Part 8

In the experiments here referred to, glass lenses were employed to concentrate the rays. But glass, though highly transparent to the luminous, is in a high degree opaque to the invisible, heat-rays of the electric lamp, and hence a large portion of those rays was intercepted by the glass. The obvious remedy here is to employ rock-salt lenses instead of glass ones, or to abandon the use of lenses wholly, and to concentrate the rays by a metallic mirror. Both of these improvements have been introduced, and, as anticipated, the invisible foci have been thereby rendered more intense. The mode of operating remains however the same, in principle, as that made known in 1862. It was then found that an instant's exposure of the face of the thermoelectric pile to the focus of invisible rays, dashed the needles of a coarse galvanometer violently aside. It is now found that on substituting for the face of the thermo-electric pile a combustible body, the invisible rays are competent to set that body on fire.

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6. Visible and Invisible Rays of the Electric Light.

We have next to examine what proportion the non-luminous rays of the electric light bear to the luminous ones. This the opaque solution of iodine enables us to do with an extremely close approximation to the truth.

The pure bisulphide of carbon, which is the solvent of the iodine, is perfectly transparent to the luminous, and almost perfectly transparent to the dark, rays of the electric lamp. Supposing the total radiation of the lamp to pass through the transparent bisulphide, while through the solution of iodine only the dark rays are transmitted. If we determine, by means of a thermoelectric pile, the total radiation, and deduct from it the purely obscure, we obtain the value of the purely luminous emission. Experiments, performed in this way, prove that if all the visible rays of the electric light were converged to a focus of dazzling brilliancy, its heat would only be one-eighth of that produced at the unseen focus of the invisible rays.

Exposing his thermometers to the successive colours of the solar spectrum, Sir William Herschel determined the heating power of each, and also that of the region beyond the extreme red. Then drawing a straight line to represent the length of the spectrum, he erected, at various points, perpendiculars to represent the calorific intensity existing at those points. Uniting the ends of all his perpendiculars, he obtained a curve which showed at a glance the manner in which the heat was distributed in the solar spectrum. Professor Müller of Freiburg, with improved instruments, afterwards made similar experiments, and constructed a more accurate diagram of the same kind. We have now to examine the distribution of heat in the spectrum of the electric light; and for this purpose we shall employ a particular form of the thermo-electric pile, devised by Melloni. Its face is a rectangle, which by means of movable side-pieces can be rendered as narrow as desired. We can, for example, have the face of the pile the tenth, the hundredth, or even the thousandth of an inch in breadth. By means of an endless screw, this linear thermo-electric pile may be moved through the entire spectrum, from the violet to the red, the amount of heat falling upon the pile at every point of its march, being declared by a magnetic needle associated with the pile.

When this instrument is brought up to the violet end of the spectrum of the electric light, the heat is found to be insensible. As the pile is gradually moved from the violet end towards the red, heat soon manifests itself, augmenting as we approach the red. Of all the colours of the visible spectrum the red possesses the highest heating power. On pushing the pile into the dark region beyond the red, the heat, instead of vanishing, rises suddenly and enormously in intensity, until at some distance beyond the red it attains a maximum. Moving the pile still forward, the thermal power falls, somewhat more rapidly than it rose. It then gradually shades away, but, for a distance beyond the red greater than the length of the whole visible spectrum, signs of heat may be detected.

Drawing a datum line, and erecting along it perpendiculars, proportional in length to the thermal intensity at the respective points, we obtain the extraordinary curve, shown on the opposite page, which exhibits the distribution of heat in the spectrum of the electric light. In the region of dark rays, beyond the red, the curve shoots up to B, in a steep and massive peak--a kind of Matterhorn of heat, which dwarfs the portion of the diagram C D E, representing the luminous radiation. Indeed the idea forced upon the mind by this diagram is that the light rays are a mere insignificant appendage to the heat-rays represented by the area A B C D, thrown in as it were by nature for the purpose of vision.

Figure 1. Spectrum of Electric Light

The diagram drawn by Professor Müller to represent the distribution of heat in the solar spectrum is not by any means so striking as that just described, and the reason, doubtless, is that prior to reaching the earth the solar rays have to traverse our atmosphere. By the aqueous vapour there diffused, the summit of the peak representing the sun's invisible radiation is cut off. A similar lowering of the mountain of invisible heat is observed when the rays from the electric light are permitted to pass through a film of water, which acts upon them as the atmospheric vapour acts upon the rays of the sun.

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7. Combustion by Invisible Rays.

