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Chapter Iv., and in the Account of the Volcanic Series of Carboniferous

The Ancient Volcanoes of Great Britain, Volume 1 (of 2) · Archibald Geikie — chapter 19 of 45 · ~8,394 words · public domain

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age in Central Scotland, where a basic lava can sometimes be proved to be a true flow and not an intrusive sill by the fact that portions of its upper slaggy surface are enclosed in overlying sandstone, shale or limestone.

2. The presence of GLASS, or of some result of the devitrification of an original glass, is an indication that the rock which exhibits it has once been in a state of fusion. Even where no trace of the original vitreous condition may remain, stages in its devitrification, that is, in its conversion into a stony or lithoid condition, may be traceable. Thus what are called spherulitic and perlitic structures (which will be immediately described), either visible to the naked eye or only observable with the aid of the microscope, afford evidence of the consolidation and conversion of a glassy into a lithoid substance.

Striking evidence of the former glassy, and therefore molten, condition of many rocks now lithoid is to be gained by the examination of thin slices of them under the microscope. Not only are vestiges of the original glass recognizable, but the whole progress of devitrification may be followed into a crystalline structure. The primitive crystallites or microlites of different minerals may be seen to have grouped themselves together into more or less perfect crystals, while scattered crystals of earlier consolidation have been partially dissolved in and corroded by the molten glass. These and other characteristics of once fused rocks have to a considerable extent been imitated artificially by MM. Fouqué and Michel Lévy, who have fused the constituent minerals in the proper proportions.

Since traces of glass or of its representative devitrified structures are so abundantly discoverable in lavas, we may infer the original condition of most lavas to have been vitreous. Where, for instance, the outer selvages of a basic dyke or sill are coated with a layer of black glass which rapidly passes into a fine-grained crystalline basalt, and then again into a more largely crystalline or doleritic texture in the centre, there can be no hesitation in believing that glassy coating to be due to the sudden chilling and consolidation of the lava injected between the cool rocks that enclose it. The part that solidified first may be regarded as probably representing the condition of the whole body of lava at the time of intrusion. The lithoid or crystalline portion between the two vitreous outer layers shows the condition which the molten rock finally assumed as it cooled more slowly.

Some lavas, such as obsidians and pitchstones, have consolidated in the glassy form. More usually, however, a lithoid structure has been developed, the original glass being only discoverable by the microscope, and often not even by its aid. Two varieties of devitrification may be observed among lavas, which, though not marked off from each other by any sharp lines, are on the whole distinctive of the two great groups of acid and basic rocks.

(1) Among the acid rocks, what is called the Felsitic type of devitrification is characteristic. Thus, obsidians pass by intermediate stages from a clear transparent or translucent glass into a dull flinty or horny mass. When thin slices of these transitional forms are examined under the microscope, minute hairs and fibres or trichites, which may be observed even in the most perfectly glassy rocks, are seen to increase in number until they entirely take the place of the glass. Microlites of definite minerals may likewise be observed, together with indefinite granules, and the rock finally becomes a rhyolite, felsite or allied variety (Fig. 3).

At the same time it should be observed that, even in the vitreous condition of a lava, definite crystals of an early consolidation were generally already present. Felspars and quartz, usually in large porphyritic forms, may be seen in the glass, often so corroded as to indicate that they were in course of being dissolved in the magma at the time of the cooling and solidification of the mass. In obsidians and pitchstones such relics of an earlier or derived series of crystallized minerals may often be recognized, while in felsites and quartz-porphyries they are equally prominent. Where large dispersed crystals form a prominent characteristic in a rock they give rise to what is termed the Porphyritic structure.

Accompanying the passage of glass into stone, various structures make their appearance, sometimes distinctly visible to the naked eye, at other times only perceptible with the aid of the microscope. One of these structures, known as Perlitic (Fig. 4), consists in the formation of minute curved or straight cracks between which the vitreous or felsitic substance, during its contraction in cooling, assumed a finely globular form.

Another structure, termed Spherulitic (Fig. 5), shows the development of globules or spherules which may range from grains of microscopic minuteness up to balls two inches or more in diameter. These not infrequently present a well-formed internal fibrous radiation, which gives a black cross between crossed Nicol prisms. Spherulites are more especially developed along the margins of intrusive rocks, and may be found in dykes, sills and bosses (see Figs. 375 and 377). Where the injected mass is not thick it may be spherulitic to the very centre, as can be seen among the felsitic and granophyric dykes of Skye.

Some felsitic lavas possess a peculiar nodular structure, which was developed during the process of consolidation. So marked does this arrangement sometimes become that the rocks which display it have actually been mistaken for conglomerates. It is well exhibited among the Lower Silurian lavas of Snowdon, the Upper Silurian lavas of Dingle, and the Lower Old Red Sandstone lavas near Killarney.

A marked structure among some intrusive rocks, especially of an acid composition, is that called Micropegmatitic or Granophyric. It consists in a minute intergrowth of two component minerals, especially quartz and felspar, and is more especially characteristic of certain granitic or granitoid rocks which have consolidated at some distance from the surface and occur as bosses, sills and dykes. It is also met with, however, in some basic sills. Examples of all these and other structures will occur in the course of the following description of British volcanic rocks.

