Part 21

The sun's disk is much less bright near the margin than near the centre, a point on the limb of the sun being only about a fourth as bright as one near the centre of the disk. This diminution of brightness towards the margin of the disk is due to the increase in the absorption of the solar atmosphere as we pass from the centre towards the margin of the sun's disk; and this increased absorption is due to the fact, that the rays which reach us from near the margin have to traverse a much greater thickness of the solar atmosphere than those which reach us from the centre of the disk. This will be evident from Fig. 162, in which the arrows mark the paths of rays from different parts of the solar disk.

The Spectroscope.

147. The Spectroscope as an Astronomical Instrument.--The spectroscope is now continually employed in the study of the physical condition and chemical constitution of the sun and of the other heavenly bodies. It has become almost as indispensable to the astronomer as the telescope.

148. The Dispersion Spectroscope.--The essential parts of the dispersion spectroscope are shown in Fig. 163. These are the collimator tube, the prism, and the telescope. The collimator tube has a narrow slit at one end, through which the light to be examined is admitted, and somewhere within the tube a lens for condensing the light. The light is dispersed on passing through the prism: it then passes through the objective of the telescope, and forms within the tube an image of the spectrum, which is examined by means of the eye-piece. The power of the spectroscope is increased by increasing the number of prisms, which are arranged so that the light shall pass through one after another in succession. Such an arrangement of prisms is shown in Fig. 164. One end of the collimator tube is seen at the left, and one end of the telescope at the right. Sometimes the prisms are made long, and the light is sent twice through the same train of prisms, once through the lower, and once through the upper, half of the prisms. This is accomplished by placing a rectangular prism against the last prism of the train, as shown in Fig. 165.

149. The Micrometer Scale.--Various devices are employed to obtain an image of a micrometer scale in the tube of the telescope beside that of the spectrum.

One of the simplest of these methods is shown in Fig. 166. A is the telescope, B the collimator, and C the micrometer tube. The opening at the outer end of C contains a piece of glass which has a micrometer scale marked upon it. The light from the candle shines through this glass, falls upon the surface of the prism P, and is thence reflected into the telescope, where it forms an enlarged image of the micrometer scale alongside the image of the spectrum.

150. The Comparison of Spectra.--In order to compare two spectra, it is desirable to be able to see them side by side in the telescope. The images of two spectra may be obtained side by side in the telescope tube by the use of a little rectangular prism, which covers one-half of the slit of the collimator tube, as shown in Fig. 167. The light from one source is admitted directly through the uncovered half of the slit, while the light from the other source is sent through the covered portion of the slit by reflection from the surface of the rectangular prism. This arrangement and its action will be readily understood from Fig. 167.

151. Direct-Vision Spectroscope.--A beam of light may be dispersed, without any ultimate deflection from its course, by combining prisms of crown and flint glass with equal refractive, but unequal dispersive powers. Such a combination of prisms is called a direct-vision combination. One of three prisms is shown in Fig. 168, and one of five prisms in Fig. 169.

A direct-vision spectroscope (Fig. 170) is one in which a direct-vision combination of prisms is employed. C is the collimator tube, P the train of prisms, F the telescope, and r the comparison prism.

152. The Telespectroscope.--The spectroscope, when used for astronomical work, is usually combined with a telescope. The compound instrument is called a telespectroscope. The spectroscope is mounted at the end of the telescope in such a way that the image formed by the object-glass of the telescope falls upon the slit at the end of the collimator tube. A telespectroscope of small dispersive power is shown in Fig. 171; a being the object-glass of the telescope, cc the tube of the telescope, and e the comparison prism at the end of the collimator tube. A more powerful instrument is shown in Fig. 172. A is the telescope, C the collimator tube of the spectroscope, P the train of prisms, and E the telescope tube. Fig. 173 shows a still more powerful spectroscope attached to the great Newall refractor (18).

153. The Diffraction Spectroscope.--A diffraction spectroscope is one in which the spectrum is produced by reflection of the light from a finely ruled surface, or grating, as it is called, instead of by dispersion in passing through a prism. The essential parts of this instrument are shown in Fig 174. This spectroscope may be attached to the telescope in the same manner as the dispersion spectroscope. When the spectroscope is thus used, the eye-piece of the telescope is removed.

Spectra.

154. Continuous Spectra.--Light from an incandescent solid or liquid which has suffered no absorption in the medium which it has traversed gives a spectrum consisting of a continuous colored band, in which the colors, from the red to the violet, pass gradually and imperceptibly into one another. The spectrum is entirely free from either light or dark lines, and is called a continuous spectrum.

155. Bright-Lined Spectra.--Light from a luminous gas or vapor gives a spectrum composed of bright lines separated by dark spaces, and known as a bright-lined spectrum. It has been found that the lines in the spectrum of a substance in the state of a gas or vapor are the most characteristic thing about the substance, since no two vapors give exactly the same lines: hence, when we have once become acquainted with the bright-lined spectrum of any substance, we can ever after recognize that substance by the spectrum of its luminous vapor. Even when several substances are mixed, they may all be recognized by the bright-lined spectrum of the mixture, since the lines of all the substances will be present in the spectrum of the mixture. This method of identifying substances by their spectra is called spectrum analysis.

