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Fragments of Science: a Series of Detached Essays, Addresses, and Reviews. V. 1-2 · John Tyndall — chapter 5 of 79 · ~5,581 words · public domain

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The sources of this vibration are the ponderable masses of the universe. Let us take a sample of these and examine it in detail. When we look to our planet, we find it to be an aggregate of solids, liquids, and gases. Subjected to a sufficiently low temperature, the two last, would also assume the solid form. When we look at any one of these, we generally find it composed of still more elementary parts. We learn, for example, that the water of our rivers is formed by the union, in definite proportions, of two gases, oxygen and hydrogen. We know how to bring these constituents together, so as to form water: we also know how to analyse the water, and recover from it its two constituents. So, likewise, as regards the solid portions of the earth. Our chalk hills, for example, are formed by a combination of carbon, oxygen, and calcium. These are the so-called elements the union of which, in definite proportions, has resulted in the formation of chalk. The flints within the chalk we know to be a compound of oxygen and silicium, called silica; and our ordinary clay is, for the most part, formed by the union of silicium, oxygen, and the well-known light metal, aluminium. By far the greater portion of the earth's crust is compounded of the elementary substances mentioned in these few lines.

The principle of gravitation has been already described as an attraction which every particle of matter, however small, exerts on every other particle. With gravity there is no selection; no particular atoms choose, by preference, other particular atoms as objects of attraction; the attraction of gravitation is proportional simply to the quantity of the attracting matter, regardless of its quality. But in the molecular world which we have now entered matters are otherwise arranged. Here we have atoms between which a strong attraction is exercised, and also atoms between which a weak attraction is exercised. One atom can jostle another out of its place, in virtue of a superior force of attraction. But, though the amount of force exerted varies thus from atom to atom, it is still an attraction of the same mechanical quality, if I may use the term, as that of gravity itself. Its intensity might be measured in the same way, namely by the amount of motion which it can generate in a certain time. Thus the attraction of gravity at the earth's surface is expressed by the number 32; because, when acting freely on a body for a second of time, gravity imparts to the body a velocity of thirty-two feet a second. In like manner the mutual attraction of oxygen and hydrogen might be measured by the velocity imparted to the atoms in their rushing together. Of course such a unit of time as a second is not here to be thought of, the whole interval required by the atoms to cross the minute spaces which separate them amounting only to an inconceivably small fraction of a second.

It has been stated that when a body falls to the earth it is warmed by the shock. Here, to use the terminology of Mayer, we have a mechanical combination of the earth and the body. Let us suffer the falling body and the earth to dwindle in imagination to the size of atoms, and for the attraction of gravity let us substitute that of chemical affinity; we have then what is called a chemical combination. The effect of the union in this case also is the development of heat, and from the amount of heat generated we can infer the intensity of the atomic pull. Measured by ordinary mechanical standards, this is enormous. Mix eight pounds of oxygen with one of hydrogen, and pass a spark through the mixture; the gases instantly combine, their atoms rushing over the little distances which separate them. Take a weight of 47,000 pounds to an elevation of 1,000 feet above the earth's surface, and let it fall; the energy with which it will strike the earth will not exceed that of the eight pounds of oxygen atoms, as they dash against one pound of hydrogen atoms to form water.

It is sometimes stated that gravity is distinguished from all other forces by the fact of its resisting conversion into other forms of force. Chemical affinity, it is said, can be converted into heat and light, and these again into magnetism and electricity: but gravity refuses to be so converted; being a force maintaining itself under all circumstances, and not capable of disappearing to give place to another. The statement arises from vagueness of thought. If by it be meant that a particle of matter can never be deprived of its weight, the assertion is correct; but the law which affirms the convertibility of natural forces was never intended, in the minds of those who understood it, to affirm that such a conversion as that here implied occurs in any case whatever. As regards convertibility into heat, gravity and chemical affinity stand on precisely the same footing. The attraction in the one case is as indestructible as in the other. Nobody affirms that when a stone rests upon the surface of the earth, the mutual attraction of the earth and stone is abolished; nobody means to affirm that the mutual attraction of oxygen for hydrogen ceases, after the atoms have combined to form water. What is meant, in the case of chemical affinity, is, that the pull of that affinity, acting through a certain space, imparts a motion of translation of the one atom towards the other. This motion is not heat, nor is the force that produces it heat. But when the atoms strike and recoil, the motion of translation is converted into a motion of vibration, which is heat. The vibration, however, so far from causing the extinction of the original attraction, is in part carried on by that attraction. The atoms recoil, in virtue of the elastic force which opposes actual contact, and in the recoil they are driven too far back. The original attraction then triumphs over the force of recoil, and urges the atoms once more together. Thus, like a pendulum, they oscillate, until their motion is imparted to the surrounding aether; or, in other words, until their heat becomes radiant heat.

