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Part 12

Experiments and Considerations Touching Colours (1664) · Robert Boyle — chapter 12 of 23 · ~3,878 words · public domain

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D F & [delta] . Those Reflected Rays which are partly refracted towards G & . colourless, and partly reflected, towards H & [theta].

F H & [theta]. Those reflected Rays which are refracted towards I & . and there paint an other fainter Iris, the colours of which are contrary to the former 5 4 3 2 1. signifying Purple, Blew, Green, Yellow, Red, so that the Prism in this posture exhibits four Rainbows.

I know not whether you will think it Inconsiderable to annex to this Experiment, That we observ'd in a Room not Darken'd, that the Prismatical Iris (if I may so call it) might be Reflected without losing any of its several Colours (for we now consider not their Order) not onely from a plain Looking-glass and from the calm Surface of Fair Water, but also from a Concave Looking-glass; and that Refraction did as little Destroy those Colours as Reflection. For by the help of a large (double Convex) Burning-glass through which we Refracted the Suns Beams, we found that one part of the Iris might be made to appear either beyond, or on this side of the other Parts of the same Iris; but yet the same Vivid Colours would appear in the Displac'd part (if I may so term it) as in the other. To which I shall add, that having, by hiding the side of the Prism, obverted to the Sun with an Opacous Body, wherein only one small hole was left for the Light to pass through, reduc'd the Prismatical Iris (cast upon White Paper) into a very narrow compass, and look'd upon it througn a Microscope; the Colours appear'd the same as to kind that they did to the naked Eye.

EXPERIMENT VI.

It may afford matter of Speculation to the Inquisitive, such as you, Prophilus, that as the Colours of outward Objects brought into a Darken'd Room, do so much depend for their Visibility upon the Dimness of the Light they are there beheld by; that the ordinary Light of the day being freely let in upon them, they immediately disappear: so our Tryals have inform'd us, that as to the Prismatical Iris painted on the Floor by the beams of the Sun Trajected through a Triangular-glass; though the Colours of it appear very Vivid ev'n at Noon-day, and in Sun shiny Weather, yet by a more Powerfull Light they may be made to disappear. For having sometimes, (in prosecution of some Conjectures of mine not now to be Insisted on,) taken a large Metalline Concave Speculum, and with it cast the converging Beams of the Sun upon a Prismatical Iris which I had caus'd to be projected upon the Floor, I found that the over-powerfull Light made the Colours of the Iris disappear. And if I so Reflected the Light as that it cross'd but the middle of the Iris, in that part only the Colours vanish'd or were made Invisible; those parts of the Iris that were on the right and left hand of the Reflected Light (which seem'd to divide them, and cut the Iris asunder) continuing to exhibit the same Colours as before. But upon this we must not now stay to Speculate.

EXPERIMENT VII.

I have sometimes thought it worth while to take notice, whether or no the Colours of Opacous Bodies might not appear to the Eye somewhat Diversify'd, not only by the Disposition of the Superficial parts of the Bodyes themselves and by the Position of the Eye in Reference to the Object and the Light, (for these things are Notorious enough;) but according also to the Nature of the Lucid Body that shines upon them. And I remember that in Prosecution of this Curiosity, I observ'd a manifest Difference in some Kinds of Colour'd Bodyes look'd on by Day-light, and afterwards by the light of the Moon; either directly falling on them or Reflected upon them from a Concave Looking-glass. But not finding at present in my Collections about Colours any thing set down of this Kind, I shall, till I have opportunity to repeat them, content my self to add what I find Register'd concerning Colours look'd on by Candle-light, in regard that not only the Experiment is more easie to be repeated, but the Objects being the Same Sorts of Colour'd Paper lastly mention'd, the Collation of the two Experiments may help to make the Conjectures they will suggest somewhat the less uncertain.

Within a few dayes of the time above mention'd, divers Sheets of Colour'd Paper that had been look'd upon before in the Sunshine were look'd upon at night by the light of a pretty big Candle, (snuff'd) and the Changes that were observ'd were these.

