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Book Iii. Chapter V.) Implies Not Only Force, but Something

History of Scientific Ideas · William Whewell — chapter 63 of 85 · ~1,616 words · public domain

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which resists the action of force.]

{59} 10. Use of the Molecular Hypothesis.--In this form, representing matter as a collection of molecules or centers of force, the Atomic Theory has been abundantly employed in modern times as an hypothesis on which calculations respecting the elementary forces of bodies might be conducted. When thus employed it is to be considered as expressing the principle that the properties of bodies depend upon forces emanating from immovable points of their mass. This view of the way in which the properties of bodies are to be treated by the mechanical philosopher was introduced by Newton, and was a natural sequel to the success which he had obtained by reasoning concerning central forces on a large scale. I have already quoted his Preface to the Principia, in which he says, 'Many things induce me to believe that the rest of the phenomena of nature, as well as those of astronomy, may depend upon certain forces by which the particles of bodies, in virtue of causes not yet known, are urged towards each other and cohere in regular figures, or are mutually repelled and recede; and philosophers, knowing nothing of these forces, have hitherto failed in their examination of nature.' Since the time of Newton, this line of speculation has been followed with great assiduity, and by some mathematicians with great success. In particular Laplace has shown that the hypothesis may, in many instances, be made a much closer representation of nature, if we suppose the forces exerted by the particles to decrease so rapidly with the increasing distance from them, that {60} the force is finite only at distances imperceptible to our senses, and vanishes at all remoter points. He has taught the method of expressing and calculating such forces, and he and other mathematicians of his school have applied this method to many of the most important questions of physics; as capillary action, the elasticity of solids, the conduction and radiation of heat. The explanation of many apparently unconnected and curious observed facts by these mathematical theories gives a strong assurance that its essential principles are true. But it must be observed that the actual constitution of bodies as composed of distinct and separate particles is by no means proved by these coincidences. The assumption, in the reasoning, of certain centers of force acting at a distance, is to be considered as nothing more than a method of reducing to calculation that view of the constitution of bodies which supposes that they exert force at every point. It is a mathematical artifice of the same kind as the hypothetical division of a body into infinitesimal parts, in order to find its center of gravity; and no more implies a physical reality than that hypothesis does.

11. Poisson's Inference.--When, therefore, M. Poisson, in his views of Capillary Action, treats this hypothetical distribution of centers of force as if it were a physical fact, and blames Laplace for not taking account of their different distribution at the surface of the fluid and below it[45\6], he appears to push the claims of the molecular hypothesis too far. The only ground for the assumption of separate centers, is that we can thus explain the action of the whole mass. The intervals between the centers nowhere enter into this explanation: and therefore we can have no reason for assuming these intervals different in one part of the fluid and in the other. M. Poisson asserts that the density of the fluid diminishes when we approach very near the surface; but he allows that this diminution is not detected by experiment, and that the formulæ on {61} his supposition, so far as the results go, are identical with those of Laplace. It is clear, then, that his doctrine consists merely in the assertion of the necessary truth of a part of the hypothesis which cannot be put to the test of experiment. It is true, that so long as we have before us the hypothesis of separate centers, the particles very near the surface are not in a condition symmetrical with that of the others: but it is also true that this hypothesis is only a step of calculation. There results, at one period of the process of deduction, a stratum of smaller density at the surface of the fluid; but at a succeeding point of the reasoning the thickness of this stratum vanishes; it has no physical existence.

Thus the molecular hypothesis, as used in such cases, does not differ from the doctrine of forces acting at every point of the mass; and this principle, which is common to both the opposite views, is the true part of each.

12. Wollaston's Argument.--An attempt has been made in another case, but depending on nearly the same arguments, to bring the doctrine of ultimate atoms to the test of observation. In the case of the air, we know that there is a diminution of density in approaching the upper surface of the atmosphere, if it have a surface: but it is held by some that except we allow the doctrine of ultimate molecules, it will not be bounded by any surface, but will extend to an infinite distance. This is the reasoning of Wollaston[46\6]. 'If air consists of any ultimate particles no longer divisible, then must the expansion of the medium composed of them cease at that distance where the force of gravity downwards is equal to the resistance arising from the repulsive force of the medium.' But if there be no such ultimate particles, every stratum will require a stratum beyond it to prevent by its weight a further expansion, and thus the atmosphere {62} must extend to an infinite distance. And Wollaston conceived that he could learn from observation whether the atmosphere was thus diffused through all space; for if so, it must, he argued, be accumulated about the larger bodies of the system, as Jupiter and the Sun, by the law of universal gravitation; and the existence of an atmosphere about these bodies, might, he remarked, be detected by its effects in producing refraction. His result is, that 'all the phenomena accord entirely with the supposition that the earth's atmosphere is of finite extent, limited by the weight of ultimate atoms of definite magnitude, no longer divisible by repulsion of their parts.'

A very little reflection will show us that such a line of reasoning cannot lead to any result. For we know nothing of the law which connects the density with the compressing force, in air so extremely rare as we must suppose it to be near the boundary of the atmosphere. Now there are possible laws of dependence of the density upon the compressing force such that the atmosphere would terminate in virtue of the law without any assumption of atoms. This may be proved by mathematical reasoning. If we suppose the density of air to be as the square root of the compressing force, it will follow that at the very limits of the atmosphere, the strata of equal thickness may observe in their densities such a law of proportion as is expressed by the numbers 7, 5, 3, 1[47\6].

If it be asked how, on this hypothesis, the density of the highest stratum can be as 1, since there is {63} nothing to compress it, we answer that the upper part of the highest stratum compresses the lower, and that the density diminishes continually to the surface, so that the need of compression and the compressing weight vanish together.

The fallacy of concluding that because the height of the atmosphere is finite, the weight of the highest stratum must be finite, is just the same as the fallacy of those who conclude that when we project a body vertically upwards, because it occupies only a finite time in ascending to the highest point, the velocity at the last instant of the ascent must be finite. For it might be said, if the last velocity of ascent be not finite, how can the body describe the last particle of space in a finite time? and the answer is, that there is no last finite particle of space, and therefore no last finite velocity.

13. Permanence of Properties of Bodies.--We have already seen that, in explaining the properties of matter as we find them in nature, the assumption of solid, hard, indestructible particles is of no use or value. But we may remark, before quitting the subject, that Newton appears to have had another reason for assuming such particles, and one well worthy of notice. He wished to express, by means of this hypothesis, the doctrine that the laws of nature do not alter with the course of time. This we have already seen in the quotation from Newton. 'The ultimate particles of matter are indestructible, unalterable, impenetrable; for if they could break or wear, the structure of material bodies now would be different from that which it was when the particles were new.' No philosopher will deny the truth which is thus conveyed by the assertion of atoms; but it is obviously equally easy for a person who rejects the atomic view, to state this truth by saying that the forces which matter exerts do not vary with time, but however modified by the new modifications of its form, are always unimpaired in quantity, and capable of being restored to their former mode of action. {64}

We now proceed to speculations in which the fundamental conceptions may, perhaps, be expressed, at least in some cases, by means of the arrangement of atoms; but in which the philosophy of the subject appears to require a reference to a new Fundamental Idea.

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