Part 7

The word 'atoms' has been more than once employed in this discourse. Chemists have taught us that all matter is reducible to certain elementary forms to which they give this name. These atoms are endowed with powers of mutual attraction, and under suitable circumstances they coalesce to form compounds. Thus oxygen and hydrogen are elements when separate, or merely mixed, but they may be made to combine so as to form molecules, each consisting of two atoms of hydrogen and one of oxygen. In this condition they constitute water. So also chlorine and sodium are elements, the former a pungent gas, the latter a soft metal; and they unite together to form chloride of sodium or common salt. In the same way the element nitrogen combines with hydrogen, in the proportion of one atom of the former to three of the latter, to form ammonia. Picturing in imagination the atoms of elementary bodies as little spheres, the molecules of compound bodies must be pictured as groups of such spheres. This is the atomic theory as Dalton conceived it. Now if this theory have any foundation in fact, and if the theory of an aether pervading space, and constituting the vehicle of atomic motion, be founded in fact, it is surely of interest to examine whether the vibrations of elementary bodies are modified by the act of combination--whether as regards radiation and absorption, or, in other words, whether as regards the communication of motion to the aether, and the acceptance of motion from it, the deportment of the uncombined atoms will be different from that of the combined.

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4. Absorption of Radiant Heat by Gases.

We have now to submit these considerations to the only test by which they can be tried, namely, that of experiment. An experiment is well defined as a question put to Nature; but, to avoid the risk of asking amiss, we ought to purify the question from all adjuncts which do not necessarily belong to it. Matter has been shown to be composed of elementary constituents, by the compounding of which all its varieties are produced. But, besides the chemical unions which they form, both elementary and compound bodies can unite in another and less intimate way. Gases and vapours aggregate to liquids and solids, without any change of their chemical nature. We do not yet know how the transmission of radiant heat may be affected by the entanglement due to cohesion; and, as our object now is to examine the influence of chemical union alone, we shall render our experiments more pure by liberating the atoms and molecules entirely from the bonds of cohesion, and employing them in the gaseous or vaporous form.

Let us endeavour to obtain a perfectly clear mental image of the problem now before us. Limiting in the first place our enquiries to the phenomena of absorption, we have to picture a succession of waves issuing from a radiant source and passing through a gas; some of them striking against the gaseous molecules and yielding up their motion to the latter; others gliding round the molecules, or passing through the intermolecular spaces without apparent hindrance. The problem before us is to determine whether such free molecules have any power whatever to stop the waves of heat; and if so, whether different molecules possess this power in different degrees.

In examining the problem let us fall back upon an actual piece of work, choosing as the source of our heat-waves a plate of copper, against the back of which a steady sheet of flame is permitted to play. On emerging from the copper, the waves, in the first instance, pass through a space devoid of air, and then enter a hollow glass cylinder, three feet long and three inches wide. The two ends of this cylinder are stopped by two plates of rock-salt, a solid substance which offers a scarcely sensible obstacle to the passage of the calorific waves. After passing through the tube, the radiant heat falls upon the anterior face of a thermo-electric pile, [Footnote: In the Appendix to the first chapter of 'Heat as a Mode of Motion,' the construction of the thermo-electric pile is fully explained.] which instantly converts the heat into an electric current. This current conducted round a magnetic needle deflects it, and the magnitude of the deflection is a measure of the heat falling upon the pile. This famous instrument, and not an ordinary thermometer, is what we shall use in these enquiries, but we shall use it in a somewhat novel way. As long as the two opposite faces of the thermo-electric pile are kept at the same temperature, no matter how high that may be, there is no current generated. The current is a consequence of a difference of temperature between the two opposite faces of the pile. Hence, if after the anterior face has received the heat from our radiating source, a second source, which we may call the compensating source, be permitted to radiate against the posterior face, this latter radiation will tend to neutralise the former. When the neutralisation is perfect, the magnetic needle connected with the pile is no longer deflected, but points to the zero of the graduated circle over which it hangs.

And now let us suppose the glass tube, through which the waves from the heated plate of copper are passing, to be exhausted by an air-pump, the two sources of heat acting at the same time on the two opposite faces of the pile. When by means of an adjusting screen, perfectly equal quantities of heat are imparted to the two faces, the needle points to zero. Let any gas be now permitted to enter the exhausted tube; if its molecules possess any power of intercepting the calorific waves, the equilibrium previously existing will be destroyed, the compensating source will triumph, and a deflection of the magnetic needle will be the immediate consequence. From the deflections thus produced by different gases, we can readily deduce the relative amounts of wave-motion which their molecules intercept.