The Yellow seem'd much fainter than in the Day, and inclinable to a pale Straw Colour.

The Red seem'd little Chang'd; but seem'd to Reflect Light more strongly than any other Colour (for White was none of them.)

A fair Deep Green look'd upon by it self seem'd to be a Dark Blew: But being look'd upon together with a Dark Blew, appear'd Greenish; and beheld together with a Yellow appear'd more Blew than at first.

The Blew look'd more like a Deep Purple or Murray than it had done in the Daylight.

The Purple seem'd very little alter'd.

The Red look'd upon with the Yellow made the Yellow look almost like Brown Cap-paper.

N. The Caution Subjoyned to the third Experiments is also Applicable to this.

EXPERIMENT VIII.

But here I must not omit to subjoyn, that to satisfie our Selves, whether or no the Light of a Candle were not made unsincere, and as it were Ting'd with a Yellow Colour by the Admixtion of the Corpuscles it assumes from its Fuel; we did not content our selves with what appears to the Naked Eye, but taking a pretty thick Rod or Cylinder (for thin Peeces would not serve the turn) of deep Blew Glass, and looking upon the Candles flame at a Convenient distance througn it, we perceiv'd as we expected, the Flame to look Green; which as we often note, is the Colour wont to emerge from the Composition of Opacous Bodies, which were apart one of them Blew, and the other Yellow. And this perchance may be the main Reason of that which some observe, that a sheet of very White Paper being look'd upon by Candle light, 'tis not easie at first to discern it from a light Yellow or Lemon Colour; White Bodyes (as we have elsewhere observ'd) having more than those that are otherwise Colour'd, of a Specular Nature; in regard that though they exhibit not, (unless they be Polish'd,) the shape of the Luminary that shines on them, yet they Reflect its Light more Sincere and Untroubl'd, by either Shades or Refractions, than Bodyes of other Colours (as Blew, or Green, or Yellow or the like.)

EXPERIMENT IX.

We took a Leaf of Such Foliated Gold as Apothecaries are wont to Gild their Pills with; and with the Edge of a Knife, (lightly moysten'd by drawing it over the Surface of the Tongue, and afterwards) laid upon the edge of the Gold Leaf; we so fasten'd it to the Knife, that being held against the light, it conctinu'd extended like a little Flagg. This Leaf being held very near the Eye, and obverted to the Light, appear'd so full of Pores, that it seem'd to have such a kind of Transparency as that of a Sive, or a piece of Cyprus, or a Love-Hood; but the Light that pass'd by these Pores was in its Passages So Temper'd with Shadow, and Modify'd, that the Eye discern'd no more a Golden Colour, but a Greenish Blew. And for other's satisfaction, we did in the Night look upon a Candle through such a Leaf of Gold; and by trying the Effect of Several Proportions of Distance betwixt the Leaf, the Eye and the Light, we quickly hit upon such a Position for the Leaf of Gold, as that the flame, look'd on through it, appear'd of a Greenish Blew, as we have seen in the Day time. The like Experiment try'd with a Leaf of Silver succeeded not well.

* * * * *

EXPERIMENT X.