(2) The second type of devitrification, conspicuous in rocks of more basic composition, is marked by a more complete development of crystallization. Among basic, as among acid rocks, there are proofs of the consolidation of definite minerals at more than one period. Where the molten material has suddenly cooled into a black glass, porphyritic felspars or other minerals are often to be seen which were already floating in the magma in its molten condition. During devitrification, however, other felspars of a later period of generation made their appearance, but they are generally distinguishable from their predecessors. Probably most basic and intermediate rocks, when poured out at the surface as lavas, were no longer mere vitreous material, but had already advanced to various stages of progress towards a stony condition. These stages are still to some extent traceable by the aid of the microscope.

Microlites of the component minerals are first developed, which, if the process of aggregation is not arrested, build up more or less perfect crystals or crystalline grains of the minerals. Eventually the glass may be so completely devitrified by the development of its constituent minerals as to be wholly used up, the rock then becoming entirely crystalline, or to survive only in scanty interstitial spaces. In the family of the basalts and dolerites the gradual transition from a true glass into a holocrystalline compound may be followed with admirable clearness. The component minerals have sometimes crystallized in their own distinct crystallographic forms (idiomorphic); in other cases, though thoroughly crystalline, they have assumed externally different irregular shapes, fitting into each other without their Proper geometric boundaries (allotriomorphic).

A specially characteristic feature of many basic rocks is the presence of what is termed an Ophitic structure (Fig. 7). Thus the component crystals of pyroxene occur as large plates separated and penetrated by small needles and crystals of felspar. The portions of pyroxene, divided by the enclosed felspar, are seen under the microscope to be in optical continuity, and to have crystallized round the already formed felspar. This structure is never found in metamorphic crystalline rocks. It has been reproduced artificially from fusion by Messrs. Fouqué and Michel Lévy.

The name Variolitic is applied to another structure of basic rocks (Fig. 8), in which, especially towards the margin of eruptive masses, abundant spheroidal aggregates have been developed from the size of a millet-seed to that of a walnut, imbedded in a fine-grained or compact greenish matrix into which the kernels seem to shade off. These kernels consist of silicates arranged either radially or in concentric zones.

3. Flow-structure is an arrangement of the crystals, vesicles, spherulites, or devitrification-streaks in bands or lines, which sweep round any enclosed object, such as a porphyritic crystal or detached spherulite, and represent the curving flow of a mobile or viscous mass. Admirable examples of this structure may often be observed in old lavas, as well as in dykes and sills, the streaky lines of flow being marked as distinctly as the lines of foam that curve round the boulders projecting from the surface of a mountain-brook.

Flow-structure is most perfectly developed among the obsidians, rhyolites, felsites and other acid rocks, of which it may be said to be a frequently conspicuous character (Fig. 9). In these rocks it is revealed by the parallel arrangement of the minute hair-like bodies and crystals, or by alternate layers of glassy and lithoid material. The streaky lines thus developed are sometimes almost as thin and parallel as the leaves of a book. But they generally show interruptions and curvatures, and may be seen to bend round larger enclosed crystals, or to gather into eddy-like curves, in such a manner as vividly to portray the flow of a viscous substance. These lines represent on a minute scale the same flow-structure which may be traced in large sheets among the lavas. The porphyritic crystals and the spherulites are also drawn out in rows in the same general direction. Sometimes, indeed, the spherulites have been so symmetrically grouped in parallel rows that they appear as rod-like aggregates which extend along the margin of a dyke.

Among lavas of more basic composition flow-structure is not so often well displayed. It most frequently shows itself by the orientation of porphyritic felspars or of lines of steam-vesicles. Occasionally, however, sheets of basalt may be found in which a distinct streakiness has been developed owing to variations in the differentiation of the original molten magma. A remarkable and widespread occurrence of such a structure is met with among the Tertiary basalt-plateaux of the Inner Hebrides and the Faroe Islands. In the lower parts of these thick accumulations of successive lava-sheets, a banded character is so marked as to give the rocks the aspect of truly stratified deposits. The observer, indeed, can hardly undeceive himself as to their real nature until he examines them closely. As a full description of this structure will be given in a later chapter, it may suffice to state here that the banding arises from two causes. In some cellular lavas, the vesicles are arranged in layers which lie parallel with the upper and under surfaces of the sheets. These layers either project as ribs or recede into depressions along the outcrop, and thus impart a distinctly stratified aspect to the rock. More frequently, however, the banded structure is produced by the alternation of different varieties of texture, and even of composition, in the same sheet of basalt. Lenticular seams of olivine-basalt may be found intercalated in a more largely crystalline dolerite. These differences appear to point to considerable variations in the constitution of the magma from which the lavas issued--variations which already existed before the discharge of these lavas, and which showed themselves in the successive outflow of basaltic and doleritic material during the eruption of what was really, as regards its appearance at the surface, one continuous stream of molten rock. It is impossible to account for such variations in the same sheet of lava by any process of differentiation in the melted material during its outflow and cooling. Analogous variations occur among the basic sills and bosses of the Tertiary volcanic series of Britain. These, as will be more fully discussed in later chapters, indicate a considerable amount of heterogeneity in the deep-seated magma from which the intrusive sheets and bosses were supplied (see vol. ii. pp. 329, 342).