In this sense, and in this sense only, is chemical affinity converted into heat. There is, first of all, the attraction between the atoms; there is, secondly, space between them. Across this space the attraction urges them. They collide, they recoil, they oscillate. There is here a change in the form of the motion, but there is no real loss. It is so with the attraction of gravity. To produce motion by gravity space must also intervene between the attracting bodies. When they strike together motion is apparently destroyed, but in reality there is no destruction. Their atoms are suddenly urged together by the shock; by their own perfect elasticity these atoms recoil; and thus is set up the molecular oscillation which, when communicated to the proper nerves, announces itself as heat.

It was formerly universally supposed that by the collision of unelastic bodies force was destroyed. Men saw, for example, that when two spheres of clay, painter's putty, or lead for example, were urged together, the motion possessed by the masses, prior to impact, was more or less annihilated. They believed in an absolute destruction of the force of impact. Until recent times, indeed, no difficulty was experienced in believing this, whereas, at present, the ideas of force and its destruction refuse to be united in most philosophic minds. In the collision of elastic bodies, on the contrary, it was observed that the motion with which they clashed together was in great part restored by the resiliency of the masses, the more perfect the elasticity the more complete being the restitution. This led to the idea of perfectly elastic bodies--bodies competent to restore by their recoil the whole of the motion which they possessed before impact--and this again to the idea of the conservation of force, as opposed to that destruction of force which was supposed to occur when unelastic bodies met in collision.

We now know that the principle of conservation holds equally good with elastic and unelastic bodies. Perfectly elastic bodies would develop no heat on collision. They would retain their motion afterwards, though its direction might be changed; and it is only when sensible motion is wholly or partly destroyed, that heat is generated. This always occurs in unelastic collision, the heat developed being the exact equivalent of the sensible motion extinguished. This heat virtually declares that the property of elasticity, denied to the masses, exists among their atoms; by the recoil and oscillation of which the principle of conservation is vindicated.

But ambiguity in the use of the term 'force' makes itself more and more felt as we proceed. We have called the attraction of gravity a force, without any reference to motion. A body resting on a shelf is as much pulled by gravity as when, after having been pushed off the shelf, it falls towards the earth. We applied the term force also to that molecular attraction which we called chemical affinity. When, however, we spoke of the conservation of force, in the case of elastic collision, we meant neither a pull nor a push, which, as just indicated, might be exerted upon inert matter, but we meant force invested in motion--the vis viva, as it is called, of the colliding masses.

Force in this form has a definite mechanical measure, in the amount of work that it can perform. The simplest form of work is the raising of a weight. A man walking up-hill, or up-stairs, with a pound weight in his hand, to an elevation say of sixteen feet, performs a certain amount of work, over and above the lifting of his own body. If he carries the pound to a height of thirty-two feet, he does twice the work; if to a height of forty-eight feet, he does three times the work; if to sixty-four feet, he does four times the work, and so on. If, moreover, he carries up two pounds instead of one, other things being equal, he does twice the work; if three, four, or five pounds, he does three, four, or five times the work. In fact, it is plain that the work performed depends on two factors, the weight raised and the height to which it is raised. It is expressed by the product of these two factors.

