Part 41

As we now know that man existed in Britain during the inter-glacial, if not the pre-glacial period, and as so violent a volcanic disturbance as that which poured out the lavas of Antrim and the Mourne district could scarcely have subsided suddenly, but was probably followed by ages of declining activity, it is not at all surprising that this period of minor activity should have extended into that of tradition and the earliest of historical records.

TRAVERTINE.

The old exclamation about Augustus finding Rome of brick and leaving it of marble, deceives many. Ancient Rome was by no means a marble city, although the quarries of Massa and Carrara are not far distant. The staple-building materials of the Imperial City, even in its palmiest days, were brick and travertine. The brick, however, was very different from the porous cakes of crudely burnt clay of which the modern metropolis of the world is built. I have examined on the spot a great many specimens, and found them all to be of remarkably compact structure, somewhere between the material of modern terra-cotta and that of common flower-pots, and similarly intermediate in color. The Roman builders appear to have had no standard size; the bricks vary even in the same building—the Coliseum for example; all that I have seen are much thinner than our bricks—we should call them tiles.

But the most characteristic material is the travertine. The walls of the Coliseum are made up of a mixture of this and the tiles above-mentioned. The same is the case with most of the other very massive ruins, as the baths, etc. Many of the temples with columns and facing of marble have inner walls built of this mixture, while others are entirely of travertine.

I was greatly surprised at the wondrous imperishability of this remarkable material. In buildings of which the smooth crystalline marble had lost all its sharpness and original surface, this dirty, yellow, spongy-looking limestone remained without the slightest indication of weathering. A most remarkable instance of this is afforded by the temple of Neptune at Paestum, in Calabria. This is the most perfect ruin of a pure classic temple that now remains in existence, and in my opinion is the finest. I prefer it even to the Parthenon.

We have a little sample of it in London. The Doric columns at the entrance of the Euston station are copies of those of its peristyle. The originals are of travertine, the blocks forming them are laid upon each other without mortar or cement, and so truly flattened that in walking round the building and carefully prying, I could find no crevice into which a slip of ordinary writing paper, or the blade of a pen-knife could be inserted. Yet this temple was an antiquarian monument in the days of the Roman emperors.

The rough natural surface of the stone is exposed, and at first sight appears as though weathered, but this appearance is simply due to its natural sponge-like structure. It appears to have been coated with some sort of stucco or smoothing film, which, either by forming a thin layer, or possibly by only filling up the pores of the travertine, gave a smooth surface upon which the coloring was applied. This is now only indistinctly visible here and there, and if I remember rightly, some have disputed its existence.

But this travertine, though so familiar to the Italian, is such a rarity here that some further description of its structure and composition may be demanded. It is a limestone formed by chemical precipitation. Most limestones are more or less of organic origin, are agglomerations of shells, corals, etc., but this is formed by the same kind of action as that which produces the stalactites in limestone caverns. It has some resemblance to the incrustation formed on boilers by calcareous water. Although the material of so many ancient edifices, it is, geologically speaking, the youngest of all the hard rocks. Its formation is now in progress at some of the very quarries that supplied Imperial Rome.

On the Campagna, between Rome and Tivoli, is a small circular lake, from which a stream of tepid water, that wells up from below, is continually flowing. Its local name is the “The Lake of Tartarus.” The water, like that of Zoedone, or soda-water or champagne, is supersaturated with carbonic acid that was forced into it while under pressure down below. This carbonic acid has dissolved some of the limestones through which the subterranean water passes, and when it comes to the surface, the carbonic acid flies away like that which escapes when we uncork a bottle of soda-water, though less suddenly, and the lime losing its solvent is precipitated, and forms a crust on whatever is covered by the water.

When I visited this lake in the month of February it was surrounded by a chevaux de frise of an extraordinary character; thousands of tubes of about half an inch to one inch in diameter outside, with calcareous walls about one eighth of an inch in thickness. These were standing up from two to three feet high, and so close together that we had to break our way through the dense palisade they formed in order to reach the margin of the lake. After some consideration and inquiry, their origin was discovered. They are the encrusted remains of bullrushes that had flourished in the summer and died down since. During the time of their growth the water had risen, and thus they became coated with a crust of compact travertine. This deposition takes place so rapidly that a piece of lace left in the lake for a few hours comes out quite stiff, every thread being coated with limestone. Such specimens, and twigs similarly covered, are sold to tourists or prepared by them if they have time to stop. Sir Humphry Davy drove a stick into the bottom of the lake and left it standing upright in the water from May to the following April, and then had some difficulty in breaking with a sharp pointed hammer the crust formed round the stick. This crust was several inches in thickness. That which I saw round the ex-bullrushes may have all been formed in a few days or weeks. The rivulet that flows from the lake deposits travertine throughout its course, and when it overflows leaves every blade of grass that it covers encrusted with this limestone.