It is a common error to assume that flow-structure is a distinctive character of lavas that have flowed out at the surface. In reality some of the most perfect examples of the structure occur in dykes and sills, both among acid and basic rocks. Innumerable instances might be quoted from the British Isles in support of this statement.

Although, in the vast majority of cases, the presence of flow-structure may be confidently assumed to indicate a former molten condition of the rock in which it occurs, it is not an absolutely reliable test for an igneous rock. Experiment has shown that under enormous pressure even solid metals may be made to flow into cavities prepared for their reception. Under the vast compression to which the earth's crust is subjected during terrestrial contraction, the most obdurate rocks are crushed into fragments varying from large blocks to the finest powder. This comminuted material is driven along in the direction of thrust, and when it comes to rest presents a streakiness, with curving lines of flow round the larger fragments, closely simulating the structure of many rhyolites and obsidians. It is only by attention to the local surroundings that such deceptive resemblances can be assigned to their true cause.

4. The DISPOSITION OF LAVAS IN SHEETS OR BEDS is the result of successive outflows of molten rock. Such sheets may range from only a yard or two to several hundred feet in thickness. As a rule, though with many exceptions, the basic lavas, such as the basalts, appear in thinner beds than the acid forms. This difference is well brought out if we compare, for instance, the massive rhyolites or felsites of North Wales with the thin sheets of basalt in Antrim and the Inner Hebrides. The regularity of the bedded character is likewise more definite among the basic than among the acid rocks, and this contrast also is strikingly illustrated by the two series of rocks just referred to. The rhyolites and felsites, sometimes also the trachytes and andesites, assume lumpy, irregular forms, and some little care may be required to trace their upper and under surfaces, and to ascertain that they really do form continuous sheets, though varying much in thickness from place to place (Fig. 10). Like modern acid lavas, they seem to have flowed out in a pasty condition, and to have been heaped up round the vents in the form of domes, or with an irregular hummocky or mounded surface. The basalts, and dolerites, and sometimes the andesites, have issued in a more fluid condition, and have spread out in sheets of more uniform thickness, as may be instructively seen in the sea-cliffs of Antrim, Mull, Skye, and the Faroe Islands, where the horizontal or gently-inclined flows of basalt lie upon each other in even parallel beds traceable for considerable distances along the face of the precipices (Figs. 11, 265, and 286). The andesites of the Old Red Sandstone (Figs. 99, 100) and Carboniferous series (Figs. 107, 108, 111, 112, 113, 123) in Scotland likewise form terraced hills.

The length of a lava-stream may vary within wide limits. Sometimes an outflow of lava has not reached the base of the cone from the side of which it issued, like the obsidian stream on the flanks of the little cone of the island of Volcano. In other cases, the molten rock has flowed for forty or fifty miles, like the copious Icelandic lava-floods of 1783. In the basalt-plateaux of the Inner Hebrides a single sheet may sometimes be traced for several miles.

The island on the left is Borö, that in the centre Viderö, and that on the right Svinö.]

Some lavas, more especially among the basic series, assume in cooling a Columnar structure, of which two types may be noticed. In one of these the columns pass with regularity and parallelism from the top to the bottom of a bed (Figs. 171, 225). The basalt in which Fingal's Cave, in the isle of Staffa, has been hollowed out may be taken as a characteristic example (Fig. 266a). Not infrequently the columns are curved, as at the well-known Clam-shell Cave of Staffa. In the other type, the columns or prisms are not persistent, but die out into each other and have a wavy, irregular shape, somewhat like prisms of starch. These two types may occur in successive sheets of basalt, or may even pass into each other. At Staffa the regularly columnar bed is immediately overlain with one of the starch-like character. The columnar structure in either case is a contraction phenomenon, produced during the cooling and shrinking of the lava. But it is difficult to say what special conditions in the lava were required for its production, or why it should sometimes have assumed the regular, at others the irregular form. It may be found not only in superficial lavas but in equal perfection in some dykes and intrusive sills or injections, as among the Tertiary volcanic rocks of the island of Canna (Figs. 307 and 308).

The precipitation of a lava-stream into a lake or the sea may cause the outer crust of the rock to break up with violence, so that the still molten material inside may rush into the water. Some basic lavas on flowing into water or into a watery silt have assumed a remarkable spheroidal sack-like or pillow-like structure, the spheroids being sometimes pressed into shapes like piles of sacks. A good instance of this structure occurs in a basalt at Acicastello in Sicily. A similar appearance will be described in a later chapter as peculiarly characteristic of certain Lower Silurian lavas associated with radiolarian cherts in Britain and in other countries (Fig. 12).

It probably seldom happens that a solitary sheet of lava occurs among non-volcanic sedimentary strata, with no other indication around it of former volcanic activity. Such an isolated record does not seem to have been met with in the remarkably ample volcanic register of the British Isles. The outpouring of molten rock has generally been accompanied with the ejection of fragmentary materials. Hence among the memorials of volcanic eruptions, while intercalated lavas are generally associated with sheets of tuff, bands of tuff may not infrequently be encountered in a sedimentary series without any lava. Instances in illustration of these statements may be culled from the British Palæozoic formations back even into the Cambrian system.

