Part 14

To which I shall further add, that having sometimes had the Curiosity to observe whether the Beams of the Sun near the Horizon trajected through a very Red Sky, would not (though such rednesses are taken to be but Emphatical Colours) exhibit the like Colour, I found that the Beams falling within a Room upon a very White Object, plac'd directly opposite to the Sun, disclos'd a manifest Redness, as if they had pass'd through a Colour'd Medium.

EXPERIMENT XVII.

The emergency, Pyrophilus, of Colours upon the Coalition of the Particles of such Bodies as were neither of them of the Colour of that Mixture whereof they are the Ingredients, is very well worth our attentive Observation, as being of good use both Speculative and Practical; For much of the Mechanical use of Colours among Painters and Dyers, doth depend upon the Knowledge of what Colours may be produc'd by the Mixtures of Pigments so and so Colour'd. And (as we lately intimated) 'tis of advantage to the contemplative Naturalist, to know how many and which Colours are Primitive (if I may so call them) and Simple, because it both eases his Labour by confining his most sollicitous Enquiry to a small Number of Colours upon which the rest depend, and assists him to judge of the nature of particular compounded Colours, by shewing him from the Mixture of what more Simple ones, and of what Proportions of them to one another, the particular Colour to be consider'd does result. But because to insist on the Proportions, the Manner and the Effects of such Mixtures would oblige me to consider a greater part of the Painters Art and Dyers Trade, than I am well acquainted with, I confin'd my self to make Trial of several ways to produce Green, by the composition of Blew and Yellow. And shall in this place both Recapitulate most of the things I have Dispersedly deliver'd already concerning that Subject, and Recruit them.

And first, whereas Painters (as I noted above) are wont to make Green by tempering Blew and Yellow, both of them made into a soft Consistence, with either Water or Oyl, or some Liquor of Kin to one of those two, according as the Picture is to be Drawn with those they call water Colours, or those they term Oyl Colours, I found that by choosing fit Ingredients, and mixing them in the form of Dry Powders, I could do, what I could not if the Ingredients were temper'd up with a Liquor; But the Blew and Yellow Powders must not only be finely Ground, but such as that the Corpuscles of the one may not be too unequal to those of the other, lest by their Disproportionate Minuteness the Smaller cover and hide the Greater. We us'd with good success a slight Mixture of the fine Powder of Bise, with that of Orpiment, or that of good Yellow Oker, I say a slight Mixture, because we found that an exquisite Mixture did not do so well, but by lightly mingling the two Pigments in several little Parcels, those of them in which the Proportion and Manner of Mixture was more Lucky, afforded us a good Green.

2. We also learn'd in the Dye-houses, that Cloth being Dy'd Blew with Woad, is afterwards by the Yellow Decoction of Luteola or Woud-wax or Wood-wax Dy'd into a Green Colour.

3. You may also remember what we above Related, where we intimated, that having in a Darkn'd Room taken two Bodies, a Blew and a Yellow, and cast the Light Reflected from the one upon the other, we likewise obtain'd a Green.

4. And you may remember, that we observ'd a Green to be produc'd, when in the same Darkn'd Room we look'd at the Hole at which alone the Light enter'd, through the Green and Yellow parts of a sheet of Marbl'd Paper laid over one another.

5. We found too, that the Beams of the Sun being trajected through two pieces of Glass, the one Blew and the other Yellow, laid over one another, did upon a sheet of White paper on which they were made to fall, exhibit a lovely Green.

6. I hope also, that you have not already forgot, what was so lately deliver'd, concerning the composition of a Green, with a Blew and Yellow; of which most Authors would call the one a Real, and the other an Emphatical.

7. And I presume, you may have yet fresh in your memory, what the fourteenth Experiment informs you, concerning the exhibiting of a Green, by the help of a Blew and Yellow, that were both of them Emphatical.

