SECTION I.. _the_ Analysis _of_ Vegetable Substances.

The ANALYSIS of VEGETABLE SUBSTANCES.

A vast many vegetable substances, such as kernels and seeds, yield, by strong compression, great quantities of mild, fat, unctuous Oils, which are not soluble in ardent spirits: these are what we called Expressed Oils. They are also sometimes called Fat Oils, on account of their unctuousness, in which they exceed all other sorts of Oil. As these oils are obtained without the aid of fire, it is certain that they existed in the mixt just as we see them, and that they are not in the least altered: which could not have been the case had they been obtained by distillation; for that never produces any Oils but such as are acrid and soluble in spirit of wine.

Some vegetable matters, such as the rind of citrons, lemons, oranges, &c. also yield, only by being squeezed between the fingers, a great deal of Oil. This spirts out in fine small jets, which being received upon any polished surface, such as a looking glass, run together and form a liquor that is a real Oil.

But it must be carefully noted, that this sort of Oil, though obtained by expression only, is nevertheless very different from the Oils mentioned before, to which the title of Expressed Oils peculiarly belongs: for this is far lighter and thinner; moreover, it retains the perfect odour of the fruit which yields it, and is soluble in spirit of wine; in a word, it is a true essential Oil, but abounds so in the fruits which produce it, and is lodged therein in such a manner, occupying a vast number of little cells provided in the peel for its reception, that a very slight pressure discharges it; which is not the case with many other vegetables that contain an essential Oil.

Succulent and green plants yield by compression a great deal of liquor or juice, which consists of most of the phlegm, of the salts, and a small portion of the oil and earth of the plant. These juices, being set in a cool place for some time, deposite saline crystals, which are a combination of the acid of the plant with part of its oil and earth, wherein the acid is always predominant. These salts, as is evident from the description here given, bear a great resemblance to the tartar of wine treated of above. They are called Essential Salts; so that Tartar might likewise be called the Essential Salt of Wine.

Dried plants, and such as are of a ligneous, or acid nature, require to be long triturated with water, before they will yield their essential salts. Trituration with water is an excellent way to get out of them all their saline and saponaceous contents.

A vegetable matter that is very oily yields its essential salt with much difficulty, if at all; because the excessive quantity of oil entangles the salt so that it cannot extricate itself or shoot into crystals. Mr. Gerike, in his Principles of Chymistry, says, that if part of the oil of a plant be extracted by spirit of wine, its essential salt may be afterwards obtained with more ease and in greater quantity. This must be a very good method for such plants as have an excessive proportion of essential oil; but will not succeed if the essential salt be hindered from crystallizing by a redundancy of fat oil, because fat oils are not soluble in spirit of wine.

Essential Salts are among those substances which cannot be extracted from mixts by distillation: for the first impression of fire decomposes them.

Though the acid which predominates in the Essential Salts of plants, be most commonly analogous to the vegetable acid, properly so called, that is, to the acid of vinegar and tartar, which is probably no other than the vitriolic acid disguised; yet it sometimes differs therefrom, and somewhat resembles the nitrous or the marine acid. This depends on the places where the plants grow which produce these salts: if they be maritime plants, their acid is akin to the acid of sea-salt; if on the contrary they grow upon walls, or in nitrous grounds, their acid is like that of nitre. Sometimes one and the same plant contains salts analogous to all the three mineral acids; which shews that the vegetable acids are no other than the mineral acids variously changed by circulating through plants.

Liquors containing the Essential Salts of plants being evaporated by a gentle heat to the consistence of honey, or even further, are called Extracts. Hence it is plain, that an Extract is nothing but the essential salt of a plant, combined with some particles of its oil and earth, that remained suspended in the liquor, and are now incorporated by evaporation.

Extracts of plants are also prepared by boiling them long in water, and then evaporating some part of it. But these Extracts are of inferior virtue; because the fire dissipates many of the oily and saline parts.

EMULSIONS.