A characteristic feature of some interest in connection with the flow of lava is the effect produced by it on the underlying rocks. If these are not firmly compacted they may be ploughed up or even dislocated. Thus the tuffs of the Velay have sometimes been plicated, inverted, and fractured by the movement of a flowing current of basalt. The great heat of the lava has frequently induced considerable alteration upon the underlying rocks. Induration is the most common result, often accompanied with a reddening of the altered substance. Occasionally a beautifully prismatic structure has been developed in the soft material immediately beneath a basalt, as in ferruginous clay near the village of Esplot in the Velay, in which the close-set columns are 50 centimetres long and 4 to 5 centimetres in diameter. Changes of this nature, however, are more frequent among sills than among superficial lavas. Many examples of them may be gathered from the Scottish Carboniferous districts.

Variations of structure in single lava-sheets.--From what has been said above in regard to certain kinds of flow-structure among basic rocks, it will be evident that some considerable range of chemical, but more particularly of mineralogical, composition may be sometimes observed even within the same sheet of lava. Such differences, it is true, are more frequent among intrusive rocks, especially thick sills and large bosses. But they have been met with in so many instances among superficial lavas as to show that they are the results of some general law, which probably has a wide application among the surface-products of volcanic action. Scrope expressed the opinion that in the focus of a volcano there may be a kind of filtration of the constituents of a molten mass, the heavier minerals sinking through the lighter, so that the upper portions of the mass will become more felspathic and the lower parts more augitic and ferruginous.

Leopold von Buch found that in some of the highly glassy lavas of the Canary Islands the felspar increases towards the bottom of the mass, becoming so abundant as almost to exclude the matrix, and giving rise to a compound that might be mistaken for a primitive rock.

Darwin observed that in a grey basalt filling up the hollow of an old crater in James Island, one of the Galapagos group, the felspar crystals became much more abundant in the lower scoriaceous part, and he discussed the question of the descent of crystals by virtue of their specific gravity through a still molten lava.

Mr. Clarence King during a visit to Hawaii found that in every case where he broke newly-congealed streamlets of lava, "the bottom of the flow was thickly crowded with triclinic felspars and augites, while the whole upper part of the stream was of nearly pure isotropic and acid glass." This subject will be again referred to when we come to discuss the characters of intrusive sills and bosses, for it is among them that the most marked petrographical variations may be observed. Examples will be cited both from the intrusive and extrusive volcanic groups of Britain.

Volcanic cycles.--Closely related to the problem of the range of structure and composition in a single mass of lava is another problem presented by the remarkable sequence of different types of lava which are erupted within a given district during a single volcanic period. Nearly thirty years ago Baron von Richthofen drew attention to the sequence of volcanic materials erupted within the same geographical area. He showed, more especially from observations in Western America, that a definite order of appearance in the successive species of lava could be established, the earliest eruptions consisting of materials of an intermediate or average composition, and those of subsequent outflows becoming on the whole progressively more acid, but finishing by an abrupt transition to a basic type. His sequence was as follows: 1. Propylite; 2. Andesite; 3. Trachyte; 4. Rhyolite; 5. Basalt. This generalisation has been found to hold good over wide regions of the Old World as well as the New. It is not, however, of universal application. Examples are not uncommon of an actual alternation of acid and basic lavas from the same, or at least from adjacent vents. Such an alternation occurs among the Tertiary eruptions of Central France and among those of Old Red Sandstone age in Scotland.

The range of variation in the nature of the eruptive rocks during the whole of a volcanic period in any district may be termed "a volcanic cycle." In Britain, where the records of many volcanic periods have been preserved, a number of such cycles may be studied. In this way the evolution of the subterranean magma during one geological age may be compared with that of another. It will be one of the objects of the following chapters to trace out this evolution in each period where the requisite materials for the purpose are available. We shall find that back to Archæan time a number of distinct cycles may be observed, differing in many respects from each other, but agreeing in the general order of development of the successive eruptions. Leaving these British examples for future consideration, it may be useful to cite here a few from the large series now collected from the European continent and North America.

Among the older rocks of the European continent, Prof. Brögger has shown that in the Christiania district the eruptive rocks which traverse the Cambrian and Silurian formations began with the outburst of basic material such as melaphyre, augite-porphyrite, and gabbro-diabase, having from about 44 to about 52 per cent of silica. These were followed by rocks with a silica-percentage ranging from about 50 to 61, including some characteristic Norwegian rocks, like the rhomben-porphyry. The acidity continued to increase, for in the next series of eruptions the silica-percentage rose to between 60 and 67, the characteristic rock being a quartz-syenite. Then came deep-seated protrusions of highly acid rocks, varieties of granite, containing from 68 to 75 per cent of silica. The youngest eruptive masses in the district show a complete change of character. They are basic dykes (proterobase, diabase, etc.).

The same author institutes a comparison between the post-Silurian eruptive series of Christiania and that of the Triassic system in the Tyrol, and believes that the two cycles closely agree.

