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Fragments of Science: a Series of Detached Essays, Addresses, and Reviews. V. 1-2 · John Tyndall — chapter 26 of 79 · ~1,990 words · public domain

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4 Off Cabreta Point Black-indigo Much less thick, very pure

5 Off Tarifa Undecided Thicker than No. 4

6 Beyond Tarifa Cobalt-blue Much purer than No. 5

7 Twelve miles Yellow-green Very thick from Cadiz

8 Cadiz Harbour Yellow-green Exceedingly thick

9 Fourteen miles Yellow-green Thick, but less so from Cadiz

10 Fourteen miles Bright green Much less thick from Cadiz

11 Between Capes Deep Indigo Very little matter, St. Mary and Vincent very pure

12 Off the Burlings. Strong green Thick, with fine matter

13 Beyond the Burlings Indigo Very little matter, pure

14 Off Cape Finisterre Undecided Less pure

15 Bay of Biscay Black-indigo Very little matter, very pure

16 Bay of Biscay Indigo Very fine matter. Iridescent

17 Off Ushant Dark green A good deal of matter

18 Off St. Catherine's Yellow-green Exceedingly thick

19 Spithead Green Exceedingly thick

Here we have three specimens of water, described as green, a clearer green, and bright green, taken in Gibraltar Harbour, at a point two miles from the harbour, and off Cabreta Point. The home examination showed the first to be thick with suspended matter, the second less thick, and the third still less thick. Thus the green brightened as the suspended matter diminished in amount.

Previous to the fourth observation our excellent navigating lieutenant, Mr. Brown, steered along the coast, thus avoiding the adverse current which sets in, through the Strait, from the Atlantic to the Mediterranean. He was at length forced to cross the boundary of the Atlantic current, which was defined with extraordinary sharpness. On the one side of it the water was a vivid green, on the other a deep blue. Standing at the bow of the ship, a bottle could be filled with blue water, while at the same moment a bottle cast from the stern could be filled with green water. Two bottles were secured, one on each side of this remarkable boundary. In the distance the Atlantic had the hue called ultra-marine; but looked fairly down upon, it was of almost inky blackness--black qualified by a trace of indigo.

What change does the home examination here reveal? In passing to indigo, the water becomes suddenly augmented in purity, the suspended matter becoming suddenly less. Off Tarifa, the deep indigo disappears, and the sea is undecided in colour. Accompanying this change, we have a rise in the quantity of suspended matter. Beyond Tarifa, we change to cobalt-blue, the suspended matter falling at the same time in quantity. This water is distinctly purer than the green. We approach Cadiz, and at twelve miles from the city get into yellow-green water; this the London examination shows to be thick with suspended matter. The same is true of Cadiz harbour, and also of a point fourteen miles from Cadiz in the homeward direction. Here there is a sudden change from yellow-green to a bright emerald-green, and accompanying the change a sudden fall in the quantity of suspended matter. Between Cape St. Mary and Cape St: Vincent the water changes to the deepest indigo, a further diminution of the suspended matter being the concomitant phenomenon.

We now reach the remarkable group of rocks called the Burlings, and find the water between the shore and the rocks a strong green; the home examination shows it to be thick with fine matter. Fifteen or twenty miles beyond the Burlings we come again into indigo water, from which the suspended matter has in great part disappeared. Off Cape Finisterre, about the place where the 'Captain' went down, the water becomes green, and the home examination pronounces it to be thicker. Then we enter the Bay of Biscay, where the indigo resumes its power, and where the home examination shows the greatly augmented purity of the water. A second specimen of water, taken from the Bay of Biscay, held in suspension fine particles of a peculiar kind; the size of them was such as to render the water richly iridescent. It showed itself green, blue, or salmon-coloured, according to the direction of the line of vision. Finally, we come to our last two bottles, the one taken opposite St. Catherine's lighthouse, in the Isle of Wight, the other at Spithead. The sea at both these places was green, and both specimens, as might be expected, were pronounced by the home examination to be thick with suspended matter.

Two distinct series of observations are here referred to--the one consisting of direct observations of the colour of the sea, conducted during the voyage from Gibraltar to Portsmouth: the other carried out in the laboratory of the Royal Institution. And here it is to be noted that in the home examination I never knew what water was placed in my hands. The labels, with the names of the localities written upon them, had been tied up, all information regarding the source of the water being thus held back. The bottles were simply numbered, and not till all of them had been examined, and described, were the labels opened, and the locality and sea-colour corresponding to the various specimens ascertained. The home observations, therefore, must have been perfectly unbiassed, and they clearly establish the association of the green colour with fine suspended matter, and of the ultramarine colour, and more especially of the black-indigo hue of the Atlantic, with the comparative absence of such matter.