But a body may be caused to reach a certain elevation in opposition to the force of gravity, without being actually carried up. If a hodman, for example, wished to land a brick at an elevation of sixteen feet above the place where he stood, he would probably pitch it up to the bricklayer. He would thus impart, by a sudden effort, a velocity to the brick sufficient to raise it to the required height; the work accomplished by that effort being precisely the same as if he had slowly carried up the brick. The initial velocity to be imparted, in this case, is well known. To reach a height of sixteen feet, the brick must quit the man's hand with a velocity of thirty-two feet a second. It is needless to say, that a body starting with any velocity, would, if wholly unopposed or unaided, continue to move for ever with the same velocity. But when, as in the case before us, the body is thrown upwards, it moves in opposition to gravity, which incessantly retards its motion, and finally brings it to rest at an elevation of sixteen feet. If not here caught by the bricklayer, it would return to the hodman with an accelerated motion, and reach his hand with the precise velocity it possessed on quitting it.

An important relation between velocity and work is here to be pointed out. Supposing the hodman competent to impart to the brick, at starting, a velocity of sixty-four feet a second, or twice its former velocity, would the amount of work performed be twice what it was in the first instance? No; it would be four times that quantity; for a body starting with twice the velocity of another, will rise to four times the height. In like manner, a three-fold velocity will give a nine-fold elevation, a four-fold velocity will give a sixteen-fold elevation, and so on. The height attained, then, is not proportional to the initial velocity, but to the square of the velocity. As before, the work is also proportional to the weight elevated. Hence the work which any moving mass whatever is competent to perform, in virtue of the motion which it at any moment possesses, is jointly proportional to its weight and the square of its velocity. Here, then, we have a second measure of work, in which we simply translate the idea of height into its equivalent idea of motion.

In mechanics, the product of the mass of a moving body into the square of its velocity, expresses what is called the vis viva, or living force. It is also sometimes called the 'mechanical effect.' If, for example, a cannon pointed to the zenith urge a ball upwards with twice the velocity imparted to a second ball, the former will rise to four times the height attained by the latter. If directed against a target, it will also do four times the execution. Hence the importance of imparting a high velocity to projectiles in war. Having thus cleared our way to a perfectly definite conception of the vis viva of moving masses, we are prepared for the announcement that the heat generated by the shock of a falling body against the earth is proportional to the vis viva annihilated. The heat is proportional to the square of the velocity. In the case, therefore, of two cannon-balls of equal weight, if one strike a target with twice the velocity of the other, it will generate four times the heat, if with three times the velocity, it will generate nine times the heat, and so on.

Mr. Joule has shown that a pound weight falling from a height of 772 feet, or 772 pounds falling through one foot, will generate by its collision with the earth an amount of heat sufficient to raise a pound of water one degree Fahrenheit in temperature. 772 "foot-pounds" constitute the mechanical equivalent of heat. Now, a body falling from a height of 772 feet, has, upon striking the earth, a velocity of 223 feet a second; and if this velocity were imparted to the body, by any other means, the quantity of heat generated by the stoppage of its motion would be that stated above. Six times that velocity, or 1,338 feet, would not be an inordinate one for a cannon-ball as it quits the gun. Hence, a cannon-ball moving with a velocity of 1,338 feet a second, would, by collision, generate an amount of heat competent to raise its own weight of water 36 degrees Fahrenheit in temperature. If composed of iron, and if all the heat generated were concentrated in the ball itself, its temperature would be raised about 360 degrees Fahrenheit; because one degree in the case of water is equivalent to about ten degrees in the case of iron. In artillery practice, the heat generated is usually concentrated upon the front of the bolt, and on the portion of the target first struck. By this concentration the heat developed becomes sufficiently intense to raise the dust of the metal to incandescence, a flash of light often accompanying collision with the target.

Let us now fix our attention for a moment on the gunpowder which urges the cannon-ball. This is composed of combustible matter, which if burnt in the open air would yield a certain amount of heat. It will not yield this amount if it perform the work of urging a ball. The heat then generated by the gunpowder will fall short of that produced in the open air, by an amount equivalent to the vis viva of the ball; and this exact amount is restored by the ball on its collision with the target. In this perfect way are heat and mechanical motion connected.