During Tertiary time in Central France more than one cycle may be made out in distinct districts. Thus in the Velay, during the Miocene Period, volcanic activity began with the outpouring of basalts, followed successively by trachytes, labradorites and augitic andesites, phonolites and basalts. The Pliocene eruptions showed a reversion to the intermediate types of augitic andesites and trachytes, followed by abundant basalts, which continued to be poured forth in Pleistocene time.

Further north, in Auvergne, where the eruptions come down to a later period, the volcanic sequence appears to have been first a somewhat acid group of lavas (trachytes or domites), followed by a series of basalts, then by andesites and labradorites, the latest outflows again consisting of basalts.

Not less striking is the succession of lavas in the Yellowstone region, as described by Mr. Iddings. The first eruptions consisted of andesites. These were followed by abundant discharges of basalt, succeeded by later outflows of andesite, and of basalt like that previously erupted. After a period of extensive erosion, occupying a prolonged interval of time, volcanic energy was renewed by the eruption of a vast flood of rhyolite, after which came a feebler outflow of basalt that brought the cycle to a close, though geysers and fumaroles show that the volcanic fires are not yet entirely extinguished below.

But not only is there evidence of a remarkable evolution or succession or erupted material within the volcanic cycle of a single geological period. One of the objects of the present work is to bring forward proofs that such cycles have succeeded each other again and again, at widely separated intervals, within the same region. After the completion of a cycle and the relapse of volcanic energy into repose, there has been a renewal of the previous condition of the subterranean magma, giving rise ultimately to a similar succession of erupted materials.

If we are at a loss to account for the changes in the sequence of lavas during a single volcanic cycle, our difficulties are increased when we find that in some way the magma is restored each time to somewhat the same initial condition. Analogies may be traced between the differentiation which has taken place within a plutonic intrusive boss or sill and the sequence of lavas in volcanic cycles. It can be shown that though the original magma that supplied the intrusive mass may be supposed to have had a fairly uniform composition deep down in its reservoir, differentiation set in long before the intrusive mass consolidated, the more basic constituents travelling outwards to the margin and leaving the central parts more acid. If some such process takes place within a lava-reservoir, it may account for a sequence of variations in composition. But this would not meet all the difficulties of the case, nor explain the determining cause of the separation of the constituents within the reservoir of molten rock, whether arising from temperature, specific gravity, or other influence. This subject will be further considered in connection with intrusive Bosses.

Another fact which may be regarded as now well established is the persistence of composition and structure in the lavas of all ages. Notwithstanding the oft-repeated cycles in the character of the magma, the materials erupted to the surface, whether acid or basic, have retained with wonderful uniformity the same fundamental characteristics. No part of the contribution of British geology to the elucidation of the history of volcanic action is of more importance than the evidence which it furnishes for this persistent sameness of the subterranean magma. An artificial line has sometimes been drawn between the volcanic products of Tertiary time and those of earlier ages. But a careful study of the eruptive rocks of Britain shows that no such line of division is based upon any fundamental differences.

The lavas of Palæozoic time have of course been far longer exposed to alterations of every kind than those of the Tertiary periods, and certain superficial distinctions may be made between them. But when these accidental differences are eliminated, we find that the oldest known lavas exhibit the same types of structure and composition that are familiar in those of Tertiary and recent volcanoes. Many illustrations of this statement will be furnished in later chapters. As a particularly striking instance, I may cite here the most ancient and most modern lavas of the Grand Cañon of the Colorado. Mr. Walcott and Mr. Iddings have shown that in the Lower Cambrian, or possibly pre-Cambrian, formations of that great gorge, certain basic lavas were contemporaneously interstratified, which, in spite of their vast antiquity, are only slightly different from the modern basalts that have been poured over the surrounding plateau.

The chief lavas found in Britain.--Of the lavas which have been poured out at the surface within the region of the British Isles, the following varieties are of most frequent occurrence. In the acid series are Rhyolites and Felsites, but the vitreous forms are probably all intrusive. The intermediate series is represented by Trachytes and Andesites (Porphyrites), which range from a glassy to a holocrystalline structure. The basic series includes Dolerites, Diabases, Basalts, Limburgites (or Magma-basalts, containing little or no felspar), and Picrites or other varieties of Peridotites. The intrusive rocks display a greater variety of composition and structure.

ii. VOLCANIC AGGLOMERATES, BRECCIAS AND TUFFS

The coarser fragmentary materials thrown from volcanic vents are known as Agglomerates where they show no definite arrangement, and especially where they actually fill up the old funnels of discharge. When they have accumulated in sheets or strata of angular detritus outside an active vent they are termed Breccias, or if their component stones have been water-worn, Conglomerates. The finer ejected materials may be comprehended under the general name of Tuffs.

