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Fragments of Science: a Series of Detached Essays, Addresses, and Reviews. V. 1-2 · John Tyndall — chapter 17 of 79 · ~2,119 words · public domain

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I had noticed, as before stated, that as the clouds formed in the experimental tube became denser, the polarisation of the light discharged at right angles to the beam became weaker, the direction of maximum polarisation becoming oblique to the beam. Experiments on the fumes of chloride of ammonium gave me also reason to suspect that the position of the neutral point was not constant, but that it varied with the density of the illuminated fumes.

The examination of these questions led to the following new and remarkable results: The laboratory being well filled with the fumes of incense, and sufficient time being allowed for their uniform diffusion, the electric beam was sent through the smoke. From the track of the beam polarised light was discharged; but the direction of maximum polarisation, instead of being perpendicular, now enclosed an angle of only 12° or 13° with the axis of the beam.

A neutral point, with complementary effects at opposite sides of it, was also exhibited by the beam. The angle enclosed by the axis of the beam, and a line drawn from the neutral point to the observer's eye, measured in the first instance 66°.

The windows of the laboratory were now opened for some minutes, a portion of the incense-smoke being permitted to escape. On again darkening the room and turning on the light, the line of vision to the neutral point was found to enclose, with the axis of the beam, an angle of 63°.

The windows were again opened for a few minutes, more of the smoke being permitted to escape. Measured as before, the angle referred to was found to be 54°.

This process was repeated three additional times the neutral point was found to recede lower and lower down the beam, the angle between a line drawn from the eye to the neutral point and the axis of the beam falling successively from 54° to 49°, 43° and 33°.

The distances, roughly measured, of the neutral point from the lamp, corresponding to the foregoing series of observations, were these:

1st observation 2 feet 2 inches.

2nd observation 2 feet 6 inches.

3rd observation 2 feet 10 inches.

4th observation 3 feet 2 inches.

5th observation 3 feet 7 inches.

6th observation 4 feet 6 inches.

At the end of this series of experiments the direction of maximum polarisation had again become normal to the beam.

The laboratory was next filled with the fumes of gunpowder. In five successive experiments, corresponding to five different densities of the gunpowder-smoke, the angles enclosed between the line of vision to the neutral point and the axis of the beam, were 63 degrees, 50°, 47°, 42°, and 38° respectively.

After the clouds of gunpowder had cleared away, the laboratory was filled with the fumes of common resin, rendered so dense as to be very irritating to the lungs. The direction of maximum polarisation enclosed, in this case, an angle of 12°, or thereabouts, with the axis of the beam. Looked at, as in the former instances, from a position near the electric lamp, no neutral point was observed throughout the entire extent of the beam.

When this beam was looked at normally through the selenite and Nicol, the ring-system, though not brilliant, was distinct. Keeping the eye upon the plate of selenite, and the line of vision perpendicular, the windows were opened, the blinds remaining undrawn. The resinous fumes slowly diminished, and as they did so the ring-system became paler. It finally disappeared. Continuing to look in the same direction, the rings revived, but now the colours were complementary to the former ones. The neutral point had passed me in its motion down the beam, consequent upon the attenuation of the fumes of resin.

With the fumes of chloride of ammonium substantially the same results were obtained. Sufficient, however, has been here stated to illustrate the variability of the position of the neutral point. [Footnote: Brewster has proved the variability of the position of the neutral point for skylight with the sun's altitude, a result obviously connected with the foregoing experiments.]

By a puff of tobacco-smoke, or of condensed steam, blown into the illuminated beam, the brilliancy of the selenite colours may be greatly enhanced. But with different clouds two different effects are produced. Let the ring-system observed in the common air be brought to its maximum strength, and then let an attenuated cloud of chloride of ammonium be thrown into the beam at the point looked at; the ring system flashes out with augmented brilliancy, but the character of the polarisation remains unchanged. This is also the case when phosphorus, or sulphur, is burned underneath the beam, so as to cause the fine particles of phosphorus or of sulphur to rise into the light. With the sulphur-fumes the brilliancy of the colours is exceedingly intensified; but in none of these cases is there any change in the character of the polarisation.

But when a puff of the fumes of hydrochloric acid, hydriodic acid, or nitric acid is thrown into the beam, there is a complete reversal of the selenite tints. Each of these clouds twists the plane of polarisation 90°, causing the centre of the ring-system to change from black to white, and the rings themselves to emit their complementary colours. [Footnote: Sir John Herschel suggested to me that this change of the polarisation from positive to negative may indicate a change from polarisation by reflection to polarisation by refraction. This thought repeatedly occurred to me while looking at the effects; but it will require much following up before it emerges into clearness.]

Almost all liquids have motes in them sufficiently numerous to polarise sensibly the light, and very beautiful effects may be obtained by simple artificial devices. When, for example, a cell of distilled water is placed in front of the electric lamp, and a thin slice of the beam is permitted to pass through it, scarcely any polarised light is discharged, and scarcely any colour produced with a plate of selenite. But if a bit of soap be agitated in the water above the beam, the moment the infinitesimal particles reach the light the liquid sends forth laterally almost perfectly polarised light; and if the selenite be employed, vivid colours flash into existence. A still more brilliant result is obtained with mastic dissolved in a great excess of alcohol.