The bright-lined spectra of several substances are given in the frontispiece. The number of lines in the spectra of the elements varies greatly. The spectrum of sodium is one of the simplest, while that of iron is one of the most complex. The latter contains over six hundred lines. Though no two vapors give identical spectra, there are many cases in which one or more of the spectral lines of one element coincide in position with lines of other elements.

156. Methods of rendering Gases and Vapors Luminous.--In order to study the spectra of vapors and gases it is necessary to have some means of converting solids and liquids into vapor, and also of rendering the vapors and gases luminous. There are four methods of obtaining luminous vapors and gases in common use.

(1) By means of the Bunsen Flame.--This is a very hot but an almost non-luminous flame. If any readily volatilized substance, such as the compounds of sodium, calcium, strontium, etc., is introduced into this flame on a fine platinum wire, it is volatilized in the flame, and its vapor is rendered luminous, giving the flame its own peculiar color. The flame thus colored may be examined by the spectroscope. The arrangement of the flame is shown in Fig. 175.

(2) By means of the Voltaic Arc.--An electric lamp is shown in Fig. 176. When this lamp is to be used for obtaining luminous vapors, the lower carbon is made larger than the upper one, and hollowed out at the top into a little cup. The substance to be volatilized is placed in this cup, and the current is allowed to pass. The heat of the voltaic arc is much more intense than that of the Bunsen flame: hence substances that cannot be volatilized in the flame are readily volatilized in the arc, and the vapor formed is raised to a very high temperature.

(3) By means of the Spark from an Induction Coil.--The arrangement of the coil for obtaining luminous vapors is shown in Fig. 177.

The terminals of the coil between which the spark is to pass are brought quite close together. When we wish to vaporize any metal, as iron, the terminals are made of iron. On the passage of the spark, a little of the iron at the ends of the terminals is evaporated; and the vapor is rendered luminous in the space traversed by the spark. A condenser is usually placed in the circuit. With the coil, the temperature may be varied at pleasure; and the vapor may be raised even to a higher temperature than with the electric lamp. To obtain a low temperature, the coil is used without the condenser. By using a larger and larger condenser, the temperature may be raised higher and higher.

By means of the induction coil we may also heat gases to incandescence. It is only necessary to allow the spark to pass through a space filled with the gas.

(4) By means of a Vacuum Tube.--The form of the vacuum tube commonly used for this purpose is shown in Fig. 178. The gas to be examined, and which is contained in the tube, has very slight density: but upon the passage of the discharge from an induction coil or a Holtz machine, through the tube, the gas in the capillary part of the tube becomes heated to a high temperature, and is then quite brilliant.

157. Reversed Spectra.--If the light from an incandescent cylinder of lime, or from the incandescent point of an electric lamp, is allowed to pass through luminous sodium vapor, and is then examined with a spectroscope, the spectrum will be found to be a bright spectrum crossed by a single dark line in the position of the yellow line of the sodium vapor. The spectrum of sodium vapor is reversed, its bright lines becoming dark and its dark spaces bright. With a spectroscope of any considerable power, the yellow line of sodium vapor is resolved into a double line. With a spectroscope of the same power, the dark sodium line of the reversed spectrum is seen to be a double line.

It is found to be generally true, that the spectrum of the light from an incandescent solid or liquid which has passed through a luminous vapor on its way to the spectroscope is made up of a bright ground crossed by dark lines; there being a dark line for every bright line that the vapor alone would give.

158. Explanation of Reversed Spectra.--It has been found that gases absorb and quench rays of the same degree of refrangibility as those which they themselves emit, and no others. When a solid is shining through a luminous vapor, this absorbs and quenches those rays from the solid which have the same degrees of refrangibility as those which it is itself emitting: hence the lines of the spectrum receive light from the vapor alone, while the spaces between the lines receive light from the solid. Now, solids and liquids, when heated to incandescence, give a very much brighter light than vapors and gases at the same temperature: hence the lines of a reversed spectrum, though receiving light from the vapor or gas, appear dark by contrast.

159. Effect of Increasing the Power of the Spectroscope upon the Brilliancy of a Spectrum.--An increase in the power of a spectroscope diminishes the brilliancy of a continuous spectrum, since it makes the colored band longer, and therefore spreads the light out over a greater extent of surface; but, in the case of a bright-lined spectrum, an increase of power in the spectroscope produces scarcely any alteration in the brilliancy of the lines, since it merely separates the lines farther without making the lines themselves any wider. In the case of a reversed spectrum, an increase of power in the spectroscope dilutes the light in the spaces between the lines without diluting that of the lines: hence lines which appear dark in a spectroscope of slight dispersive power may appear bright in an instrument of great dispersive power.

160. Change of the Spectrum with the Density of the Luminous Vapor.--It has been found, that, as the density of a luminous vapor is diminished, the lines in its spectrum become fewer and fewer, till they are finally reduced to one. On the other hand, an increase of density causes new lines to appear in the spectrum, and the old lines to become thicker.

161. Change of the Spectrum with the Temperature of the Luminous Vapor.--It has also been found that the appearance of a bright-lined spectrum changes considerably with the temperature of the luminous vapor. In some cases, an increase of temperature changes the relative intensities of the lines; in other cases, it causes new lines to appear, and old lines to disappear.