Although these various forms of pyroclastic detritus consist as a rule of thoroughly volcanic material, they may include fragments of non-volcanic rocks. This is especially the case among those which represent the earliest explosions of a volcano. The first efforts to establish an eruptive vent lead to the shattering of the terrestrial crust, and the consequent discharge of abundant debris of that crust. The breccias or agglomerates thus produced may contain, indeed, little or no truly volcanic material, but may be made up of fragments of granite, gneiss, sandstone, limestone, shale, or whatever may happen to be the rocks through which the eruptive orifice has been drilled. If the first explosions exhausted the energy of the vent, it may happen that the only discharges from it consisted merely of non-volcanic debris. Examples of this kind have been cited from various old volcanic districts. A striking case occurs at Sepulchre Mountain in the Yellowstone Park, where the lower breccias, the product of the earliest explosions of the Electric Peak volcano, and attaining a thickness of 500 feet, are full of pieces of the Archæan rocks which underlie the younger formations of that district. These non-volcanic stones do not occur among the breccias higher up. Obviously, however, though most abundant at first, pieces of the underlying rocks may reappear in subsequent discharges, wherever by the energy of explosion, fragments are broken from the walls of a volcanic chimney and hurled out of the crater. Illustrations of these features will be given in the account of the British Carboniferous, Permian and Tertiary volcanic rocks.

It will be obvious that where the component materials of such fragmentary accumulations consist entirely of non-volcanic rocks, great caution must be exercised in attributing them to volcanic agency. Two sources of error in such cases may here be pointed out. In the first place, where angular detritus has been precipitated into still water, as, for instance, from a crag or rocky declivity into a lake, a very coarse and tumultuous kind of breccia may be formed. It is conceivable that, in course of time, such a breccia may be buried under ordinary sediments, and may thereby be preserved, while all trace of its parent precipice may have disappeared. The breccia might resemble some true volcanic agglomerates, but the resemblance would be entirely deceptive.

In the second place, notice must be taken of the frequent results of movements within the terrestrial crust, whereby rocks have not only been ruptured but, as already pointed out, have been crushed into fragments. In this way, important masses of breccia or conglomerate have been formed, sometimes running for a number of miles and attaining a breadth of several hundred feet. The stones, often in huge blocks, have been derived from the surrounding rocks, and while sometimes angular, are sometimes well-rounded. They are imbedded in a finer matrix of the same material, and may be scattered promiscuously through the mass, in such a way as to present the closest resemblance to true volcanic breccia. Where the crushed material has included ancient igneous rocks it might deceive even an experienced geologist. Indeed, some rocks which have been mapped and described as volcanic tuffs or agglomerates are now known to be only examples of "crush-conglomerates."

Not only have vast quantities of detritus of non-volcanic rocks been shot forth from volcanic vents, but sometimes enormous solid masses of rock have been brought up by ascending lavas or have been ejected by explosive vapours. Every visitor to the puys of Auvergne will remember the great cliff-like prominence of granite and mica-schist which, as described long ago by Scrope, has been carried up by the trachyte of the Puy Chopine, and forms one of the summits of the dome (Fig. 344). The same phenomenon is observable at the Puy de Montchar, where large blocks of granite have been transported from the underlying platform. Abich has described some remarkable examples in the region of Erzeroum. The huge crater of Palandokän, 9687 feet above the sea contains, in cliff-like projections from its walls as well as scattered over its uneven bottom, great masses of marmorised limestone and alabaster, associated with pieces of the green chloritic schists, serpentines and gabbros of the underlying non-volcanic platform. These rocks, which form an integral part of the structure of the crater, have been carried up by masses of trachydoleritic, andesitic and quartz-trachytic lavas. Examples will be given in a later chapter showing how gigantic blocks of mica-schist and other rocks have been carried many hundred feet upwards and buried among sheets of lava or masses of agglomerates during the Tertiary volcanic period in Britain (Fig. 262).

In the vast majority of cases, the fragmentary substances ejected by ancient volcanic explosions, like those of the present day, have consisted wholly or mainly of material which existed in a molten condition within the earth, and which has been violently expelled to the surface. Such ejected detritus varies from the finest impalpable dust or powder up to huge masses of solid rock. These various materials may come from more than one source. Where a volcanic orifice is blown out through already solidified lavas belonging to previous eruptions, the fragments of these lavas may accumulate within or around the vent, and be gradually consolidated into agglomerate or breccia. Again, explosions within the funnel may break up lava-crusts that have there formed over the cooling upper surface of the column of molten rock. Or the uprising lava in the chimney may be spurted out in lumps of slag and bombs, or may be violently blown out in the form of minute lapilli, or of extremely fine dust and ashes.

Although in theory these several varieties of origin may be discriminated, it is hardly possible always to distinguish them among the products of ancient volcanic action. In the great majority of cases old tuffs, having been originally deposited in water, have undergone a good deal of decomposition, and such early alteration has been aggravated by the subsequent influence of percolating meteoric water.

Where disintegration has not proceeded too far, the finer particles of tuffs may be seen to consist of minute angular pieces of altered glass, or of microlites or crystals, or of some vitreous or semi-vitreous substance, in which such microlites and crystals are enclosed. It has already been stated that the occurrence of glass, or of any substance which has resulted from the devitrification of glass, may be taken as good evidence of former volcanic activity.