8. Wherefore we will proceed to take notice, that we also devis'd a way of trying whether or no Metalline Solutions though one of them at least had its Colour Adventitious, by the mixture of the Menstruum employ'd to dissolve it, might not be made to compound a Green after the manner of other Bodies. And though this seem'd not easie to be perform'd by reason of the Difficulty of finding Metalline Solutions of the Colour requisite, that would mix without Præcipitating each other; yet after a while having consider'd the matter, the first Tryal afforded me the following Experiment. I took a High Yellow Solution of good Gold in Aqua-Regis, (made of Aqua-fortis, and as I remember half its weight of Spirit of Salt) To this I put a due Proportion of a deep and lovely Blew Solution of Crude Copper, (which I have elsewhere taught to be readily Dissoluble in strong Spirit of Urine) and these two Liquors though at first they seem'd a little to Curdle one another, yet being throughly mingl'd by Shaking, they presently, as had been Conjectur'd, united into a Transparent Green Liquor, which continu'd so for divers days that I kept it in a small Glass wherein 'twas made, only letting fall a little Blackish Powder to the Bottom. The other Phænomena of this Experiment belong not to this place, where it may suffice to take notice of the Production of a Green, and that the Experiment was more than once repeated with Success.

9. And lastly, to try whether this way of compounding Colours would hold ev'n in Ingredients actually melted by the Violence of the Fire, provided their Texture were capable of safely induring Fusion, we caus'd some Blew and Yellow Ammel to be long and well wrought together in the Flame of a Lamp, which being Strongly and Incessantly blown on them kept them in some degree of Fusion, and at length (for the Experiment requires some Patience as well as Skil) we obtain'd the expected Ammel of a Green Colour.

I know not, Pyrophilus, whether it be worth while to acquaint you with the ways that came into my Thoughts, whereby in some measure to explicate the first of the mention'd ways of making a Green; for I have sometimes Conjectur'd, that the mixture of the Bise and the Orpiment produc'd a Green by so altering the Superficial Asperity, which each of those Ingredients had apart, that the Light Incident on the mixture was Reflected with differing Shades, as to Quantity, or Order, or both, from those of either of the Ingredients, and such as the Light is wont to be Modify'd with, when it Reflects from Grass, or Leaves, or some of those other Bodies that we are wont to call Green. And sometimes too I have doubted, whether the produced Green might not be partly at least deriv'd from this, That the Beams that Rebound from the Corpuscles of the Orpiment, giving one kind of stroak upon the Retina, whose Perception we call Yellow, and the Beams Reflected from the Corpuscles of the Bise, giving another stroak upon the same Retina, like to Objects that are Blew, the Contiguity and Minuteness of these Corpuscles may make the Appulse of the Reflected Light fall upon the Retina within so narrow a Compass, that the part they Beat upon being but as it were a Physical point, they may give a Compounded stroak, which may consequently exhibit a Compounded and new Kind of Sensation, as we see that two Strings of a Musical Instrument being struck together, making two Noises that arrive at the Ear at the same time as to Sense, yield a Sound differing from either of them, and as it were Compounded of both; Insomuch that if they be Discordantly ton'd, though each of them struck apart would yield a Pleasing Sound, yet being struck together they make but a Harsh and troublesome Noise. But this not being so fit a place to prosecute Speculations, I shall not insist, neither upon these Conjectures nor any others, which the Experiment we have been mentioning may have suggested to me. And I shall leave it to you, Pyrophilus, to derive what Instruction you can from comparing together the Various ways whereby a Yellow and a Blew can be made to Compound a Green. That which I now pretend to, being only to shew that the first of those mention'd ways, (not to take at present notice of the rest) does far better agree with our Conjectures about Colours, than either with the Doctrine of the Schools, or with that of the Chymists, both which seem to be very much Disfavour'd by it.

For first, since in the Mixture of the two mention'd Powders I could by the help of a very excellent Microscope (for ordinary ones will scarce serve the turn) discover that which seem'd to the naked Eye a Green Body, to be but a heap of Distinct, though very small Grains of Yellow Orpiment and Blew Bise confusedly enough Blended together, it appears that the Colour'd Corpuscles of either kind did each retain its own Nature and Colour; By which it may be guess'd, what meer Transposition and Juxtaposition of Minute and Singly unchang'd Particles of Matter can do to produce a new Colour; For that this Local Motion and new Disposition of the small parts of the Orpiment did Intervene is much more manifest than it is easie to Explicate how they should produce this new Green otherwise than by the new Manner of their being put together, and consequently by their new Disposition to Modifie the Incident Light by Reflecting it otherwise than they did before they were Mingl'd together.