We have sometimes found in the Shops of our Druggists, a certain Wood, which is there called Lignum Nephriticum, because the Inhabitants of the Country where it grows, are wont to use the Infusion of it made in fair Water against the Stone of the Kidneys, and indeed an Eminent Physician of our Acquaintance, who has very Particularly enquir'd into that Disease, assures me, that he has found such an Infusion one of the most effectual Remedyes, which he has ever tried against that formidable Disease. The ancientest Account I have met with of this Simple, is given us by the Experienc'd Monardes in these Words. Nobis, says he, Nova Hispania mittit quoddam ligni genus crassum & enode, cujus usus jam diu receptus fuit in his Regionibus ad Renum vitia & urinæ difficultates ac arenulas pellendas. Fit autem hac ratione, Lignum assulatim & minutim concisum in limpidissima aqua fontana maceratur, inque ea relinquitur, donec aqua à bibentibus absumpta sit, dimidia hora post injectum lignum aqua cæruleum colorem contrabit, qui sensim intenditur pro temporis diuturnitate, tametsi lignum candidum fit. This Wood, Pyrophilus, may afford us an Experiment, which besides the singularity of it, may give no small assistance to an attentive Considerer towards the detection of the Nature of Colours. The Experiment as we made it is this. Take Lignum Nephriticum, and with a Knife cut it into thin Slices, put about a handfull of these Slices into two three or four pound of the purest Spring-water, let them infuse there a night, but if you be in hast, a much shorter time may suffice; decant this Impregnated Water into a clear Glass Vial, and if you hold it directly between the Light and your Eye, you shall see it wholly Tincted (excepting the very top of the Liquor, wherein you will some times discern a Sky-colour'd Circle) with an almost Golden Colour, unless your Infusion have been made too Strong of the Wood, for in that case it will against the Light appear somewhat Dark and Reddish, and requires to be diluted by the addition of a convenient quantity of fair Water. But if you hold this Vial from the Light, so that your Eye be plac'd betwixt the Window and the Vial, the Liquor will appear of a deep and lovely Cæruleous Colour, of which also the drops, if any be lying on the outside of the Glass, will seem to be very perfectly; And thus far we have try'd the Experiment, and found it to Succeed even by the Light of Candles of the larger size. If you so hold the Vial over against your Eyes, that it may have a Window on one side of it, and a Dark part of the Room both before it and on the other side, you shall see the Liquor partly of a Blewish and partly of a Golden Colour. If turning your back to the Window, you powr out some of the Liquor towards the Light and towards your Eyes, it will seem at the comming out of the Glass to be perfectly Cæruleous, but when it is fallen down a little way, the drops may seem Particolour'd, according as the Beams of Light do more or less fully Penetrate and Illustrate them. If you take a Bason about half full of Water, and having plac'd it so in the Sun-beams Shining into a Room, that one part of the Water may be freely illustrated by the Beams of Light, and the other part of it Darkned by the shadow of the Brim of the Bason, if then I say you drop of our Tincture, made somewhat strong, both into the Shaded and Illuminated parts of the Water, you may by looking upon it from several places, and by a little Agitation of the water, observe divers pleasing Phænomena which were tedious to particularize. If you powr a little of this Tincture upon a sheet of White Paper, so as the Liquor may remain of some depth upon it, you may perceive the Neighbouring drops to be partly of one Colour, and partly of the other, according to the position of your Eye in reference to the Light when it looks upon them, but if you powr off all the Liquor, the Paper will seem Dy'd of an almost Yellow Colour. And if a sheet of Paper with some of this Liquor in it be plac'd in a window where the Sunbeams may shine freely on it, then if you turn your back to the Sun and take a Pen or some such slender Body, and hold it over-thwart betwixt the Sun and the Liquor, you may perceive that the Shadow projected by the Pen upon the Liquor, will not all of it be a vulgar and Dark, but in part a curiously Colour'd shadow, that edge of it, which is next the Body that makes it, being almost of a lively Golden Colour, and the remoter verge of a Cæruleous one.

Nicolaus Monardes lib simplic. ex India allatis, cap. 27.

