(6) Rosin.
(7) Rubber.
(8) Linseed oil.
(9) Casein and albumen.
(10) Silicates of soda and oxychloride cements.
(11) Flour and starch.
(12) Miscellaneous, including core compounds.
I. Plaster of Paris is, of course, often used alone as a paste; which quickly {33} solidifies, for gas and wood distillation retorts, etc., and similar places where quickness of setting is requisite. It is more often, however, used with some fibrous material to give it greater strength. Asbestos is the most commonly used material of these, as it will stand a high temperature. When that is not so important, straw, plush trimmings, hair, etc., are used as binders, while broken stone, glass, and various mineral substances are used as fillers, but they do not add anything to the strength. These lutes seem to be particularly suitable for oil vapors and hydrocarbon gases.
Formulas:
(1) Plaster and water. (2) Plaster (wet) and asbestos. (3) Plaster (wet) and straw. (4) Plaster (wet) and plush trimmings. (5) Plaster (wet) and hair. (6) Plaster (wet) and broken stone, etc.
II. Hydraulic Cement.—Cement is used either alone or with sand, asbestos, etc. These lutes are suitable for nitric acid. When used with substances such as rosin or sulphur, cement is probably employed because it is in such a fine state of division and used as a filler and not because of any powers of setting by hydration.
Formulas:
(1) Cement—neat. (2) Cement and asbestos. (3) Cement and sand.
III. Clay.—This most frequently enters into the composition of lutes as a filler, but even then the very finely divided condition of certain grades renders it valuable, as it gives body to a liquid, such as linseed oil, which, unless stiffened, would be pervious to a gas, the clay in all cases being neutral. Thus, for luting pipes carrying chlorine, a stiff paste of clay and molasses has been suggested by Theo. Köller in Die Surrogate, but it soon gives way.
Formulas:
(1) Clay and linseed oil. (2) Same, using fire clay. (3) Clay and molasses.
(1) Is suitable for steam, etc.; (2) for chlorine, and (3) for oil vapors.
IV. Lime is used in the old lute known as putty, which consists of caustic lime and linseed oil. Frequently the lime is replaced by chalk and china clay, but the lime should be, in part at least, caustic, so as to form a certain amount of lime soap. Lime is also used in silicate and casein compositions, which are very strong and useful, but will be described elsewhere.
Formulas:
(1) Lime and boiled oil to stiff mass. (2) Clay, etc., boiled oil to stiff mass.
V. Asphalt and Pitch.—These substances are used in lutes somewhat interchangeably. As a rule, pitch makes the stronger lutes. Tar is sometimes used, but, because of the light oils and, frequently, water contained, it is not so good as either of the others.
Asphalt dissolved in benzol is very useful for uniting glass for photographic, microscopical, and other uses. Also for coating wood, concrete, etc., where the melted asphalt would be too thick to cover well. Benzol is the cheapest solvent that is satisfactory for this purpose, as the only one that is cheaper would be a petroleum naphtha, which does not dissolve all the constituents of the asphalt. For waterproofing wood, brick, concrete, etc., melted asphalt alone is much used, but when a little paraffine is added, it improves its waterproofing qualities, and in particular cases boiled oil is also added to advantage.
Formulas:
1. Refined lake asphalt.
2. Asphalt 4 parts Paraffine 1 part
3. Asphalt 10 parts Paraffine 2 parts Boiled oil 1 part
Any of these may be thinned with hot benzol or toluol. Toluol is less volatile than benzol and about as cheap, if not cheaper, the straw-colored grades being about 24 cents per gallon.
Examples of so-called “stone cement” are:
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