Part 32

Fuels for steam boilers may be classified as solid, liquid or gaseous. Of the solid fuels, anthracite and bituminous coals are the most common, but in this class must also be included lignite, peat, wood, bagasse and the refuse from certain industrial processes such as sawdust, shavings, tan bark and the like. Straw, corn and coffee husks are utilized in isolated cases.

The class of liquid fuels is represented chiefly by petroleum, though coal tar and water-gas tar are used to a limited extent.

Gaseous fuels are limited to natural gas, blast furnace gas and coke oven gas, the first being a natural product and the two latter by-products from industrial processes. Though waste gases from certain processes may be considered as gaseous fuels, inasmuch as the question of combustion does not enter, the methods of utilizing them differ from that for combustible gaseous fuel, and the question will be dealt with separately.

Since coal is by far the most generally used of all fuels, this chapter will be devoted entirely to the formation, composition and distribution of the various grades, from anthracite to peat. The other fuels will be discussed in succeeding chapters and their combustion dealt with in connection with their composition.

Formation of Coal--All coals are of vegetable origin and are the remains of prehistoric forests. Destructive distillation due to great pressures and temperatures, has resolved the organic matter into its invariable ultimate constituents, carbon, hydrogen, oxygen and other substances, in varying proportions. The factors of time, depth of beds, disturbance of beds and the intrusion of mineral matter resulting from such disturbances have produced the variation in the degree of evolution from vegetable fiber to hard coal. This variation is shown chiefly in the content of carbon, and Table 35 shows the steps of such variation.

TABLE 35

APPROXIMATE CHEMICAL CHANGES FROM WOOD FIBER TO ANTHRACITE COAL

+----------------------+-------+--------+-------+ |Substance |Carbon |Hydrogen|Oxygen | +----------------------+-------+--------+-------+ |Wood Fiber | 52.65 | 5.25 | 42.10 | |Peat | 59.57 | 5.96 | 34.47 | |Lignite | 66.04 | 5.27 | 28.69 | |Earthy Brown Coal | 73.18 | 5.68 | 21.14 | |Bituminous Coal | 75.06 | 5.84 | 19.10 | |Semi-bituminous Coal | 89.29 | 5.05 | 5.66 | |Anthracite Coal | 91.58 | 3.96 | 4.46 | +----------------------+-------+--------+-------+

Composition of Coal--The uncombined carbon in coal is known as fixed carbon. Some of the carbon constituent is combined with hydrogen and this, together with other gaseous substances driven off by the application of heat, form that portion of the coal known as volatile matter. The fixed carbon and the volatile matter constitute the combustible. The oxygen and nitrogen contained in the volatile matter are not combustible, but custom has applied this term to that portion of the coal which is dry and free from ash, thus including the oxygen and nitrogen.

The other important substances entering into the composition of coal are moisture and the refractory earths which form the ash. The ash varies in different coals from 3 to 30 per cent and the moisture from 0.75 to 45 per cent of the total weight of the coal, depending upon the grade and the locality in which it is mined. A large percentage of ash is undesirable as it not only reduces the calorific value of the fuel, but chokes up the air passages in the furnace and through the fuel bed, thus preventing the rapid combustion necessary to high efficiency. If the coal contains an excessive quantity of sulphur, trouble will result from its harmful action on the metal of the boiler where moisture is present, and because it unites with the ash to form a fusible slag or clinker which will choke up the grate bars and form a solid mass in which large quantities of unconsumed carbon may be imbedded.

Moisture in coal may be more detrimental than ash in reducing the temperature of a furnace, as it is non-combustible, absorbs heat both in being evaporated and superheated to the temperature of the furnace gases. In some instances, however, a certain amount of moisture in a bituminous coal produces a mechanical action that assists in the combustion and makes it possible to develop higher capacities than with dry coal.

Classification of Coal--Custom has classified coals in accordance with the varying content of carbon and volatile matter in the combustible. Table 36 gives the approximate percentages of these constituents for the general classes of coals with the corresponding heat values per pound of combustible.