The sun's invisible rays far transcend the visible ones in heating power, so that if the alleged performances of Archimedes during the siege of Syracuse had any foundation in fact, the dark solar rays would have been the philosopher's chief agents of combustion. On a small scale we can readily produce, with the purely invisible rays of the electric light, all that Archimedes is said to have performed with the sun's total radiation. Placing behind the electric light a small concave mirror, the rays are converged, the cone of reflected rays and their point of convergence being rendered clearly visible by the dust always floating in the air. Placing between the luminous focus and the source of rays our solution of iodine, the light of the cone is entirely cut away; but the intolerable heat experienced when the band is placed, even for a moment, at the dark focus, shows that the calorific rays pass unimpeded through the opaque solution.

Almost anything that ordinary fire can effect may be accomplished at the focus of invisible rays; the air at the focus remaining at the same time perfectly cold, on account of its transparency to the heat-rays. An air thermometer, with a hollow rack-salt bulb, would be unaffected by the heat of the focus: there would be no expansion, and in the open air there is no convection. The aether at the focus, and not the air, is the substance in which the heat is embodied. A block of wood, placed at the focus, absorbs the heat, and dense volumes of smoke rise swiftly upwards, showing the manner in which the air itself would rise, if the invisible rays were competent to heat it. At the perfectly dark focus dry paper is instantly inflamed: chips of wood are speedily burnt up: lead, tin, and zinc are fused: and disks of charred paper are raised to vivid incandescence. It might be supposed that the obscure rays would show no preference for black over white; but they do show a preference, and to obtain rapid combustion, the body, if not already black, ought to be blackened. When metals are to be burned, it is necessary to blacken or otherwise tarnish them, so as to diminish their reflective power. Blackened zinc foil, when brought into the focus of invisible rays, is instantly caused to blaze, and burns with its peculiar purple light. Magnesium wire flattened, or tarnished magnesium ribbon, also bursts into flame. Pieces of charcoal suspended in a receiver full of oxygen are also set on fire when the invisible focus falls upon them; the dark rays after having passed through the receiver, still possessing sufficient power to ignite the charcoal, and thus initiate the attack of the oxygen. If, instead of being plunged in oxygen, the charcoal be suspended in vacuo, it immediately glows at the place where the focus falls.

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8. Transmutation of Rays: Calorescence.

Eminent experimenters were long occupied in demonstrating the substantial identity of light and radiant heat, and we have now the means of offering a new and striking proof of this identity. A concave mirror produces, beyond the object which it reflects, an inverted and magnified image of the object. Withdrawing, for example, our iodine solution, an intensely luminous inverted image of the carbon points of the electric light is formed at the focus of the mirror employed in the foregoing experiments. When the solution is interposed, and the light is cut away, what becomes of this image? It disappears from sight; but an invisible thermograph remains, and it is only the peculiar constitution of our eyes that disqualifies us from seeing the picture formed by the calorific rays. Falling on white paper, the image chars itself out: falling on black paper, two holes are pierced in it, corresponding to the images of the two coke points: but falling on a thin plate of carbon in vacuo, or upon a thin sheet of platinised platinum, either in vacuo or in air, radiant heat is converted into light, and the image stamps itself in vivid incandescence upon both the carbon and the metal. Results similar to those obtained with the electric light have also been obtained with the invisible rays of the lime-light and of the sun.

Before a Cambridge audience it is hardly necessary to refer to the excellent researches of Professor Stokes at the opposite end of the spectrum. The above results constitute a kind of complement to his discoveries. Professor Stokes named the phenomena which he has discovered and investigated Fluorescence; for the new phenomena here described I have proposed the term Calorescence. He, by the interposition of a proper medium, so lowered the refrangibility of the ultraviolet rays of the spectrum as to render them visible. Here, by the interposition of the platinum foil, the refrangibility of the ultra-red rays is so exalted as to render them visible. Looking through a prism at the incandescent image of the carbon points, the light of the image is decomposed, and a complete spectrum is obtained. The invisible rays of the electric light, remoulded by the atoms of the platinum, shine thus visibly forth; ultra-red rays being converted into red, orange, yellow, green, blue, indigo, violet, and ultraviolet ones. Could we, moreover, raise the original source of rays to a sufficiently high temperature, we might not only obtain from the dark rays of such a source a single incandescent image, but from the dark rays of this image we might obtain a second one, from the dark rays of the second a third, and so on--a series of complete images and spectra being thus extracted from the invisible emission of the primitive source. [Footnote: On investigating the calorescence produced by rays transmitted through glasses of various colours, it was found that in the case of certain specimens of blue glass, the platinum foil glowed with a pink or purplish light. The effect was not subjective, and considerations of obvious interest are suggested by it. Different kinds of black glass differ notably as to their power of transmitting radiant heat. When thin, some descriptions tint the sun with a greenish hue: others make it appear a glowing red without any trace of green. The latter are far more diathermic than the former. In fact, carbon when perfectly dissolved and incorporated with a good white glass, is highly transparent to the calorific rays, and by employing it as an absorbent the phenomena of 'calorescence' may be obtained, though in a less striking form than with the iodine. The black glass chosen for thermometers, and intended to absorb completely the solar heat, may entirely fail in this object, if the glass in which the carbon is incorporated be colourless. To render the bulb of a thermometer a perfect absorbent, the glass ought in the first instance to be green. Soon after the discovery of fluorescence the late Dr. William Allen Miller pointed to the lime-light as an illustration of exalted refrangibility. Direct experiments have since entirely confirmed the view expressed at page 210 of his work on 'Chemistry,' published in 1855.]