Secondly, The Green thus made being (if I may so speak) Mechanically produc'd, there is no pretence to derive it from I know not what incomprehensible Substantial Form, from which yet many would have us believe that Colours must flow; Nor does this Green, though a Real and Permanent, not a Phantastical and Vanid Colour, seem to be such an Inherent Quality as they would have it, since not only each part of the Mixture remains unalter'd in Colour, and consequently of a differing Colour from the Heap they Compose, but if the Eye be assisted by a Microscope to discern things better and more distinctly than before it could, it sees not a Green Body, but a Heap of Blew and Yellow Corpuscles.

And in the third place, I demand what either Sulphur, or Salt, or Mercury has to do in the Production of this Green; For neither the Bise nor the Orpiment were indu'd with that Colour before, and the bare Juxtaposition of the Corpuscles of the two Powders that work not upon each other, but might if we had convenient Instruments be separated, unalter'd, cannot with any probability be imagin'd either to Increase or Diminish any of the three Hypostatical Principles, (to which of them soever the Chymists are pleas'd to ascribe Colours) nor does there here Intervene so much as Heat to afford them any colour to pretend, that at least there is made an Extraversion (as the Helmontians speak) of the Sulphur or of any of the two other supposed Principles; But upon this Experiment we have already Reflected enough, if not more than enough for once.

EXPERIMENT XVIII.

But here, Pyrophilus, I must advertise you, that 'tis not every Yellow and every Blew that being mingl'd will afford a Green; For in case one of the Ingredients do not Act only as endow'd with such a Colour, but as having a power to alter the Texture of the Corpuscles of the other, so as to Indispose them to Reflect the Light, as Corpuscles that exhibit a Blew or a Yellow are wont to Reflect it, the emergent Colour may be not Green, but such as the change of Texture in the Corpuscles of one or both of the Ingredients qualifies them to shew forth; as for instance, if you let fall a few Drops of Syrrup of Violets upon a piece of White Paper, though the Syrrup being spread will appear Blew, yet mingling with it two or three Drops of the lately mention'd Solution of Gold, I obtain'd not a Green but a Reddish mixture, which I expected from the remaining Power of the Acid Salts abounding in the Solution, such Salts or Saline Spirits being wont, as we shall see anon, though weakn'd, so to work upon that Syrrup as to change it into a Red or Reddish Colour. And to confirm that for which I allege the former Experiment, I shall add this other, that having made a very strong and high-colour'd Solution of Filings of Copper with Spirit of Urine, though the Menstruum seem'd Glutted with the Metall, because I put in so much Filings that many of them remain'd for divers days Undissolv'd at the Bottom, yet having put three or four Drops of Syrrup of Violets upon White Paper, I found that the deep Blew Solution proportionably mingl'd with this other Blew Liquor did not make a Blew mixture, but, as I expected, a fair Green, upon the account of the Urinous Salt that was in the Menstruum.

EXPERIMENT XIX.