So much for mere observation; but what is the cause of the dark hue of the deep ocean? [Footnote: A note, written to me on October 22, by my friend Canon Kingsley, contains the following reference to this point: 'I have never seen the Lake of Geneva, but I thought of the brilliant dazzling dark blue of the mid-Atlantic under the sunlight, and its black-blue under cloud, both so solid that one might leap off the sponson on to it without fear; this was to me the most wonderful thing which I saw on my voyages to and from the West Indies.']

A preliminary remark or two will clear our way towards an explanation. Colour resides in white light, appearing when any constituent of the white light is withdrawn. The hue of a purple liquid, for example, is immediately accounted for by its action on a spectrum. It cuts out the yellow and green, and allows the red and blue to pass through. The blending of these two colours produces the purple. But while such a liquid attacks with special energy the yellow and green, it enfeebles the whole spectrum. By increasing the thickness of the stratum we may absorb the whole of the light. The colour of a blue liquid is similarly accounted for. It first extinguishes the red; then, as the thickness augments, it attacks the orange, yellow, and green in succession; the blue alone finally remaining. But even it might be extinguished by a sufficient depth of 'the liquid.

And now we are prepared for a brief, but tolerably complete, statement of that action of sea-water upon light, to which it owes its darkness. The spectrum embraces three classes of rays--the thermal, the visual, and the chemical. These divisions overlap each other; the thermal rays are in part visual, the visual rays in part chemical, and vice versa. The vast body of thermal rays lie beyond the red, being invisible. These rays are attacked with exceeding energy by water. They are absorbed close to the surface of the sea, and are the great agents in evaporation. At the same time the whole spectrum suffers enfeeblement; water attacks all its rays, but with different degrees of energy. Of the visual rays, the red are first extinguished. As the solar beam plunges deeper into the sea, orange follows red, yellow follows orange, green follows yellow, and the various shades of blue, where the water is deep enough, follow green. Absolute extinction of the solar beam would be the consequence if the water were deep and uniform. If it contained no suspended matter, such water would be as black as ink. A reflected glimmer of ordinary light would reach us from its surface, as it would from the surface of actual ink; but no light, hence no colour, would reach us from the body of the water.

In very clear and deep sea-water this condition is approximately fulfilled, and hence the extraordinary darkness of such water. The indigo, already referred to, is, I believe, to be ascribed in part to the suspended matter, which is never absent, even in the purest natural water; and in part to the slight reflection of the light from the limiting surfaces of strata of different densities. A modicum of light is thus thrown back to the eye, before the depth necessary to absolute extinction has been attained. An effect precisely similar occurs under the moraines of glaciers. The ice here is exceptionally compact, and, owing to the absence of the internal scattering common in bubbled ice, the light plunges into the mass, where it is extinguished, the perfectly clear ice presenting an appearance of pitchy blackness. [Footnote: I learn from a correspondent that certain Welsh tarns, which are reputed bottomless, have this inky hue.]

The green colour of the sea has now to be accounted for; and here, again, let us fall back upon the sure basis of experiment. A strong white dinner-plate had a lead weight securely fastened to it. Fifty or sixty yards of strong hempen line were attached to the plate.

My assistant, Thorogood, occupied a boat, fastened as usual to the davits of the "Urgent," while I occupied a second boat nearer the stern of the ship. He cast the plate as a mariner heaves the lead, and by the time it reached me it had sunk a considerable depth in the water. In all cases the hue of this plate was green. Even when the sea was of the darkest indigo, the green, was vivid and pronounced. I could notice the gradual deepening of the colour as the plate sank, but at its greatest depth, even in indigo water, the colour was still a blue-green. [Footnote: In no case, of course, is the green pure, but a mixture of green and blue.]

Other observations confirmed this one. The "Urgent" is a screw steamer, and right over the blades of the screw was an orifice called the screw-well, through which one could look from the poop down upon the screw. The surface-glimmer, which so pesters the eye, was here in a great measure removed. Midway down, a plank crossed the screw-well from side to side; on this I placed myself and observed the action of the screw underneath. The eye was rendered sensitive by the moderation of the light; and, to remove still further all disturbing causes, Lieutenant Walton had a sail and tarpaulin thrown over the mouth of the well. Underneath this I perched myself on the plank and watched the screw. In an indigo sea the play of colour was indescribably beautiful, and the contrast between the water, which had the screw-blades, and that which had the bottom of the ocean, as a background, was extraordinary. The one was of the most brilliant green, the other of the deepest ultramarine. The surface of the water above the screw-blade was always ruffled. Liquid lenses were thus formed, by which the coloured light was withdrawn from some places and concentrated upon others, the water flashing with metallic lustre. The screw-blades in this case played the part of the dinner-plate in the former case, and there were other instances of a similar kind. The white bellies of porpoises showed the green hue, varying in intensity as the creatures swung to and fro between the surface and the deeper water. Foam, at a certain depth below the surface, was also green. In a rough sea the light which penetrated the summit of a wave sometimes reached the eye, a beautiful green cap being thus placed upon the wave, even in indigo water.

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