TABLE 36

APPROXIMATE COMPOSITION AND CALORIFIC VALUE OF GENERAL GRADES OF COAL ON BASIS OF COMBUSTIBLE

+-------------------+----------------------------+--------------+ | Kind of Coal | Per Cent of Combustible | B. t. u. | | +------------+---------------+ Per Pound of | | |Fixed Carbon|Volatile Matter| Combustible | +-------------------+------------+---------------+--------------+ |Anthracite |97.0 to 92.5| 3.0 to 7.5 |14600 to 14800| |Semi-anthracite |92.5 to 87.5| 7.5 to 12.5 |14700 to 15500| |Semi-bituminous |87.5 to 75.0| 12.5 to 25.0 |15500 to 16000| |Bituminous--Eastern|75.0 to 60.0| 25.0 to 40.0 |14800 to 15300| |Bituminous--Western|65.0 to 50.0| 35.0 to 50.0 |13500 to 14800| |Lignite | Under 50 | Over 50 |11000 to 13500| +-------------------+------------+---------------+--------------+

Anthracite--The name anthracite, or hard coal, is applied to those dry coals containing from 3 to 7 per cent volatile matter and which do not swell when burned. True anthracite is hard, compact, lustrous and sometimes iridescent, and is characterized by few joints and clefts. Its specific gravity varies from 1.4 to 1.8. In burning, it kindles slowly and with difficulty, is hard to keep alight, and burns with a short, almost colorless flame, without smoke.

Semi-anthracite coal has less density, hardness and luster than true anthracite, and can be distinguished from it by the fact that when newly fractured it will soot the hands. Its specific gravity is ordinarily about 1.4. It kindles quite readily and burns more freely than the true anthracites.

Semi-bituminous coal is softer than anthracite, contains more volatile hydrocarbons, kindles more easily and burns more rapidly. It is ordinarily free burning, has a high calorific value and is of the highest order for steam generating purposes.

Bituminous coals are still softer than those described and contain still more volatile hydrocarbons. The difference between the semi-bituminous and the bituminous coals is an important one, economically. The former have an average heating value per pound of combustible about 6 per cent higher than the latter, and they burn with much less smoke in ordinary furnaces. The distinctive characteristic of the bituminous coals is the emission of yellow flame and smoke when burning. In color they range from pitch black to dark brown, having a resinous luster in the most compact specimens, and a silky luster in such specimens as show traces of vegetable fiber. The specific gravity is ordinarily about 1.3.

Bituminous coals are either of the caking or non-caking class. The former, when heated, fuse and swell in size; the latter burn freely, do not fuse, and are commonly known as free burning coals. Caking coals are rich in volatile hydrocarbons and are valuable in gas manufacture.

Bituminous coals absorb moisture from the atmosphere. The surface moisture can be removed by ordinary drying, but a portion of the water can be removed only by heating the coal to a temperature of about 250 degrees Fahrenheit.

Cannel coal is a variety of bituminous coal, rich in hydrogen and hydrocarbons, and is exceedingly valuable as a gas coal. It has a dull resinous luster and burns with a bright flame without fusing. Cannel coal is seldom used for steam coal, though it is sometimes mixed with semi-bituminous coal where an increased economy at high rates of combustion is desired. The composition of cannel coal is approximately as follows: fixed carbon, 26 to 55 per cent; volatile matter, 42 to 64 per cent; earthy matter, 2 to 14 per cent. Its specific gravity is approximately 1.24.

Lignite is organic matter in the earlier stages of its conversion into coal, and includes all varieties which are intermediate between peat and coal of the older formation. Its specific gravity is low, being 1.2 to 1.23, and when freshly mined it may contain as high as 50 per cent of moisture. Its appearance varies from a light brown, showing a distinctly woody structure, in the poorer varieties, to a black, with a pitchy luster resembling hard coal, in the best varieties. It is non-caking and burns with a bright but slightly smoky flame with moderate heat. It is easily broken, will not stand much handling in transportation, and if exposed to the weather will rapidly disintegrate, which will increase the difficulty of burning it.

Its composition varies over wide limits. The ash may run as low as one per cent and as high as 50 per cent. Its high content of moisture and the large quantity of air necessary for its combustion cause large stack losses. It is distinctly a low-grade fuel and is used almost entirely in the districts where mined, due to its cheapness.

Peat is organic matter in the first stages of its conversion into coal and is found in bogs and similar places. Its moisture content when cut is extremely high, averaging 75 or 80 per cent. It is unsuitable for fuel until dried and even then will contain as much as 30 per cent moisture. Its ash content when dry varies from 3 to 12 per cent. In this country, though large deposits of peat have been found, it has not as yet been found practicable to utilize it for steam generating purposes in competition with coal. In some European countries, however, the peat industry is common.

Distribution--The anthracite coals are, with some unimportant exceptions, confined to five small fields in Eastern Pennsylvania, as shown in the following list. These fields are given in the order of their hardness.

Lehigh or Eastern Middle Field Green Mountain District Black Creek District Hazelton District Beaver Meadow District Panther Creek District

Mahanoy or Western Field East Mahanoy District West Mahanoy District