Near to the Lake of Tartarus is the Solfatara lake which contains similar calcareous water, but strongly impregnated with sulphureted hydrogen; it consequently deposits a mixture of carbonate and sulphide of calcium, a sort of porous tufa, some of it so porous that it floats like a stony scum, forming what the cicerone call “floating islands.” Lyell, in his “Principles of Geology,” confounds these lakes, and describes Tartarus under the name of Solfatara.

The travertine used as a building stone is chiefly derived from the quarries of Ponte Lucano, and is the deposit that was formed on the bed of a lake like that of Tartarus. The celebrated cascade of the Anio at Tivoli forms calcareous stalactites, and all the country round has rivulets, caverns, and deposits, where this formation may be seen in progress or completed.

It varies considerably in structure, some specimens are compact and smooth, others have the appearance of a petrified moss, and great varieties may be found among the materials of a single building. It is, however, usually rough and more or less spongy-looking, as above stated, but this structure does not seem to affect its stability, at least, not in the climate of Italy. Whether it would stand long frosts is an open question. The night frosts at and about Rome are rather severe, but usually followed by a warm sunny day; thus there is no great penetration of ice.

Every specimen I have examined shows a remarkable compactness of molecular structure in spite of visible porosity. All give out a clear metallic ring when struck, and the intimate surface, if I may so describe the surface of the warm-like structure it sometimes displays, is always clear and smooth as though varnished. To this I attribute its durability. Lest the above description should appear self-contradictory, I will explain a little further. If melted glass were run into threads, and those threads while soft were allowed to agglomerate loosely into a convoluted mass, it would, as regarded in mass, have a porous or spongy-looking structure, but nevertheless its molecular structure would be compact and vitreous; there would be mechanical but not molecular, porosity. Travertine is similar.

Have we any travertine in England? This is a practical question of some importance, and one to which I have no hesitation in replying, Yes. There is plenty formed and forming in the neighborhood of Matlock, but that which I have seen on the face of caverns, etc., is not so compact and metal-like as the Italian. This, however, does not prove the entire absence of the useful travertine. Not having any commercial interest in the search, I have only looked at what has come in my way, but have little doubt that there are other kinds besides those I saw. I have also seen travertine in course of formation in Ireland, where I think there is a fine field for exploration in the mountain limestone regions, which have been disturbed by volcanic action of the Miocene period. The travertines of Italy are found in the neighborhood of extinct volcanoes.

The classic associations of this material, its remarkable stability, and the faculty with which it may be worked, render it worthy of more attention than it has yet received from British builders.

THE ACTION OF FROST IN WATER-PIPES AND ON BUILDING MATERIALS.

Popular science has penetrated too deeply now to render necessary any refutation of the old popular fallacy which attributed the bursting of water-pipes to the thaw following a frost; everybody now understands that the thaw merely renders the work of the previous freezing so disastrously evident. Nevertheless, the general subject of the action of freezing water upon our dwellings is not so fully understood by all concerned as it should be. Builders and house-owners should understand it thoroughly, as most of the domestic miseries resulting from severe winters may be greatly mitigated, if not entirely prevented, by scientific adaptation in the course of building construction. Now-a-days tenants know something about this and select accordingly. Thus the market value of a building may be increased by such adaptation.

Solids, liquids, and gases expand as they are heated. This great general law is, however, subject to a few exceptions, the most remarkable of which is that presented by water. Let us suppose a simple experiment. Imagine a thermometer tube with its bulb and stem so filled with water that when the water is heated nearly to its boiling point it will rise to nearly the top of the long stem. Now let us cool it. As the cooling proceeds the water will descend, and this descending will continue until it attains the temperature marked on our ordinary thermometer as 39°, or more strictly 39-2/10; then a strange inversion occurs. As the temperature falls below this, the water rises gradually in the stem until the freezing point is reached.