Most commonly, especially in the case of tuffs of high antiquity, like those associated with the Palæozoic formations, the fresh glassy and microlitic constituents, so conspicuous in modern volcanic ashes, are hardly to be recognised. The finer dust which no doubt contained these characteristic substances has generally passed into dull, earthy, granular, or structureless material, though here and there, among basic tuffs, remaining as palagonite. In the midst of this decayed matrix, the lapilli of disrupted lavas may endure, but it may be difficult or impossible to decide whether they were derived from the breaking up of older lavas by explosion, or from the blowing out of the lava-crusts within the funnel.

The cellular structure, which we have seen to be a markedly volcanic peculiarity among the lavas, is not less so in their fragments among the agglomerates, breccias and tuffs; indeed it may be said to be eminently characteristic of them. The vesicles in the lapilli, bombs, and blocks are sometimes of large size, as in masses of ejected slag, but they range down to microscopic minuteness. The lapilli of many old tuffs are sometimes so crowded with such minute pores, as to show that they were originally true pumice.

The composition of tuffs must obviously depend upon that of the lavas from which they were derived. But their frequently decayed condition makes it less easy, in their case, to draw definite boundary-lines between varieties. In a group of acid lavas, the tuffs may be expected to be also acid, while among intermediate or basic lavas, the tuffs will generally be found to correspond. There are, however, exceptions to this general rule. As will be afterwards described in detail, abundant felsitic tuffs may be seen among the andesitic lavas of Lower Old Red Sandstone age in Scotland, and rhyolitic tuffs occur also among the Tertiary basalts of Antrim.

As a rule, basic and intermediate tuffs, like the lavas from which they have been derived, are rather more prone to decomposition than the acid varieties. One of their most characteristic features is the presence in them of lapilli of a minutely vesicular pumice, which will be more particularly described in connection with volcanic necks, of which it is a characteristic constituent. Occasional detached crystals of volcanic minerals, either entire or broken, may be detected in them, though perhaps less frequently than in the agglomerates. The earthy matrix is generally greenish in colour, varying into shades of brick-red, purple and brown.

The acid tuffs are, on the whole, paler in colour than the others, sometimes indeed they are white or pale grey, but graduate into tones of hæmatitic red or brown, the varying ferruginous tints being indicative of stages in the oxidation of the iron-bearing constituent minerals. Small rounded lapilli or angular fragments of felsite or rhyolite may be noticed among them, sometimes exhibiting the most perfect flow-structure. As typical examples of such tuffs, I may refer to those of the Pentland Hills, near Edinburgh, and those that lie between the two groups of basalt in Antrim.

Thrown out promiscuously from active vents, the materials that form tuffs arrange themselves, on the whole, according to relative size over the surface on which they come to rest, the largest being generally grouped nearest to the focus of discharge, and the finest extending farthest from it. As the volcanoes of which records have been preserved among the geological formations were chiefly subaqueous, the fragmentary substances, as they fell into water, would naturally be to some extent spread out by the action of currents or waves. They would thus tend to take a more or less distinctly stratified arrangement. Moreover, as during an eruption there might be successive paroxysms of violence in the discharges, coarser and finer detritus would successively fall over the same spot. In this way, rapid alternations of texture would arise (Fig. 13). A little experience will enable the observer to distinguish between such truly volcanic variations and those of ordinary sedimentation, where, for instance, layers of gravel and sand repeatedly alternate. Besides the volcanic nature of the fragments and their non-water-worn forms, he will notice that here and there the larger blocks may be placed on end--a position the reverse of that usual in the disposal of aqueous sediments, but one which is not infrequently assumed by ejected stones, even when they fall through some little depth of water. Further, the occurrence of large pieces of lava, scattered at random through deposits of fine tuff, would lead him to recognize the tumultuous discharges of a volcanic focus, rather than the sorting and sifting action of moving water.

Admirable illustrations of these various characteristics may be gathered in endless number from the Palæozoic volcanic chronicles of Britain. I may especially cite the basin of the Firth of Forth as a classical region for the study of Carboniferous examples.

When the conditions of modern volcanic eruptions are considered, it will be seen that where ejected ashes and stones fall into water, they will there mingle with any ordinary sediment that may be in course of deposition at the time. There will thus be a blending of volcanic and non-volcanic detritus, and the transition between the two may be so insensible that no hard line of demarcation can be drawn. Such intermingling has continually taken place during past ages. One of the first lessons learnt by the geologist, who begins the study of ancient volcanic records, is the necessity of recognizing this gradation of material, and likewise the frequently recurring alternations of true tuff with shale, sandstone, limestone or other entirely non-volcanic detritus (Fig. 14). He soon perceives that such facts as these furnish him with some of the most striking proofs of the reality and progress of former eruptions. The intermingling of much ordinary detritus with the volcanic material may be regarded as indicative either of comparatively feeble activity, or at least of considerable distance from the focus of discharge. It is sometimes possible to trace such intermixtures through gradually augmenting proportions of volcanic dust and stones, until the deposit becomes wholly volcanic in composition, and so coarse in texture as to indicate the proximity of the eruptive vent. On the other hand, the gradual decrease of the volcanic ejections can be followed in the upward sequence of a series of stratified deposits, until the whole material becomes entirely non-volcanic.