The selenite rings, in fact, constitute an extremely delicate test as to the collective quantity of individually invisible particles in a liquid. Commencing with distilled water, for example, a thick slice of light is necessary to make the polarisation of its suspended particles sensible. A much thinner slice suffices for common water; while, with Bruecke's precipitated mastic, a slice too thin to produce any sensible effect with most other liquids, suffices to bring out vividly the selenite colours.

3. THE SKY OF THE ALPS.

The vision of an object always implies a differential action on the retina of the observer. The object is distinguished from surrounding space by its excess or defect of light in relation to that space. By altering the illumination, either of the object itself or of its environment, we alter the appearance of the object. Take the case of clouds floating in the atmosphere with patches of blue between them. Anything that changes the illumination of either alters the appearance of both, that appearance depending, as stated, upon differential action.

Now the light of the sky, being polarised, may, as the reader of the foregoing pages knows, be in great part quenched by a Nicol's prism, while the light of a common cloud, being unpolarised, cannot be thus extinguished. Hence the possibility of very remarkable variations, not only in the aspect of the firmament, which is really changed, but also in the aspect of the clouds, which have that firmament as a background. It is possible, for example, to choose clouds of such a depth of shade that when the Nicol quenches the light behind them, they shall vanish, being undistinguishable from the residual dull tint which outlives the extinction of the brilliancy of the sky. A cloud less deeply shaded, but still deep enough, when viewed with the naked eye, to appear dark on a bright ground, is suddenly changed to a white cloud on a dark ground by the quenching of the light behind it. When a reddish cloud at sunset chances to float in the region of maximum polarisation, the quenching of the surrounding light causes it to flash with a brighter crimson. Last Easter eve the Dartmoor sky, which had just been cleansed by a snow-storm, wore a very wild appearance. Round the horizon it was of steely brilliancy, while reddish cumuli and cirri floated southwards. When the sky was quenched behind them these floating masses seemed like dull embers suddenly blown upon; they brightened like a fire.

In the Alps we have the most magnificent examples of crimson clouds and snows, so that the effects just referred to may be here studied under the best possible conditions. On August 23, 1869, the evening Alpenglow was very fine, though it did not reach its maximum depth and splendour. The side of the Weisshorn seen from the Bel Alp, being turned from the sun, was tinted mauve; but I wished to observe one of the rose-coloured buttresses of the mountain. Such a one was visible from a point a few hundred feet above the hotel. The Matterhorn also, though for the most part in shade, had a crimson projection, while a deep ruddy red lingered along its western shoulder. Four distinct peaks and buttresses of the Dom, in addition to its dominant head--all covered with pure snow--were reddened by the light of sunset. The shoulder of the Alphubel was similarly coloured, while the great mass of the Fletschorn was all a-glow, and so was the snowy spine of the Monte Leone.

Looking at the Weisshorn through the Nicol, the glow of its protuberance was strong or weak according to the position of the prism. The summit also underwent striking changes. In one position of the prism it exhibited a pale white against a dark background; in the rectangular position it was a dark mauve against a light background. The red of the Matterhorn changed in a similar manner; but the whole mountain also passed through wonderful changes of definition. The air at the time was filled with a silvery haze, in which the Matterhorn almost disappeared. This could be wholly quenched by the Nicol, and then the mountain sprang forth with astonishing solidity and detachment from the surrounding air. The changes of the Dom were still more wonderful. A vast amounts of light could be removed from the sky behind it, for it occupied the position of maximum polarisation. By a little practice with the Nicol it was easy to render the extinction of the light, or its restoration, almost instantaneous. When the sky was quenched, the four minor peaks and buttresses, and the summit of the Dom, together with the shoulder of the Alphubel, glowed as if set suddenly on fire. This was immediately dimmed by turning the Nicol through an angle of 90°. It was not the stoppage of the light of the sky behind the mountains alone which produced this startling effect; the air between them and me was highly opalescent, and the quenching of this intermediate glare augmented remarkably the distinctness of the mountains.

On the morning of August 24 similar effects were finely shown. At 10 A.M. all three mountains, the Dom, the Matterhorn, and the Weisshorn, were powerfully affected by the Nicol. But in this instance also, the line drawn to the Dom being very nearly perpendicular to the solar beams, the effects on this mountain were most striking. The grey summit of the Matterhorn, at the same time, could scarcely be distinguished from the opalescent haze around it; but when the Nicol quenched the haze, the summit became instantly isolated, and stood out in bold definition. It is to be remembered that in the production of these effects the only things changed are the sky behind, and the luminous haze in front of the mountains; that these are changed because the light emitted from the sky and from the haze is plane polarised light, and that the light from the snows and from the mountains, being sensibly unpolarised, is not directly affected by the Nicol. It will also be understood that it is not the interposition of the haze as an opaque body that renders the mountains indistinct, but that it is the light of the haze which dims and bewilders the eye, and thus weakens the definition of objects seen through it.

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