This expansion amounts to 1/7692 part of the whole bulk of the water, or 100,000 parts become 100,013. So far the amount of expansion is very small, but this is only a foretaste of what is coming. Lower the temperature still further, the water begins to freeze, and at the moment of freezing it expands suddenly to an extent equalling 1/15 of its bulk, i.e., of the bulk of so much water as becomes solidified. The temperature remains at 32° until the whole of the water is frozen.

Fortunately for us, the freezing of water is always a slow process, for if this conversion of every 15 gallons into 16 took place suddenly, all our pipes would rip open with something like explosive violence. But such sudden freezing of any considerable quantity of water is practically impossible, on account of the “latent heat” of liquid water, which amounts to 142½°. All this is given out in the act of freezing. It is this giving out of so much heat that keeps the temperature of freezing water always at 32°, even though the air around may be much colder. No part of the water can fall below 32° without becoming solid, and that portion which solidifies gives out enough heat to raise 142½ times its own quantity from 31° to 32°.

The slowness of thawing is due to the same general fact. An instructive experiment may be made by simply filling a saucepan with snow or broken ice, and placing it over a common fire. The slowness of the thawing will surprise most people who have not previously tried the experiment. It takes about as long to melt this snow as it would to raise an equal weight of water from 32° to 174°. Or, if a pound of water at 174° be mixed with a pound of snow at 32°, the result will be two pounds of water at 32°; 142° will have disappeared without making the snow any warmer, it will all have been used up in doing the work of melting.

The force with which the great expansion due to freezing takes place is practically irresistible. Strong pieces of ordnance have been filled with water, and plugged at muzzle and touch-hole. They have burst in spite of their great thickness and tenacity. Such being the case, it is at first sight a matter of surprise that frozen water-pipes, whether of lead or iron, ever stand at all. They would not stand but for another property of ice, which is but very little understood, viz., its viscosity.

This requires some explanation. Though ice is what we call a solid, it is not truly solid. Like other apparent solids it is not perfect rigid, but still retains some degree of the possibility of flowing which is the characteristic of liquids. This has been shown by filling a bombshell with water, leaving the fuse-hole open and freezing it. A shell of ice is first formed on the outside, which of course plugs up the fuse-hole. Then the interior gradually freezes, but the expansion due to this forces the ice out of the fuse-hole as a cylindrical stick, just as putty might be squeezed out, only that the force required to mould and eject the ice is much greater.

I have constructed an apparatus which illustrates this very strikingly. It is an iron syringe with cylindrical interior of about half an inch in diameter, and a terminal orifice of less than 1/20 of an inch in diameter. Its piston of metal is driven down by a screw. Into this syringe I place small fragments of ice, or a cylinder of ice fitted to the syringe, and then screw down the piston. Presently a thin wire of ice is squirted forth like vermicelli when the dough from which it is made is similarly treated, showing that the ice is plastic like the dough, provided it is squeezed with sufficient force.

This viscosity of ice is displayed on a grand scale in glaciers, the ice of which actually flows like a river down the glacier valley, contracting as the valley narrows and spreading out as it widens, just as a river would; but moving only a few inches daily according to the steepness of the slope and the season, slower in winter than in summer.

Upon this, and the slowness of the act of freezing, depends the possibility of water in freezing in iron pipes without bursting them. Even iron yields a little before bursting, but ordinary qualities not sufficiently to bear the expansion of 1/15 of their contents. What happens then? The cylinder of ice contained in the tube elongates as it freezes, provided always the pipe is open at one or both ends. But there is a limit to this, seeing that the friction of such a tight-fitting core, even of slippery ice, is considerable, and if the pipe be too long, the resistance of this friction may exceed the resistance of tenacity of the pipe. I am unable to give any figures for such length; the subject does not appear to have been investigated as it should be, and as it might well be by our wealthy water companies.

We all know that lead pipes frequently succumb, but a little observation shows that they do so only after a struggle. The tenacity of lead is much less than that of iron (about 1/20 of that of ordinary wrought iron), but it yields considerably before breaking. It has, in fact, the property of viscosity similar to that of ice. At Woolwich the lead used for elongated rifle bullets is squirted like the ice in my syringe above described, powerful hydraulic pressure being used.