In this way the substances mentioned in the following table were examined, a small portion only of each being admitted into the glass tube. The quantity admitted in each case was just sufficient to depress a column of mercury associated with the tube one inch: in other words, the gases were examined at a pressure of one-thirtieth of an atmosphere. The numbers in the table express the relative amounts of wave-motion absorbed by the respective gases, the quantity intercepted by air being taken as unity.

Radiation through Gases.

Name of gas Relative absorption

Air 1

Oxygen 1

Nitrogen 1

Hydrogen 1

Carbonic oxide 750

Carbonic acid 972

Hydrochloric acid. 1,005

Nitric oxide 1,590

Nitrous oxide 1,860

Sulphide of hydrogen 2,100

Ammonia 5,460

Olefiant gas 6,030

Sulphurous acid 6,480

Every gas in this table is perfectly transparent to light, that is to say, all waves within the limits of the visible spectrum pass through it without obstruction; but for the waves of slower period, emanating from our heated plate of copper, enormous differences of absorptive power are manifested. These differences illustrate in the most unexpected manner the influence of chemical combination. Thus the elementary gases, oxygen, hydrogen, and nitrogen, and the mixture atmospheric air, prove to be practical vacua to the rays of heat; for every ray, or, more strictly speaking, for every unit of wave-motion, which any one of them intercepts, perfectly transparent ammonia intercepts 5,460 units, olefiant gas 6,030 units, while sulphurous acid gas absorbs 6,480 units. What, becomes of the wave-motion thus intercepted? It is applied to the heating of the absorbing gas. Through air, oxygen, hydrogen, and nitrogen, the waves of aether pass without absorption, and these gases are not sensibly changed in temperature by the most powerful calorific rays. The position of nitrous oxide in the foregoing table is worthy of particular notice. In this gas we have the same atoms in a state of chemical union, that exist uncombined in the atmosphere; but the absorption of the compound is 1,800 times that of air.

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5. Formation of Invisible Foci.

This extraordinary deportment of the elementary gases naturally directed attention to elementary bodies in other states of aggregation. Some of Melloni's results now attained a new significance. This celebrated experimenter had found crystals of sulphur to be highly pervious to radiant heat; he had also proved that lamp-black, and black glass, (which owes its blackness to the element carbon) were to a considerable extent transparent to calorific rays of low refrangibility. These facts, harmonising so strikingly with the deportment of the simple gases, suggested further enquiry. Sulphur dissolved in bisulphide of carbon was found almost perfectly diathermic. The dense and deeply-coloured element bromine was examined, and found competent to cut off the light of our most brilliant flames, while it transmitted the invisible calorific rays with extreme freedom. Iodine, the companion element of bromine, was next thought of, but it was found impracticable to examine the substance in its usual solid condition. It however dissolves freely in bisulphide of carbon. There is no chemical union between the liquid and the iodine; it is simply a case of solution, in which the uncombined atoms of the element can act upon the radiant heat. When permitted to do so, it was found that a layer of dissolved iodine, sufficiently opaque to cut off the light of the midday sun, was almost absolutely transparent to the invisible calorific rays. [Footnote: Professor Dewar has recently succeeded in producing a medium highly opaque to light, and highly transparent to obscure heat, by fusing together sulphur and iodine.]

By prismatic analysis Sir William Herschel separated the luminous from the non-luminous rays of the sun, and he also sought to render the obscure rays visible by concentration. Intercepting the luminous portion of his spectrum he brought, by a converging lens, the ultra-red rays to a focus, but by this condensation he obtained no light. The solution of iodine offers a means of filtering the solar beam, or failing it, the beam of the electric lamp, which renders attainable far more powerful foci of invisible rays than could possibly be obtained by the method of Sir William Herschel. For to form his spectrum he was obliged to operate upon solar light which had passed through a narrow slit or through a small aperture, the amount of the obscure heat being limited by this circumstance. But with our opaque solution we may employ the entire surface of the largest lens, and having thus converged the rays, luminous and non-luminous, we can intercept the former by the iodine, and do what we please with the latter. Experiments of this character, not only with the iodine solution, but also with black glass and layers of lampblack, were publicly performed at the Royal Institution in the early part of 1862, and the effects at the foci of invisible rays, then obtained, were such as had never been witnessed previously.