Chapter X., the Presence of This Property Is an Indication That the

matter is undergoing change accompanied by the expulsion of charged particles. It does not, however, by any means follow that because the atom of one element in the course of time becomes unstable and breaks up, that, therefore, the atoms of all the other elements pass through similar phases of instability.

It has already been mentioned (section 8), that Mme Curie made a very extensive examination of most of the elements and their compounds for radio-activity. The electric method was used, and any substance possessing an activity of ¹⁄₁₀₀ of that of uranium would certainly have been detected. With the exception of the known radio-elements and the minerals containing uranium and thorium, no other substances were found to be radio-active even to that degree.

Certain substances like phosphorus possess the property of ionizing a gas under special conditions. The air which is drawn over the phosphorus is conducting, but it has not yet been settled whether this conductivity is due merely to ions formed at the surface of the phosphorus or to ions produced by the phosphorus nuclei or emanations, as they have been termed, which are carried along with the current of air. It does not however appear that the ionization of the gas is in any way due to the presence of a penetrating type of radiation such as is emitted by the radio-active bodies. Le Bon (section 8) observed that quinine sulphate, after being heated to a temperature below the melting point and then allowed to cool, showed for a time strong phosphorescence and was able rapidly to discharge an electroscope. The discharging action of quinine sulphate under varying conditions has been very carefully examined by Miss Gates. The ionization could not be observed through thin aluminium foil or gold-leaf, but appeared to be confined to the surface of the sulphate. The current observed by an electrometer was found to vary with the direction of the electric field, indicating that the positive and negative ions had very different mobilities. The discharging action appears to be due either to an ionization of the gas very close to the surface by some short ultra-violet light waves, accompanying the phosphorescence, or to a chemical action taking place at the surface.

Thus, neither phosphorus nor quinine sulphate can be considered to be radio-active, even under the special conditions when they are able to discharge an electrified body. No evidence in either case has been found that the ionization is due to the emission of a penetrating radiation.

No certain evidence has yet been obtained that any body can be made radio-active by exposure to Röntgen rays or cathode rays. A metal exposed to the action of Röntgen rays gives rise to a secondary radiation which is very readily absorbed in a few centimetres of air. It is possible that this secondary radiation may prove to be analogous in some respects to the α rays from the radio-elements. The secondary radiation, however, ceases immediately the Röntgen rays are cut off. Villard stated that a piece of bismuth produced a feeble photographic action after it had been exposed for some time to the action of the cathode rays in a vacuum. It has not however been shown that the bismuth gives out rays of a character similar to those of the radio-active bodies. The experiments of Ramsay and Cooke on the production of apparent activity in inactive matter by the radiations from radium have already been discussed in section 264.

The existence of a very feeble radio-activity of ordinary matter has been deduced from the study of the conductivity of gases in closed vessels. The conductivity is extremely minute, and special methods are required to determine it with accuracy. A brief account will now be given of the gradual growth of our knowledge on this important question.

=284. Conductivity of air in closed vessels.= Since the time of Coulomb onwards several investigators have believed that a charged conductor placed inside a closed vessel lost its charge more rapidly than could be explained by the conduction leak across the insulating support. Matteucci, as early as 1850, observed that the rate of loss of charge was independent of the potential. Boys, by using quartz insulators of different lengths and diameters, arrived at the conclusion that the leakage must in part take place through the air. This loss of charge in a closed vessel was believed to be due in some way to the presence of dust particles in the air.

On the discovery that gases become temporary conductors of electricity under the influence of Röntgen rays and the rays from radio-active substances, attention was again drawn to this question. Geitel and C. T. R. Wilson independently attacked the problem, and both came to the conclusion that the loss of charge was due to a constant ionization of the air in the closed vessel. Geitel employed in his experiments an apparatus similar to that shown in Fig. 103. The loss of charge of an Exner electroscope, with the cylinder of wire netting Z attached, was observed in a closed vessel containing about 30 litres of air. The electroscope system was found to diminish in potential at the rate of about 40 volts per hour, and this leakage was shown not to be due to a want of insulation of the supports.

Wilson, on the other hand, used a vessel of very small volume, in order to work with air which could be completely freed from dust. In the first experiments a silvered glass vessel with a volume of only 163 c.c. was employed. The experimental arrangement is shown in Fig. 104.

The conductor, of which the loss of charge was to be measured, was placed near the centre of the vessel A. It consisted of a narrow strip of metal with a gold-leaf attached. The strip of metal was fixed to the upper rod by means of a small sulphur bead. The upper rod was connected with a sulphur condenser with an Exner electroscope B attached to indicate its potential. The gold-leaf system was initially charged to the same potential as the upper rod and condenser by means of a fine steel wire which was caused to touch the gold-leaf system by the attraction of a magnet brought near it. The rate of movement of the gold-leaf was measured by means of a microscope provided with a micrometer eye-piece. By keeping the upper rod at a slightly higher potential than the gold-leaf system, it was ensured that the loss of charge of the gold-leaf system should not be due in any way to a conduction leakage across the sulphur bead.

The method employed by Wilson in these experiments is very certain and convenient when an extremely small rate of discharge is to be observed. In this respect the electroscope measures with certainty a rate of loss of charge much smaller than can be measured by a sensitive electrometer.

Both Geitel and Wilson found that the leakage of the insulated system in dust-free air was the same for a positive as for a negative charge, and was independent of the potential over a considerable range. The leakage was the same in the dark as in diffuse daylight. The independence of leakage of the potential is strong evidence that the loss of charge is due to a constant ionization of the air. When the electric field acting on the gas exceeds a certain value, all the ions are carried to the electrodes before recombination occurs. A saturation current is reached, and it will be independent of further increase of the electric field, provided, of course, a potential sufficiently high to cause a spark to pass is not applied.

C. T. R. Wilson has recently devised a striking experiment to show the presence of ions in dust-free air which is not exposed to any external ionizing agency. Two large metal plates are placed in a glass vessel connected with an expansion apparatus similar to that described in