These and other Phænomena, which I have observ'd in this delightfull Experiment, divers of my friends have look'd upon not without some wonder, and I remember an excellent Oculist finding by accident in a friends Chamber a fine Vial full of this Liquor, which I had given that friend, and having never heard any thing of the Experiment, nor having any Body near him that could tell him what this strange Liquor might be, was a great while apprehensive, as he presently after told me, that some strange new distemper was invading his Eyes. And I confess that the unusualness of the Phænomena made me very sollicitous to find out the Cause of this Experiment, and though I am far from pretending to have found it, yet my enquiries have, I suppose, enabled me to give such hints, as may lead your greater sagacity to the discovery of the Cause of this wonder. And first finding that this Tincture, if it were too copious in the water, Kept the Colours from being so lively, and their Change from being so discernable, and finding also that the Impregnating Virtue of this Wood did by its being frequently Infus'd in New Water by degrees Decay, I Conjectur'd that the Tincture afforded by the Wood must proceed from some Subtiler parts of it drawn forth by the Water, which swimming too and fro in it did so Modifie the Light, as to exhibit such and such Colours; and because these Subtile parts were so easily Soluble even in Cold water, I concluded that they must abound with Salts, and perhaps contain much of the Essential Salt, as the Chymists call it, of the Wood. And to try whether these Subtile parts were Volatile enough to be Distill'd, without the Dissolution of their Texture, I carefully Distill'd some of the Tincted Liquor in very low Vessels, and the gentle heat of a Lamp Furnace; but found all that came over to be as Limpid and Colourless as Rock-water, and the Liquor remaining in the Vessel to be so deeply Cæruleous, that it requir'd to be oppos'd to a very strong Light to appear of any other Colour. I took likewise a Vial with Spirit of Wine, and a little Salt of Harts-horn, and found that there was a certain proportion to be met with betwixt the Liquor and the Salt, which made the Mixture fit to exhibit some little Variety of Colours not Observable in ordinary Liquors, as it was variously directed in reference to the Light and the Eye, but this Change of Colour was very far short from that which we had admir'd in our Tincture. But however, I suspected that the Tinging Particles did abound with such Salts, whose Texture, and the Colour springing from it, would probably be alter'd by peircing Acid Salts, which would in likelihood either make some Dissipation of their Parts, or Associate themselves to the like Bodies, and either way alter the Colour exhibited by them; whereupon Pouring into a small Vial full of Impregnated Water, a very little Spirit of Vinegar, I found that according to my Expectation, the Cæruleous Colour immediately vanish'd, but was deceiv'd in the Expectation I had, that the Golden Colour would do so too; for, which way soever I turned the Vial, either to or from the Light, I found the Liquor to appear always of a Yellowish Colour and no other: Upon this I imagin'd that the Acid Salts of the Vinegar having been able to deprive the Liquor of its Cæruleous Colour, a Sulphureous Salt being of a contrary Nature, would be able to Mortifie the Saline Particles of Vinegar, and Destroy their Effects; And accordingly having plac'd my Self betwixt the Window, and the Vial, and into the Same Liquor dropt a few drops of Oyl of Tartar per Deliquium, (as Chymists call it) I observ'd with pleasure, that immediately upon the Diffusion of this Liquor, the Impregnated Water was restor'd to its former Cæruleous Colour; And this Liquor of Tartar being very Ponderous, and falling at first to the Bottom of the Vial, it was easie to observe that for a little while the Lower part of the Liquor appear'd deeply Cæruleous; whilst all the Upper part retain'd its former Yellowness, which it immediately lost as soon as either Agitation or Time had made a competent Diffusion of the Liquor of Tartar through the Body of the former Tincture; and this restored Liquor did, as it was Look'd upon against or from the Light, exhibit the Same Phænomena as the Tincted Water did, before either of the Adventitious Liquors was pour'd into it.

