Part 12

Another kind of clay, bentonite, forms from weathered volcanic ash. Bentonite contains the clay mineral montmorillonite and looks smooth and soap-like. Fresh samples of this clay are white, pale green, or pale blue, but dried-out or weathered samples are tan, brown, yellow, or reddish. When wet, bentonite absorbs water, swells, and then has a jelly-like appearance.

Surface deposits of bentonite occur chiefly in Eocene Tertiary formations of the Gulf Coastal Plain, in Cretaceous formations of the Big Bend area of west Texas, and in Quaternary formations of the High Plains.

Some bentonite is used to absorb unwanted coloring material in petroleum and in vegetable oils. It is then known as a bleaching clay. Bentonite bleaching clay is obtained from some of the Tertiary formations along the Texas Gulf Coastal Plain. It has been produced in Angelina, Fayette, Gonzales, Jasper, Walker, and other counties in this area.

Another important use of bentonite, and of other clay, too, is as drilling mud. In the rotary method of drilling for oil and gas, mud is pumped down into the drilled hole. This mud carries the rock cuttings up to the surface, it cools the drilling tools, and it coats and seals the walls of the hole. Along the Gulf Coastal Plain, drilling clay is obtained from Tertiary formations.

Common Opal. See Opal.

Copper Minerals (Chalcocite, Chalcopyrite, Malachite, Azurite)

A number of minerals containing copper, such as chalcocite, chalcopyrite, malachite, and azurite, occur in small deposits in Texas. They are found chiefly in the Llano uplift area of central Texas, in the Van Horn area of Culberson and Hudspeth counties in west Texas, and in a group of counties in north-central Texas.

Copper is an important element. Because it is an unusually good conductor of electricity (only silver, which costs much more, is a better one), it is used for many kinds of wires for switchboards, generators, motors, telephone and telegraph equipment, and light and power lines.

Manufacturers commonly combine copper with other elements. For example, some copper is mixed with zinc to make brass and with tin and a little zinc to make bronze. These mixtures are called alloys. Many products are made from copper alloys, including tubing, pipes, jewelry, pots, and pans. Even our coins contain copper.

Sometimes, a prospector uses a chemical test to find out if copper is present in a mineral. First, he crushes a small sample of what he believes is a copper mineral (such as chalcocite, chalcopyrite, azurite, or malachite). He then puts the sample in a glass jar or test tube and pours in a small amount of dilute nitric acid (this acid, like hydrochloric acid, is poisonous). After the sample has dissolved in the acid, he adds enough ammonium hydroxide to make the solution alkaline. If the sample is a copper mineral, the solution turns a deep-blue color.

One of the copper minerals, chalcocite, copper sulfide, also is known as copper glance. It is a metallic mineral that commonly tarnishes to a dull black. By chipping off a fragment to obtain a fresh surface, you will see that it has a shiny lead-gray color. Chalcocite is rather soft, and it is sectile, that is, a knife will cut through it as well as scratch it. When you rub chalcocite across a streak plate, it gives a grayish-black streak. This mineral commonly occurs as compact masses or as granular masses.

Chalcocite, with its dark color, does not look at all like copper, which is a bright reddish brown. Chalcocite, however, is the chief copper mineral at the most important copper mine in Texas, the Hazel mine, which is about 15 miles northwest of Van Horn in Culberson County in west Texas. This mine, although now idle and almost filled with water, has produced about one and a half million pounds of copper along with more valuable silver ores. Here, the chalcocite and other minerals occur in material that fills large cracks in red sandstone of the Precambrian Hazel Formation. It is thought that long ago, molten igneous rock material far below the surface sent out hot solutions containing copper and other elements. These solutions moved upward and deposited minerals in the fracture zone in the sandstone.