Broadly enunciated, the principle of the conservation of force asserts, that the quantity of force in the universe is as unalterable as the quantity of matter; that it is alike impossible to create force and to annihilate it. But in what sense are we to understand this assertion? It would be manifestly inapplicable to the force of gravity as defined by Newton; for this is a force varying inversely as the square of the distance; and to affirm the constancy of a varying force would be self-contradictory. Yet, when the question is properly understood, gravity forms no exception to the law of conservation. Following the method pursued by Helmholtz, I will here attempt an elementary exposition of this law. Though destined in its applications to produce momentous changes in human thought, it is not difficult of comprehension.

For the sake of simplicity we will consider a particle of matter, which we may call F, to be perfectly fixed, and a second movable particle, D, placed at a distance from F. We will assume that these two particles attract each other according to the Newtonian law. At a certain distance, the attraction is of a certain definite amount, which might be determined by means of a spring balance. At half this distance the attraction would be augmented four times; at a third of the distance, nine times; at one-fourth of the distance, sixteen times, and so on. In every case, the attraction might be measured by determining, with the spring balance, the amount of tension just sufficient to prevent D from moving towards F. Thus far we have nothing whatever to do with motion; we deal with statics, not with dynamics. We simply take into account the distance of D from F, and the pull exerted by gravity at that distance.

It is customary in mechanics to represent the magnitude of a force by a line of a certain length, a force of double magnitude being represented by a line of double length, and so on. Placing then the particle D at a distance from F, we can, in imagination, draw a straight line from D to F, and at D erect a perpendicular to this line, which shall represent the amount of the attraction exerted on D. If D be at a very great distance from F, the attraction will be very small, and the perpendicular consequently very short. If the distance be practically infinite, the attraction is practically nil. Let us now suppose at every point in the line joining F and D a perpendicular to be erected, proportional in length to the attraction exerted at that point; we thus obtain an infinite number of perpendiculars, of gradually increasing length, as D approaches F. Uniting the ends of all these perpendiculars, we obtain a curve, and between this curve and the straight line joining F and D we have an area containing all the perpendiculars placed side by side. Each one of this infinite series of perpendiculars representing an attraction, or tension, as it is sometimes called, the area just referred to represents the sum of the tensions exerted upon the particle D, during its passage from its first position to F.

Up to the present point we have been dealing with tensions, not with motion. Thus far vis viva has been entirely foreign to our contemplation of D and F. Let us now suppose D placed at a practically infinite distance from F; here, as stated, the pull of gravity would be infinitely small, and the perpendicular representing it would dwindle almost to a point. In this position the sum of the tensions capable of being exerted on D would be a maximum. Let D now begin to move in obedience to the infinitesimal attraction exerted upon it. Motion being once set up, the idea of vis viva arises. In moving towards F the particle D consumes, as it were, the tensions. Let us fix our attention on D, at any point of the path over which it is moving. Between that point and F there is a quantity of unused tensions; beyond that point the tensions have been all consumed, but we have in their place an equivalent quantity of vis viva. After D has passed any point, the tension previously in store at that point disappears, but not without having added, during the infinitely small duration of its action, a due amount of motion to that previously possessed by D. The nearer D approaches to F, the smaller is the sum of the tensions remaining, but the greater is the vis viva; the farther D is from F, the greater is the sum of the unconsumed tensions, and the less is the living force. Now the principle of conservation affirms not the constancy of the value of the tensions of gravity, nor yet the constancy of the vis viva, taken separately, but the absolute constancy of the value of both taken together. At the beginning the vis viva was zero, and the tension area was a maximum; close to F the vis viva is a maximum, while the tension area is zero. At every other point, the work-producing power of the particle D consists in part of vis viva, and in part of tensions.

If gravity, instead of being attraction, were repulsion, then, with the particles in contact, the sum of the tensions between D and F would be a maximum, and the vis viva zero. If, in obedience to the repulsion, D moved away from F, vis viva would be generated; and the farther D retreated from F the greater would be its vis viva, and the less the amount of tension still available for producing motion. Taking repulsion as well as attraction into account, the principle of the conservation of force affirms that the mechanical value of the tensions and vires vivae of the material universe, so far as we know it, is a constant quantity. The universe, in short, possesses two kinds of property which are mutually convertible. The diminution of either carries with it the enhancement of the other, the total value of the property remaining unchanged.