To shew the Chymists, that Colours may be made to Appear or Vanish, where there intervenes no Accession or Change either of the Sulphureous, or the Saline, or the Mercurial principle (as they speak) of Bodies: I shall not make use of the Iris afforded by the Glass-prism, nor of the Colours to be seen in a fair Morning in those drops of Dew that do in a convenient manner Reflect and Refract the Beams of Light to the Eye; But I will rather mind them of what they may observe in their own Laboratories, namely, that divers, if not all, Chymical Essential Oyls, as also good Spirit of Wine, being shaken till they have good store of Bubbles, those Bubbles will (if attentively consider'd) appear adorn'd with various and lovely Colours, which all immediately Vanish, upon the relapsing of the Liquor that affords those Bubbles their Skins, into the rest of the Oyl, or Spirit of Wine, so that a Colourless Liquor may be made in a trice to exhibit variety of Colours, and may lose them in a moment without the Accession or Diminution of any of its Hypostatical Principles. And, by the way, 'tis not unworthy our notice, that some Bodies, as well Colourless, as Colour'd, by being brought to a great Thinness of parts, acquire Colours though they had none before, or Colours differing from them they were before endued with: For, not to insist on the Variety of Colours, that Water, made somewhat Glutinous by Sope, acquires, when 'tis blown into such Sphærical Bubbles as Boys are wont to make and play with; Turpentine (though it have a Colour deep enough of its own) may (by being blown into after a certain manner) be brought to afford Bubbles adorn'd with variety of Orient Colours, which though they Vanish after some while upon the breaking of the Bubbles, yet they would in likelihood always exhibit Colours upon their Superfices, (though not always the same in the same Parts of them, but Vary'd according to the Incidence of the Sight, and the Position of the Eye) if their Texture were durable enough: For I have seen one that was Skill'd at fashioning Glasses by the help of a Lamp, blowing some of them so strongly as to burst them, whereupon it was found, that the Tenacity of the Metall was such, that before it broke it suffer'd it self to be reduc'd into Films so extremely thin, that being kept clean they constantly shew'd on their Surfaces (but after the manner newly mention'd) the varying Colours of the Rain-bow, which were exceedingly Vivid, as I had often opportunity to observe in some, that I caus'd purposely to be made, to keep by me.

But lest it should be objected, that the above mentioned Instances are drawn from Transparent Liquors, it may possibly appear, not impertinent to add, what I have sometimes thought upon, and several times tried, when I was considering the Opinions of the Chymists about Colours, I took then a Feather of a convenient Bigness and Shape, and holding it at a fit distance betwixt my Eye and the Sun when he was near the Horizon, me thought there appear'd to me a Variety of little Rain-bows, with differing and very vivid Colours, of which none was constantly to be seen in the Feather; the like Phænomenon I have at other times (though not with altogether so good success) produc'd, by interposing at a due distance a piece of Black Ribband betwixt the almost setting Sun and my Eye, not to mention the Trials I have made to the same purpose, with other Bodies.

EXPERIMENT XX.

Take good Syrrup of Violets, Imprægnated with the Tincture of the flowers, drop a little of it upon a White Paper (for by that means the Change of Colour will be more conspicuous, and the Experiment may be practis'd in smaller Quantities) and on this Liquor let fall two or three drops of Spirit either of Salt or Vinegar, or almost any other eminently Acid Liquor, and upon the Mixture of these you shall find the Syrrup immediatly turn'd Red, and the way of Effecting such a Change has not been unknown to divers Persons who have produc'd the like, by Spirit of Vitriol, or juice of Limmons, but have Groundlessly ascrib'd the Effect to some Peculiar Quality of those two Liquors, whereas, (as we have already intimated) almost any Acid Salt will turn Syrrup of Violets Red. But to improve the Experiment, let me add what has not (that I know of) been hitherto observ'd, and has, when we first shew'd it them, appear'd something strange, even to those that have been inquisitive into the Nature of Colours; namely, that if instead of Spirit of Salt, or that of Vinegar, you drop upon the Syrrup of Violets a little Oyl of Tartar per Deliquium, or the like quantity of Solution of Potashes, and rubb them together with your finger, you shall find the Blew Colour of the Syrrup turn'd in a moment into a perfect Green, and the like may be perform'd by divers other Liquors, as we may have occasion elsewhere to Inform you.

Annotation upon the twentieth Experiment.