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9. Deadness of the Optic Nerve to the Calorific Rays.

The layer of iodine used in the foregoing experiments intercepted the rays of the noonday sun. No trace of light from the electric lamp was visible in the darkest room, even when a white screen was placed at the focus of the mirror employed to concentrate the light. It was thought, however, that if the retina itself were brought into the focus the sensation of light might be experienced. The danger of this experiment was twofold. If the dark rays were absorbed in a high degree by the humours of the eye the albumen of the humours might coagulate along the line of the rays. If, on the contrary, no such high absorption took place, the rays might reach the retina with a force sufficient to destroy it. To test the likelihood of these results, experiments were made on water and on a solution of alum, and they showed it to be very improbable that in the brief time requisite for an experiment any serious damage could be done. The eye was therefore caused to approach the dark focus, no defence, in the first instance, being provided; but the heat, acting upon the parts surrounding the pupil, could not be borne. An aperture was therefore pierced in a plate of metal, and the eye, placed behind the aperture, was caused to approach the point of convergence of invisible rays. The focus was attained, first by the pupil and afterwards by the retina. Removing the eye, but permitting the plate of metal to remain, a sheet of platinum foil was placed in the position occupied by the retina a moment before. The platinum became red-hot. No sensible damage was done to the eye by this experiment; no impression of light was produced; the optic nerve was not even conscious of heat.

But the humours of the eye are known to be highly impervious to the invisible calorific rays, and the question therefore arises, 'Did the radiation in the foregoing experiment reach the retina at all?' The answer is, that the rays were in part transmitted to the retina, and in part absorbed by the humours. Experiments on the eye of an ox showed that the proportion of obscure rays which reached the retina amounted to 18 per cent. of the total radiation; while the luminous emission from the electric light amounts to no more than 10 per cent. of the same total. Were the purely luminous rays of the electric lamp converged by our mirror to a focus, there can be no doubt as to the fate of a retina placed there. Its ruin would be inevitable; and yet this would be accomplished by an amount of wave-motion but little more than half of that which the retina, without exciting consciousness, bears at the focus of invisible rays.

This subject will repay a moment's further attention. At a common distance of a foot the visible radiation of the electric light employed in these experiments is 800 times the light of a candle. At the same distance, the portion of the radiation of the electric light which reaches the retina, but fails to excite vision, is about 1,500 times the luminous radiation of the candle. [Footnote: It will be borne in mind that the heat which any ray, luminous or non-luminous, is competent to generate is the true measure of the energy of the ray.] But a candle on a clear night can readily be seen at a distance of a mile, its light at this distance being less than 1/20,000,000 of its light at the distance of a foot.

Hence, to make the candle-light a mile off equal in power to the non-luminous radiation received from the electric light at a foot distance, its intensity would have to be multiplied by 1,500 x 20,000,000, or by thirty thousand millions. Thus the thirty thousand millionth part of the invisible radiation from the electric light, received by the retina at the distance of a foot, would, if slightly changed in character, be amply sufficient to provoke vision. Nothing could more forcibly illustrate that special relationship supposed by Melloni and others to subsist between the optic nerve and the oscillating periods of luminous bodies. The optic nerve responds, as it were, to the waves with which it is in consonance, while it refuses to be excited by others of almost infinitely greater energy, whose periods of recurrence are not in unison with its own.

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10. Persistence of Rays.

At an early part of this lecture it was affirmed, that when a platinum wire was, gradually raised to a state of high incandescence, new rays were constantly added, while the intensity of the old ones was increased. Thus, in Dr. Draper's experiments, the rise of temperature that generated the orange, yellow, green, and blue augmented the intensity of the red. What is true of the red is true of every other ray of the spectrum, visible and invisible. We cannot indeed see the augmentation of intensity in the region beyond the red, but we can measure it and express it numerically. With this view the following experiment was performed: A spiral of platinum wire was surrounded by a small glass globe to protect it from currents of air; through an orifice in the globe the rays could pass from the spiral and fall afterwards upon a thermo-electric pile. Placing in front of the orifice an opaque solution of iodine, the platinum was gradually raised from a low dark heat to the fullest incandescence, with the following results:

Appearance of spiral Energy of obscure radiation