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Reflections on the Motive Power of Heat · Sadi Carnot — chapter 34 of 39 · ~1,111 words · public domain

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We say, to lessen the dangers of journeys. In fact, although the use of the steam-engine on ships is attended by some danger which has been greatly exaggerated, this is more than compensated by the power of following always an appointed and well-known route, of resisting the force of the winds which would drive the ship towards the shore, the shoals, or the rocks.

Footnote 7:

We use here the expression motive power to express the useful effect that a motor is capable of producing. This effect can always be likened to the elevation of a weight to a certain height. It has, as we know, as a measure, the product of the weight multiplied by the height to which it is raised.

Footnote 8:

We distinguish here the steam-engine from the heat-engine in general. The latter may make use of any agent whatever, of the vapor of water or of any other, to develop the motive power of heat.

Footnote 9:

Certain engines at high pressure throw the steam out into the atmosphere instead of the condenser. They are used specially in places where it would be difficult to procure a stream of cold water sufficient to produce condensation.

Footnote 10:

The existence of water in the liquid state here necessarily assumed, since without it the steam-engine could not be fed, supposes the existence of a pressure capable of preventing this water from vaporizing, consequently of a pressure equal or superior to the tension of vapor at that temperature. If such a pressure were not exerted by the atmospheric air, there would be instantly produced a quantity of steam sufficient to give rise to that tension, and it would be necessary always to overcome this pressure in order to throw out the steam from the engines into the new atmosphere. Now this is evidently equivalent to overcoming the tension which the steam retains after its condensation, as effected by ordinary means.

If a very high temperature existed at the surface of our globe, as it seems certain that it exists in its interior, all the waters of the ocean would be in a state of vapor in the atmosphere, and no portion of it would be found in a liquid state.

Footnote 11:

It is considered unnecessary to explain here what is quantity of caloric or quantity of heat (for we employ these two expressions indifferently), or to describe how we measure these quantities by the calorimeter. Nor will we explain what is meant by latent heat, degree of temperature, specific heat, etc. The reader should be familiarized with these terms through the study of the elementary treatises of physics or of chemistry.

Footnote 12:

We may perhaps wonder here that the body B being at the same temperature as the steam is able to condense it. Doubtless this is not strictly possible, but the slightest difference of temperature will determine the condensation, which suffices to establish the justice of our reasoning. It is thus that, in the differential calculus, it is sufficient that we can conceive the neglected quantities indefinitely reducible in proportion to the quantities retained in the equations, to make certain of the exact result.

The body B condenses the steam without changing its own temperature—this results from our supposition. We have admitted that this body may be maintained at a constant temperature. We take away the caloric as the steam furnishes it. This is the condition in which the metal of the condenser is found when the liquefaction of the steam is accomplished by applying cold water externally, as was formerly done in several engines. Similarly, the water of a reservoir can be maintained at a constant level if the liquid flows out at one side as it flows in at the other.

One could even conceive the bodies A and B maintaining the same temperature, although they might lose or gain certain quantities of heat. If, for example, the body A were a mass of steam ready to become liquid, and the body B a mass of ice ready to melt, these bodies might, as we know, furnish or receive caloric without thermometric change.

Footnote 13:

Note A, Appendix B.

Footnote 14:

We assume here no chemical action between the bodies employed to realize the motive power of heat. The chemical action which takes place in the furnace is, in some sort, a preliminary action,—an operation destined not to produce immediately motive power, but to destroy the equilibrium of the caloric, to produce a difference of temperature which may finally give rise to motion.

Footnote 15:

This kind of loss is found in all steam-engines. In fact, the water destined to feed the boiler is always cooler than the water which it already contains. There occurs between them a useless re-establishment of equilibrium of caloric. We are easily convinced, à posteriori, that this re-establishment of equilibrium causes a loss of motive power if we reflect that it would have been possible to previously heat the feed-water by using it as condensing water in a small accessory engine, when the steam drawn from the large boiler might have been used, and where the condensation might be produced at a temperature intermediate between that of the boiler and that of the principal condenser. The power produced by the small engine would have cost no loss of heat, since all that which had been used would have returned into the boiler with the water of condensation.

Footnote 16:

The matter here dealt with being entirely new, we are obliged to employ expressions not in use as yet, and which perhaps are less clear than is desirable.

Footnote 17:

Note 13, Appendix B.

Footnote 18:

We tacitly assume in our demonstration, that when a body has experienced any changes, and when after a certain number of transformations it returns to precisely its original state, that is, to that state considered in respect to density, to temperature, to mode of aggregation—let us suppose, I say, that this body is found to contain the same quantity of heat that it contained at first, or else that the quantities of heat absorbed or set free in these different transformations are exactly compensated. This fact has never been called in question. It was first admitted without reflection, and verified afterwards in many cases by experiments with the calorimeter. To deny it would be to overthrow the whole theory of heat to which it serves as a basis. For the rest, we may say in passing, the main principles on which the theory of heat rests require the most careful examination. Many experimental facts appear almost inexplicable in the present state of this theory.

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