Part 18

Libr. 2do Cap. 34.

EXPERIMENT XLVI.

We have often taken notice, as of a remarkable thing, that Metalls as they appear to the Eye, before they come to be farther alter'd by other Bodyes, do exhibit Colours very different from those which the Fire and the Menstruum, either apart, or both together, do produce in them; especially considering that these Metalline Bodyes are after all these disguises reducible not only to their former Metalline Consistence and other more radical properties, but to their Colour too, as if Nature had given divers Metalls to each of them a double Colour, an External, and an Internal; But though upon a more attentive Consideration of this difference of Colours, it seem'd probable to me, that divers (for I say not all) of those Colours which we have just now call'd Internal, are rather produc'd by the Coalition of Metalline Particles with those of the Salts, or other Bodyes employ'd to work on them, than by the bare alteration of the parts of the Metalls themselves: and though therefore we may call the obvious Colours, Natural or Common, & the others Adventitious, yet because such changes of Colours, from whatsoever cause they be resolv'd to proceed may be properly enough taken in to illustrate our present Subject, we shall not scruple to take notice of some of them, especially because there are among them such as are produc'd without the intervention of Saline Menstruums. Of the Adventitious Colours of Metalline Bodies the Chief sorts seem to be these three. The first, such Colours as are produc'd without other Additaments by the Action of the fire upon Metalls. The next such as emerge from the Coalition of Metalline Particles with those of some Menstruum imploy'd to Corrode a Metall or Precipitate it; And the last, The Colours afforded by Metalline Bodyes either Colliquated with, or otherwise Penetrating into, other Bodies, especially fusible ones. But these (Pyrophilus,) are only as I told you, the Chief sorts of the adventitious Colours of Metalls, for there may others belong to them, of which I shall hereafter have occasion to take notice of some, and of which also there possibly may be others that I never took notice of.

And to begin with the first sort of Colours, 'tis well enough known to Chymists, that Tin being Calcin'd by fire alone is wont to afford a White Calx, and Lead Calcin'd by fire alone affords that most Common Red-Powder we call Minium: Copper also Calcin'd per se, by a long or violent fire, is wont to yield (as far as I have had occasion to take notice of it) a very Dark or Blackish Powder; That Iron likewise may by the Action of Reverberated flames be turn'd into a Colour almost like that of Saffron, may be easily deduc'd from the Preparation of that Powder, which by reason of its Colour and of the Metall 'tis made of is by Chymists call'd, Crocus Martis per se. And that Mercury made by the stress of Fire, may be turn'd into a Red Powder, which Chymists call Precipitate per se, I elsewhere more particularly declare.

Annotation I.

It is not unworthy the Admonishing you, (Pyrophilus,) and it agrees very well with our Conjectures about the dependence of the change of a Body's Colour upon that of its Texture, that the same Metall may by the successive operation of the fire receive divers Adventitious Colours, as is evident in Lead, which before it come to so deep a Colour as that of Minium, may pass through divers others.

Annotation II.

Not only the Calces, but the Glasses of Metalls, Vitrify'd per se, may be of Colours differing from the Natural or Obvious Colour of the Metall; as I have observ'd in the Glass of Lead, made by long exposing Crude Lead to a violent fire, and what I have observ'd about the Glass or Slagg of Copper, (of which I can show you some of an odd kind of Texture,) may be elsewhere more conveniently related. I have likewise seen a piece of very Dark Glass, which an Ingenious Artificer that show'd it me profess'd himself to have made of Silver alone by an extreme Violence (which seems to be no more than is needfull) of the fire.

Annotation III.

Minerals also by the Action of the Fire may be brought to afford Colours very differing from their own, as I not long since noted to you about the variously Colour'd Flowers of Antimony, to which we may add the Whitish Grey-Colour of its Calx, and the Yellow or Reddish Colour of the Glass, where into that Calx may be flux'd.

And I remember, that I elsewhere told you, that Vitriol Calcin'd with a very gentle heat, and afterwards with higher and higher degrees of it, may be made to pass through several Colours before it descends to a Dark Purplish Colour, whereto a strong fire is wont at length to reduce it. But to insist on the Colours produc'd by the Operation of fire upon several Minerals would take up farr more time than I have now to spare.

EXPERIMENT XLVII.

The Adventitious Colours produc'd upon Metalls, or rather with them, by Saline Liquors, are many of them so well known to Chymists, that I would not here mention them, but that besides a not un-needed Testimony, I can add something of my own, to what I shall repeat about them, and divers Experiments which are familiar to Chymists, are as yet unknown to the greatest part of Ingenious Men.