The considerations here applied to gravity apply equally to chemical affinity. In a mixture of oxygen and hydrogen the atoms exist apart, but by the application of proper means they may be caused to rush together across that space that separates them. While this space exists, and as long as the atoms have not begun to move towards each other, we have tensions and nothing else. During their motion towards each other the tensions, as in the case of gravity, are converted into vis viva. After they clash we have still vis viva, but in another form. It was translation, it is vibration. It was molecular transfer, it is heat.

It is possible to reverse these processes, to unlock the combined atoms and replace them in their first positions. But, to accomplish this, as much heat would be required as was generated by their union. Such reversals occur daily and hourly in nature. By the solar waves, the oxygen of water is divorced from its hydrogen in the leaves of plants. As molecular vis viva the waves disappear, but in so doing they re-endow the atoms of oxygen and hydrogen with tension. The atoms are thus enabled to recombine, and when they do so they restore the precise amount of heat consumed in their separation. The same remarks apply to the compound of carbon and oxygen, called carbonic acid, which is exhaled from our lungs, produced by our fires, and found sparingly diffused everywhere throughout the air. In the leaves of plants the sunbeams also wrench the atoms of carbonic acid asunder, and sacrifice themselves in the act; but when the plants are burnt, the amount of heat consumed in their production is restored.

This, then, is the rhythmic play of Nature as regards her forces. Throughout all her regions she oscillates from tension to vis viva, from vis viva to tension. We have the same play in the planetary system. The earth's orbit is an ellipse, one of the foci of which is occupied by the sun. Imagine the earth at the most distant part of the orbit. Her motion, and consequently her vis viva, is then a minimum. The planet rounds the curve, and begins its approach to the sun. In front it has a store of tensions, which are gradually consumed, an equivalent amount of vis viva being generated. When nearest to the sun the motion, and consequently the vis viva, reach a maximum. But here the available tensions have been used up. The earth rounds this portion of the curve and retreats from the sun. Tensions are now stored up, but vis viva is lost, to be again restored at the expense of the complementary force on the opposite side of the curve. Thus beats the heart of the universe, but without increase or diminution of its total stock of force.

I have thus far tried to steer clear amid confusion, by fixing the mind of the reader upon things rather than upon names. But good names are essential; and here, as yet, we are not provided with such. We have had the force of gravity and living force--two utterly distinct things. We have had pulls and tensions; and we might have had the force of heat, the force of light, the force of magnetism, or the force of electricity--all of which terms have been employed more or less loosely by writers on physics. This confusion is happily avoided by the introduction of the term 'energy,' which embraces both tension and vis viva. Energy is possessed by bodies already in motion; it is then actual, and we agree to call it actual or dynamic energy. It is our old vis viva. On the other hand, energy is possible to bodies not in motion, but which, in virtue of attraction or repulsion, possess a power of motion which would realise itself if all hindrances were removed. Looking, for example, at gravity; a body on the earth's surface in a position from which it cannot fall to a lower one possesses no energy. It has neither motion nor power of motion. But the same body suspended at a height above the earth has a power of motion, though it may not have exercised it. Energy is possible to such a body, and we agree to call this potential energy. It consists of our old tensions. We, moreover, speak of the conservation of energy, instead of the conservation of force; and say that the sum of the potential and dynamic energies of the material universe is a constant quantity.