Substances which abound much in Oil, being bruised and triturated with water for some time, afford a liquor of an opaque dead-white colour, like milk. This liquor consists of such juices as the water is capable of dissolving, together with a portion of the oil, which being naturally indissoluble in water, is only divided and dispersed in the liquor, the limpidity whereof is by that means destroyed. This sort of oily liquor, in which the oil is only divided, not dissolved, is called an Emulsion. The oily particles in Emulsions spontaneously separate from the water, when left at rest, and uniting into greater masses rise, on account of their lightness, to the surface of the liquor, which by that means recovers a degree of transparency.

If vegetables abounding in essential oils and resins be digested in spirit of wine, the menstruum takes up these oily matters, as being capable of dissolving them; and they may afterwards be easily separated from it by the affusion of water. The water, with which spirit of wine has a greater affinity than with oily matters, separates them by this means from their solvent, agreeably to the common laws of affinities.

Without the help of fire, scarce any thing, besides the substances already mentioned, can be obtained from a plant: but, by the means of distillation, we are enabled to analyse them more completely. In prosecuting this method of extracting from a plant the several principles of which it consists, the following order is to be observed.

A plant being exposed to a very gentle heat, in a distilling vessel set in the balneum mariæ, yields a water which retains the perfect smell thereof. Some Chymists, and particularly the illustrious Boerhaave, have called this liquor the Spiritus Rector. The nature of this odoriferous part of plants is not yet thoroughly known; because it is so very volatile that it is difficult to subject it to the experiments necessary for discovering all its properties.

If, instead of distilling the plant in the balneum mariæ, it be distilled over a naked fire, with the precaution of putting a certain quantity of water into the distilling vessel along with it, to prevent its suffering a greater heat than that of boiling water, all the essential oil contained in that plant will rise together with that water, and with the same degree of heat.

On this occasion it must be observed, that no essential oil can be obtained from a plant after the Spiritus Rector hath been drawn off; which gives ground to think that the volatility of these oils is owing to that spirit.

The heat of boiling water is also sufficient to separate from vegetable matters the fat oils which they contain. That, however, is to be done by the way of decoction only, and not by distillation: because, though these oils will swim on water, yet they will not rise in vapours without a greater degree of heat.

When the essential oil is come over, if the plant be exposed to a naked fire, without the addition of water, and the heat be increased a little, a phlegm will rise that gradually grows acid; after which, if the heat be increased as occasion requires, there will come over a thicker and heavier oil; from some a volatile alkali; and last of all, a very thick, black, empyreumatic oil.

When nothing more rises with the strongest degree of heat, there remains of the plant a mere coal only, called the Caput Mortuum, or Terra Damnata. This coal when burnt falls into ashes, which, being lixiviated with water, give a fixed alkali.

It is observable, that in the distillation of plants which yield an acid and a volatile alkali, these two salts are often found quite distinct and separate in the same receiver; which seems very extraordinary, considering that they are naturally disposed to unite, and have a great affinity with one another. The reason of this phenomenon is, that they are both combined with much oil, which embarrasses them so that they cannot unite to form a neutral salt, as they would not fail to do were it not for that impediment.

All vegetables, except such as yield a great deal of volatile alkali, being burnt in an open fire, and so as to flame, leave in their ashes a large quantity of an acrid, caustic, fixed alkali. But if care be taken to smother them, so as to prevent their flaming while they burn, by covering them with something that may continually beat down again what exhales, the salt obtained from their ashes will be much less acrid and caustic; the cause whereof is, that some part of the acid and oil of the plant being detained in the burning, and stopped from being dissipated by the fire, combines with its alkali. These salts crystallize, and, being much milder than the common fixed alkalis, may be used in medicine, and taken internally. They are called Tachenius's Salts, because invented by that Chymist.

Marine plants yield a fixed alkali analogous to that of sea-salt. As for all other plants or vegetable substances, the fixed alkalis obtained from them, if rightly prepared and thoroughly calcined, are all perfectly alike, and of the very same nature.

The last observation I have to make on the production of fixed alkalis is, that if the plant you intend to work upon be steeped or boiled in water before you burn it, a much smaller quantity of salt will be obtained from it; nay, it will yield none at all, if repeated boilings have robbed it entirely of those saline particles which must necessarily concur with its earth to form a fixed Alkali.