris (as I think it may be call'd for Distinction sake) upon a Lively Red, (for else the Experiment succeeds not so well.) And I remember, that sometimes when I try'd this upon a piece of Red Cloath, that part of the Iris which would have been Blew, (as I try'd by covering that part of the Cloath with a piece of White Paper) and Compounded with the Red, wherewith the Cloath was Imbued before, appear'd of a fair Purple, did, when I came to View it near at hand, look very Odly, as if there were some strange Reflection or Refraction or both made in the Hairs of which that Cloath was composed.

Calling likewise the Prismatical Iris upon a very Vivid Blew, I found that part of it, which would else have been the Yellow, appear Green. (Another somewhat differing Tryal, and yet fit to confirm this, you will find in the fifteenth Experiment.)

But it may seem somewhat more strange, that though the Prismatical Iris being made by the Refraction of Light through a Body that has no Colour at all, must according to the Doctrine of the Schools consist of as purely Emphatical Colours, as may be, yet even these may be Compounded with one another, as well as Real Colours in the Grossest Pigments. For I took at once two Triangular Glasses, and one of them being kept fixt in the same Posture, that the Iris it projected on the Floor might not Waver, I cast on the same Floor another Iris with the other Prism, and Moving it too and fro to bring what part of the second Iris I pleas'd, to fall upon what part of the first I thought fit, we did sometimes (for a small Errour suffices to hinder the Success) obtain by this means a Green Colour in that part of the more Stable Iris, that before was Yellow, or Blew, and frequently by casting those Beams that in one of the Iris's made the Blew upon the Red parts of the other Iris, we were able to produce a lovely Purple, which we can Destroy or Recompose at pleasure, by Severing and Reapproaching the Edges of the two Iris's.

EXPERIMENT XV.

On this occasion, Pyrophilus, I shall add, that finding the Glass-prism to be the usefullest Instrument Men have yet imploy'd about the Contemplation of Colours, and considering that Prisms hitherto in use are made of Glass, Transparent and Colourless, I thought it would not be amiss to try, what change the Superinduction of a Colour, without the Destruction of the Diaphaneity, would produce in the Colours exhibited by the Prism. But being unable to procure one to be made of Colour'd Glass, and fearing also that if it were not carefully made, the Thickness of it would render it too Opacous, I endeavoured to substitute one made of Clarify'd Rosin, or of Turpentine brought (as I elsewhere teach) to the consistence of a Transparent Gum. But though these Endeavours were not wholly lost, yet we found it so difficult to give these Materials their true Shape, that we chose rather to Varnish over an ordinary Prism with some of these few Pigments that are to be had Transparent; as accordingly we did first with Yellow, and then with Red, or rather Crimson, made with Lake temper'd with a convenient Oyl, and the Event was, That for want of good Transparent Colours, (of which you know there are but very few) both the Yellow and the Red made the Glass so Opacous, (though the Pigment were laid on but upon two Sides of the Glass, no more being absolutely necessary) that unless I look'd upon an Inlightned Window, or the Flame of a Candle, or some other Luminous or very Vivid object, I could scarce discern any Colours at all, especially when the Glass was cover'd with Red. But when I did look on such Objects, it appear'd (as I expected) that the Colour of the Pigment had Vitiated or Drown'd some of those which the Prism would according to its wont have exhibited, and mingling with others, Alter'd them: as I remember, that both to my Eyes, and others to whom I show'd it, when the Prism was cover'd with Yellow, it made those Parts of bright Objects, where the Blew would else have been Conspicuous, appear of a light Green. But, Pyrophilus, both the Nature of the Colours, and the Degree of Transparency, or of Darkness in the Pigment, besides divers other Circumstances, did so vary the Phænomena of these Tryals, that till I can procure small Colour'd Prisms, or Hollow ones that may be filled with Tincted Liquor, or obtain Some better Pigments than those I was reduc'd to imploy, I shall forbear to Build any thing upon what has been delivered, and shall make no other use of it, than to invite you to prosecute the Inquiry further.

EXPERIMENT XVI.

And here, Pyrophilus, since we are treating of Emphatical Colours, we shall add what we think not unworthy your Observation, and not unfit to afford some Exercise to the Speculative. For there are some Liquors, which though Colourless themselves, when they come to be Elevated, and Dispers'd into Exhalations, exhibit a conspicuous Colour, which they lose again, when they come to be Reconjoyn'd into a Liquor, as good Spirit of Nitre; or upon its account strong Aqua-fortis, though devoid of all appearance of Redness whilst they continue in the form of a Liquor, if a little Heat chance to turn the Minute parts of them into Vapour, the Steam will appear of a Reddish or deep Yellow Colour, which will Vanish when those Exhalations come to resume the form of Liquor.

And not only if you look upon a Glass half full of Aqua-fortis, or Spirit of Nitre, and half full of Nitrous steams proceeding from it, you will see the Upper part of the Glass of the Colour freshly mention'd, if through it you look upon the Light. But which is much more considerable, I have tried, that putting Aqua-fortis in a long clear Glass, and adding a little Copper or some such open Metall to it, to excite Heat and Fumes, the Light trajected through those Fumes, and cast upon a sheet of White Paper, did upon that appear of the Colour that the Fumes did, when directly Look'd upon, as if the Light were as well Ting'd in its passage through these Fumes, as it would have been by passing through some Glass or Liquor in which the same Colour was Inherent.

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