The occurrence of thin partings of tuff between ordinary sedimentary strata points to occasional intermittent eruptions of ashes or stones, the vigour and duration of each eruptive interval being roughly indicated by the thickness and coarseness of the volcanic detritus. The pauses in the volcanic activity allowed the deposit of ordinary sediment to proceed unchecked. The nature of such non-volcanic intercalations gives a clue to the physical conditions of sedimentation at the time, while their thickness affords some indication of the relative duration of the periods of volcanic repose.

A little reflection will convince the observer that in such a section as that represented in Fig. 14 the volcanic intercalations must be regarded as a mere local accident. Evidently the normal conditions of sedimentation at the time these strata were accumulated are indicated by the limestone bands (l, l). Had there been no volcanic eruptions, a continuous mass of limestone would have been deposited, but this continuity was from time to time interrupted by the explosions that gave rise to the intercalated bands of tuff (t, t).

The application of these rules of geological evidence will be best understood from actual examples of their use. Many illustrations of them will be subsequently given, more especially from the volcanic records of the Carboniferous period.

One of the most interesting peculiarities of interstratified tuffs is the not infrequent occurrence of the remains of plants and animals imbedded in them. Such remains would have been entombed in the ordinary sediment had there been no volcanic eruptions, and their presence in the tuffs is another convincing proof of contemporaneous volcanic action during the deposition of a sedimentary series. But they may be made to furnish much more information as to the chronology of the eruptions and the physical geography of the localities where the volcanoes were active, as will be set forth farther on.

Tuffs, as already remarked, frequently occur without any accompaniment of lava, although lavas seldom appear without some tuff. We thus learn that in the past, as at present, discharges of fragmentary materials alone were more common than the outflow of lava by itself. The relative proportions of the lavas and tuffs in a volcanic series vary indefinitely. In the Tertiary basalt-plateaux of Britain, the lavas succeed each other, sheet above sheet, for hundreds of feet, with few and trifling fragmental intercalations. Among the Carboniferous volcanic ejections, on the other hand, many solitary or successive bands of tuff may be observed without any visible sheets of lava. Viewed broadly, however, in their general distribution during geological time, the two great groups of volcanic material may be regarded as having generally appeared together. In all the great volcanic series, from the base of the Palæozoic systems up to the Tertiary plateaux, lavas and tuffs are found associated, much as they are among the ejections of modern volcanoes. They often alternate, and thus furnish evidence as to oscillations of energy at the eruptive vents.

Now and then, by the explosions from a volcano at the present day, a single stone may be ejected at such an angle and with such force as to fall to the ground at a long distance from the vent. In like manner, among the volcanic records of former periods, we may occasionally come upon a single block of lava imbedded among tuffs or even in non-volcanic strata. Where such a stone has fallen upon soft sediment, it can be seen to have sunk into it, pressing down the layers beneath it, and having the subsequently deposited layers heaped over it. An ejected block of this nature is represented among the tuffs shown in Fig. 13. Another instance from a group of non-volcanic sediments is given in Fig. 15, and is selected from a number of illustrations of this interesting feature which have been observed among the Lower Carboniferous formations of the basin of the Firth of Forth. A solitary block, imbedded in a series of strata, would not, of course, by itself afford a demonstration of volcanic activity. There are various ways in which such stones may be transported and dropped over a muddy water-bottom. They may, for example, be floated off attached to sea-weeds, or wrapped round by the roots of trees. But where a block of basalt or other volcanic rock has obviously descended with such force as to crush down the deposits on which it fell, and when lavas and tuffs are known to exist in the vicinity, there can be little hesitation in regarding such a block as having been ejected from a neighbouring vent, either during an explosion of exceptional violence or with an unusually low angle of projection.

In conclusion, reference may conveniently be made here to another variety of fragmental volcanic materials which cannot always be satisfactorily distinguished from true tuffs, although arising from a thoroughly non-volcanic agency. Where a mass of lava has been exposed to denudation, as, for instance, when a volcanic island has been formed in a lake or in the sea, the detritus worn away from it may be spread out like any other kind of sediment. Though derived from the degradation of lava, such a mechanical deposit is not properly a tuff, nor can it even be included among strictly volcanic formations. It may be called a volcanic conglomerate, rhyolitic conglomerate, diabase sandstone, felsitic shale, or by any other name that will adequately denote its composition and texture. But it may not afford proof of strictly contemporaneous volcanic activity. All that we are entitled to infer from such a deposit is that, at the time when it was laid down, volcanic rocks of a certain kind were exposed at the surface and were undergoing degradation. But the date of their original eruption may have been long previous to that of the formation of the detrital deposit from their waste.

Nevertheless, it is sometimes possible to make sure that the conglomerate or sandstone, though wholly due to the mechanical destruction of already erupted lavas, was in a general sense contemporaneous with the volcanoes that gave forth these lavas. The detrital formation may be traced perhaps up to the lavas from which it was derived, and may be found to be intercalated in the same sedimentary series with which they are associated. Or it may contain large bombs and slags, such as most probably came either directly from explosions or from the washing down of cinder-cones or other contemporaneously existing volcanic heaps. Examples of such intercalated conglomerates will be given from the Lower Old Red Sandstone of Central Scotland and from the Tertiary volcanic plateaux of the Inner Hebrides.

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