The use of what we lately deliver'd concerning the way of turning Syrrup of Violets, Red or Green, may be this; That, though it be a far more common and procurable Liquor than the Infusion of Lignum Nephriticum, it may yet be easily substituted in its Room, when we have a mind to examine, whether or no the Salt predominant in a Liquor or other Body, wherein 'tis Loose and Abundant, belong to the Tribe of Acid Salts or not. For if such a Body turn the Syrrup of a Red or Reddish Purple Colour, it does for the most part argue the Body (especially if it be a distill'd Liquor) to abound with Acid Salt. But if the Syrrup be made Green, that argues the Predominant Salt to be of a Nature repugnant to that of the Tribe of Acids. For, as I find that either Spirit of Salt, or Oyl of Vitriol, or Aqua-fortis, or Spirit of Vinegar, or Juice of Lemmons, or any of the Acid Liquors I have yet had occasion to try, will turn Syrrup of Violets, of a Red, (or at least, of a Reddish Colour, so I have found, that not only the Volatile Salts of all Animal Substances I have us'd, as Spirit of Harts-horn, of Urine, of Sal-Armoniack, of Blood, &c. but also all the Alcalizate Salts I have imploy'd, as the Solution of Salt of Tartar, of Pot-ashes, of common Wood-ashes, Lime-water, &c. will immediately change the Blew Syrrup, into a perfect Green. And by the same way (to hint that upon the by) I elsewhere show you, both the changes that Nature and Time produce, in the more Saline parts of some Bodies, may be discover'd, and also how ev'n such Chymically prepar'd Bodies, as belong not either to the Animal Kingdome, or to the Tribe of Alcali's, may have their new and superinduc'd Nature successfully Examin'd. In this place I shall only add, that not alone the Changing the Colour of the Syrrup, requires, that the Changing Body be more strong, of the Acid, or other sort of Salt that is Predominant in it, than is requisite for the working upon the Tincture of Lignum Nephriticum; but that in this is also, the Operation of the formerly mention'd Salts upon our Syrrup, differs from their Operation upon our Tinctures, that in this Liquor, if the Cæruleous Colour be Destroy'd by an Acid Salt, it may be Restor'd by one that is either Volatile, or Lixiviate; whereas in Syrrup of Violets, though one of these contrary Salts will destroy the Action of the other, yet neither of them will restore the Syrrup to its native Blew; but each of them will Change it into the Colour which it self doth (if I may so speak) affect, as we shall have Occasion to show in the Notes on the twenty fifth Experiment.

EXPERIMENT XXI.

There is a Weed, more known to Plowmen than belov'd by them, whose Flowers from their Colour are commonly call'd Blew-bottles, and Corn-weed from their Growing among Corn. These Flowers some Ladies do, upon the account of their Lovely Colour, think worth the being Candied, which when they are, they will long retain so fair a Colour, as makes them a very fine Sallad in the Winter. But I have try'd, that when they are freshly gather'd, they will afford a Juice, which when newly express'd, (for in some cases 'twill soon enough degenerate) affords a very deep and pleasant Blew. Now, (to draw this to our present Scope) by dropping on this fresh Juice, a little Spirit of Salt, (that being the Acid Spirit I had then at hand) it immediately turn'd (as I predicted) into a Red. And if instead of the Sowr Spirit I mingled with it a little strong Solution of an Alcalizate Salt, it did presently disclose a lovely Green; the same Changes being by those differing sorts of Saline Liquors, producible in this Natural juice, that we lately mention'd to have happen'd to that factitious Mixture, the Syrrup of Violets. And I remember, that finding this Blew Liquor, when freshly made, to be capable of serving in a Pen for an Ink of that Colour, I attempted by moistning one part of a piece of White Paper with the Spirit of Salt I have been mentioning, and another with some Alcalizate or Volatile Liquor, to draw a Line on the leisurely dry'd Paper, that should, e'vn before the Ink was dry, appear partly Blew, partly Red, and partly Green: But though the latter part of the Experiment succeeded not well, (whether because Volatile Salts are too Fugitive to be retain'd in the Paper, and Alcalizate ones are too Unctuous, or so apt to draw Moisture from the Air, that they keep the Paper from drying well) yet the former Part succeeded well enough; the Blew and Red being Conspicuous enough to afford a surprizing Spectacle to those, I acquaint not with (what I willingly allow you to call) the Trick.

Herbarists are wont to call this Plant Cyanus vulgaris minor.