Chalcocite occurs also in north-central Texas. It is found in Archer, Baylor, Clay, Foard, Hardeman, King, Knox, Stonewall, and several other counties of this area. Here, it occurs in Permian sedimentary rocks (called “red beds”) as rounded masses, as scattered grains, and as petrified wood. Because these deposits are far from any igneous rocks, they apparently did not form in the same way as those at the Hazel mine. These north-central Texas deposits have never really been commercially developed. During the Civil War, however, some copper from this area was made into percussion caps for the Confederacy.

Another copper mineral, chalcopyrite, is a copper-iron sulfide. It also is known as copper pyrites and yellow copper ore. This mineral has a metallic luster and a brass-yellow or a golden-yellow color. When rubbed across a streak plate, it gives a greenish-black streak. Chalcopyrite will tarnish and then has bronze, blue, purple, and other rainbow-like colors. This mineral is fairly soft—you can scratch it with a pocket knife. Because of chalcopyrite’s yellow color, it has often been mistaken for gold. For this reason, it, like iron pyrite, is often called fool’s gold. (See Gold, p. 60, for ways to tell them apart.)

Chalcopyrite commonly is found in compact masses that show no crystal shapes. These masses either are scattered through rocks or occur in material that fills cracks in rocks.

Some chalcopyrite is found in Precambrian sandstone at the Hazel mine and in other deposits in the Van Horn area of Culberson and Hudspeth counties. It also occurs in Precambrian rocks at the Sheridan and Pavitte prospects in Burnet County. These chalcopyrite localities are in districts where igneous rocks occur.

It is likely that, long ago, hot solutions containing copper moved upward, out of deeply buried molten magma. While still far below the surface, the solutions deposited the chalcopyrite in cracks and other openings in the nearby rocks.

Two copper minerals of Texas, azurite and malachite, are copper carbonates. Azurite is commonly called chessylite and blue copper; malachite is called green copper carbonate. Because these minerals are carbonates, a drop of dilute hydrochloric acid will fizz and bubble when placed on either of them.

Azurite has a bright, intense blue color and leaves a blue streak when rubbed across a streak plate. Malachite has a bright green color and leaves a green streak. These minerals have a nonmetallic luster and a glassy to dull appearance. Commonly, they are translucent, although some specimens of azurite are transparent. Both azurite and malachite are fairly soft—a pocket knife will scratch them, but a copper penny will not.

Azurite and malachite occur as individual crystals, but you are more likely to find them as crusts on rocks and on other minerals. Malachite is also found in rounded fibrous masses that resemble bunches of grapes (described then as botryoidal).

Both azurite and malachite are formed in the same way. Underground waters seep through rocks that contain deposits of copper minerals (such as chalcocite and chalcopyrite) and cause chemical reactions which change these minerals into malachite and azurite.

Malachite is more plentiful than azurite, but both minerals can be found together. You can expect to find at least one of them at the same localities where chalcocite, chalcopyrite, and other copper minerals occur.

Coquina. See Limestone.

Diatomite. See Opal.

Dolomite

Dolomite is the name given both to a rock and to a mineral. The mineral is a calcium-magnesium carbonate and has a glassy or a pearly luster. It is any of a number of colors, such as white, pink, brown, or gray, or it can be colorless. Dolomite leaves a white streak on a streak plate and is transparent to translucent. It is not particularly hard and can be scratched with a pocket knife, although not with a copper penny. Dolomite cleaves perfectly in three directions, and some of the cleavage fragments are rhombohedrons. However, the cleavages of the individual mineral grains in specimens of fine-grained massive dolomite are not readily distinguishable.

Most Texas dolomite occurs as coarse-, medium-, and fine-grained crystalline masses as the chief mineral in dolomite rock and in dolomitic marble. It is also found as 6-sided crystals that are rhomb-shaped; when the faces are curved, they have a saddle-like appearance.

Crystals of the mineral dolomite commonly occur in cavities in the dolomite rocks. It is believed that they were deposited there by seeping underground waters. The waters dissolved some of the dolomite in the rocks and then re-deposited it as crystals.