A body cast upwards consumes the actual energy of projection, and lays up potential energy. When it reaches its utmost height all its actual energy is consumed, its potential energy being then a maximum. When it returns, there is a reconversion of the potential into the actual. A pendulum at the limit of its swing possesses potential energy; at the lowest point of its arc its energy is all actual. A patch of snow resting on a mountain slope has potential energy; loosened, and shooting down as an avalanche, it possesses dynamic energy. The pine-trees growing on the Alps have potential energy; but rushing down the Holzrinne of the woodcutters they possess actual energy. The same is true of the mountains themselves. As long as the rocks which compose them can fall to a lower level, they possess potential energy, which is converted into actual when the frost ruptures their cohesion and hands them over to the action of gravity. The stone avalanches of the Matterhorn and Weisshorn are illustrations in point. The hammer of the great bell of Westminster, when raised before striking, possesses potential energy; when it falls, the energy becomes dynamic; and after the stroke, we have the rhythmic play of potential and dynamic in the vibrations of the bell. The same holds good for the molecular oscillations of a heated body. An atom is driven against its neighbour, and recoils. The ultimate amplitude of the recoil being attained, the motion of the atom in that direction is checked, and for an instant its energy is all potential. It is then drawn towards its neighbour with accelerated speed; thus, by attraction, converting its potential into dynamic energy. Its motion in this direction is also finally checked, and again, for an instant, its energy is all potential. It once more retreats, converting, by repulsion, its potential into dynamic energy, till the latter attains a maximum, after which it is again changed into potential energy. Thus, what is true of the earth, as she swings to and fro in her yearly journey round the sun, is also true of her minutest atom. We have wheels within wheels, and rhythm within rhythm.

When a body is heated, a change of molecular arrangement always occurs, and to produce this change heat is consumed. Hence, a portion only of the heat communicated to the body remains as dynamic energy. Looking back on some of the statements made at the beginning of this article, now that our knowledge is more extensive, we see the necessity of qualifying them. When, for example, two bodies clash, heat is generated; but the heat, or molecular dynamic energy, developed at the moment of collision, is not the exact equivalent of the sensible dynamic energy destroyed. The true equivalent is this heat, plus the potential energy conferred upon the molecules by the placing of greater distances between them. This molecular potential energy is afterwards, on the cooling of the body, converted into heat.

Wherever two atoms capable of uniting together by their mutual attractions exist separately, they form a store of potential energy. Thus our woods, forests, and coal-fields on the one hand, and our atmospheric oxygen on the other, constitute a vast store of energy of this kind--vast, but far from infinite. We have, besides our coal-fields, metallic bodies more or less sparsely distributed through the earth's crust. These bodies can be oxydised; and hence they are, so far as they go, stores of energy. But the attractions of the great mass of the earth's crust are already satisfied, and from them no further energy can possibly be obtained. Ages ago the elementary constituents of our rocks clashed together and produced the motion of heat, which was taken up by the aether and carried away through stellar space. It is lost for ever as far as we are concerned. In those ages the hot conflict of carbon, oxygen, and calcium produced the chalk and limestone hills which are now cold; and from this carbon, oxygen, and calcium no further energy can be derived. So it is with almost all the other constituents of the earth's crust. They took their present form in obedience to molecular force; they turned their potential energy into dynamic, and yielded it as radiant heat to the universe, ages before man appeared upon this planet. For him a residue of potential energy remains, vast, truly, in relation to the life and wants of an individual, but exceedingly minute in comparison with the earth's primitive store.

To sum up. The whole stock of energy or working-power in the world consists of attractions, repulsions, and motions. If the attractions and repulsions be so circumstanced as to be able to produce motion, they are sources of working-power, but not otherwise. As stated a moment ago, the attraction exerted between the earth and a body at a distance from the earth's surface, is a source of working-power; because the body can be moved by the attraction, and in falling can perform work. When it rests at its lowest level it is not a source of power or energy, because it can fall no farther. But though it has ceased to be a source of energy, the attraction of gravity still acts as a force, which holds the earth and weight together.

The same remarks apply to attracting atoms and molecules. As long as distance separates them, they can move across it in obedience to the attraction; and the motion thus produced may, by proper appliances, be caused to perform mechanical work. When, for example, two atoms of hydrogen unite with one of oxygen, to form water, the atoms are first drawn towards each other--they move, they clash, and then by virtue of their resiliency, they recoil and quiver. To this quivering motion we give the name of heat. This atomic vibration is merely the redistribution of the motion produced by the chemical affinity; and this is the only sense in which chemical affinity can be said to be converted into heat. We must not imagine the chemical attraction destroyed, or converted into anything else. For the atoms, when mutually clasped to form a molecule of water, are held together by the very attraction which first drew them towards each other. That which has really been expended is the pull exerted through the space by which the distance between the atoms has been diminished.

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