Having made, Pyrophilus, divers Tryals upon this Nephritick Wood, we found mention made of it by the Industrious Jesuit Kircherus, who having received a Cup Turned of it from the Mexican Procurator of his Society, has probably receiv'd also from him the Information he gives us concerning that Exotick Plant, and therefore partly for that Reason, and partly because what he Writes concerning it, does not perfectly agree with what we have deliver'd, we shall not Scruple to acquaint you in his own Words, with as much of what he writes concerning our Wood, as is requisite to our present purpose. Hoc loco (says he) neutiquam omittendum duximus quoddam ligni candidi Mexicani genus, quod Indigenæ Coalle & Tlapazatli vocant, quod etsi experientia hucusque non nisi Cæruleo aquam colore tingere docuerit, nos tamen continua experientia invenimus id aquam in omne Colorum genus transformare, quod merito cuipiam Paradoxum videri posset; Ligni frutex grandis, ut aiunt, non rarò in molem arboris excrescit, truncus illius eft crassus, enodis, instar piri arboris, folia ciceris foliis, aut rutæ haud absimilia, flores exigui, oblongi, lutei & spicatim digesti; est frigida & humida planta, licet parum recedat à medio temperamento. Hujus itaque descriptæ arboris lignum in poculum efformatum, aquam eidem infusam primo in aquam intense Cæruleam, colore floris Buglossæ; tingit, & quo diutius in eo steterit, tanto intensiorem colorem acquirit. Hanc igitur aquam si Vitreæ Sphæræ infuderis, lucique exposueris, ne ullum quidem Cærulei coloris vestigium apparebit, sed instar aquæ puræ putæ fontanæ limpidam claramque aspicientibus se præbebit. Porro si hanc phialam vitream versus locum magis umbrosum direxeris, totus humor gratissimum virorem referet; si adhuc umbrosioribus locis, subrubrum, & sic pro rerum objectarum conditione, mirum dictu, colorem mutabit; in tenebris verò vel in vase opaco posita, Cæruleum colorem suum resumet.

Kircher. Art. Mag. lucis & umbræ, lib. 1. part. 3.

In this passage we may take notice of the following Particulars. And first, he calls it a White Mexican Wood, whereas (not to mention that Mornardes informs us that it is brought out of Nova Hispania) the Wood that we have met with in several places, and employ'd as Lignum Nephriticum, was not White, but for the most part of a much Darker Colour, not unlike that of the Sadder Colour'd Wood of Juniper. 'Tis true, that Monardes himself also says, that the Wood is White; and it is affirm'd, that the Wood which is of a Sadder Colour is Adulterated by being Imbu'd with the Tincture of a Vegetable, in whose Decoction it is steep'd. But having purposely enquir'd of the Eminentest of our English Druggists, he peremptorily deny'd it. And indeed, having consider'd some of the fairest Round pieces of this Wood that I could meet with in these Parts, I had Opportunity to take notice that in one or two of them it was the External part of the Wood that was White, and the more Inward part that was of the other Colour, the contrary of which would probably have appear'd, if the Wood had been Adulterated after the afore-mention'd manner. And I have at present by me a piece of such Wood, which for about an Inch next the Bark is White, and then as it were abruptly passes to the above-mention'd Colour, and yet this Wood by the Tincture, it afforded us in Water, appears to have its Colour'd part Genuine enough; for as for the White part, it appears upon tryal of both at once, much less enrich'd with the tingent Property.

Next, whereas our Author tells us, that the Infusion of this Wood expos'd in a Vial to the Light, looks like Spring-water, in which he afterwards adds, that there is no Tincture to be seen in it, our Observation and his agree not, for the Liquor, which opposed to the Darker part of a Room exhibits a Sky-colour, did constantly, when held against the Light, appear Yellowish or Reddish, according as its Tincture was more Dilute or Deep; and then, whereas it has been already said, that the Cæruleous Colour was by Acid Salts abolished, this Yellowish one surviv'd without any considerable Alteration, so that unless our Author's Words be taken in a very Limited Sense, we must conclude, that either his Memory mis-inform'd him, or that his White Nephritick Wood, and the Sadder Colour'd one which we employ'd, were not altogether of the same Nature: What he mentions of the Cup made of Lignum Nephriticum, we have not had Opportunity to try, not having been able to procure pieces of that Wood great enough, and otherwise fit to be turned into Cups; but as for what he says in the Title of his Experiment, that this Wood tinges the Water with all Sorts of Colours, that is much more than any of those pieces of Nephritick Wood that we have hitherto employ'd, was able to make good; The change of Colours discernable in a Vial full of Water, Impregnated by any of them, as it is directed towards a place more Lightsome or Obscure, being far from affording a Variety answerable to so promising a Title. And as for what he tells us, that in the Dark the Infusion of our Wood will resume a Cæruleous Colour, I wish he had Inform'd us how he Try'd it.

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