That Gold dissolv'd in Aqua Regia ennobles the Menstruum with its own Colour, is a thing that you cannot (Pyrophilus,) but have often seen. The Solutions of Mercury in Aqua-fortis are not generally taken notice of, to give any notable Tincture to the Menstruum; but sometimes when the Liquor first falls upon the Quick Silver, I have observ'd a very remarkable, though not durable, Greenness, or Blewness to be produc'd, which is a Phænomenon not unfit for you to consider, though I have not now the leisure to discourse upon it. Tin Corroded by Aqua-fortis till the Menstruum will work no farther on it, becomes exceeding White, but as we elsewhere note, does very easily of it self acquire the consistence, not of a Metalline Calx, but of a Coagulated matter, which we have observ'd with pleasure to look so like, either to curdled Milk, or curdled Whites of Eggs, that a person unacquainted with such Solutions may easily be mistaken in it. But when I purposely prepar'd a Menstruum that would dissolve it as Aqua-fortis dissolves Silver, and not barely Corrode it, and quickly let it fall again, I remember not that I took notice of any particular Colour in the Solution, as if the more Whitish Metalls did not much Tinge their Menstruums, though the conspicuously Colour'd Metalls as Gold, and Copper, do. For Lead dissolv'd in Spirit of Vinegar or Aqua-fortis gives a Solution cleer enough, and if the Menstruum be abstracted appears either Diaphanous or White. Of the Colour of Iron we have elsewhere said something: And 'tis worth noting, that though if that Metall be dissolv'd in oyl of Vitriol diluted with water, it affords a Salt or Magistery so like in colour, as well as some other Qualities, to other green Vitriol, that Chymists do not improperly call it Vitriolum Martis; yet I have purposely try'd, that, by changing the Menstruum, and pouring upon the filings of Steel, instead of oyl of Vitriol, Aqua Fortis, (whereof as I remember, I us'd 4 parts to one of the Metall) I obtain'd not a Green, but a Saffron Colour Solution; or rather a thick Liquor of a deep but yellowish Red. Common Silver, such as is to be met with in Coines, being dissolv'd in Aqua fortis, yields a Solution tincted like that of Copper, which is not to be wondred at, because in the coining of Silver, they are wont (as we elsewhere particularly inform you) to give it an Allay of Copper, and that which is sold in shops for refined silver, is not (so far as we have tryed) so perfectly free from that ignobler Metall, but that a Solution of It in Aqua fortis, will give a Venereal Tincture to the Menstruum. But we could not observe upon the solution of some Silver, which was perfectly refin'd, (such as some that we have, from which 8 or 10 times its weight of Lead has been blown off) that the Menstruum though held against the Light in a Crystal Vial did manifestly disclose any Tincture, only it seem'd sometimes not to be quite destitute of a little, but very faint Blewishness.

But here I must take notice, that of all the Metalls, there is not any which doth so easily and constantly disclose its unobvious colour as Copper doth. For not only in acid Menstruums as Aqua Fortis and Spirit of Vinegar, it gives a Blewish green solution, but if it be almost any way corroded, it appears of one of those two colours, as may be observ'd in Verdigreese made several wayes, in that odd preparation of Venus, which we elsewhere teach you to make with Sublimate, and in the common Vitriols of Venus deliver'd by Chymists; and so constant is the disposition of Copper, notwithstanding the disguise Artists put upon it, to disclose the colour we have been mentioning, that we have by forcing it up with Sal Armoniack obtain'd a Sublimate of a Blewish Colour. Nay a famous Spagyrist affirms, that the very Mercury of it is green, but till he teach us an intelligible way of making such a Mercury, we must content ourselves to inform you, that we have had a Cupreous Body, that was Præcipitated out of a distill'd Liquor, that seem'd to be the the Sulphur of Venus, and seem'd even when flaming, of a Greenish Colour. And indeed Copper is a Metall so easily wrought upon by Liquors of several kinds, that I should tell you, I know not any Mineral, that will concurr to the production of such a variety of Colours as Copper dissol'd in several Menstruums, as Spirit of Vinegar, Aqua fortis, Aqua Regis, Spirit of Nitre, of Urine, of Soot, Oyls of several kinds, and I know not how many other Liquors, if the variety of somewhat differing colours (that Copper will be made to assume, as it is wrought upon by several Liquors) were not comprehended within the Limits of Greenish Blew, or Blewish Green.

And yet I must advertise you (Pyrophilus) that being desirous to try if I could not make with crude Copper a Green Solution without the Blewishness that is wont to accompany its Vulgar Solutions, I bethought my self of using two Menstruums, which I had not known imploy'd to work on this Metall, and which I had certain Reasons to make Tryal of, as I successfully did. The one of these Liquors (if I much misremember not) was Spirit of Sugar distill'd in a Retort, which must be warily done, (if you will avoid breaking your glasses) and the other, Oyl or Spirit of Turpentine, which affords a fine Green Solution that is useful to me on several occasions. And yet to shew that the adventitious colour may result, as well from the true and permanent Copper it self, as the Salts wherewith 'tis corroded, I shall add, that if you take a piece of good Dantzick Copperis, or any other Vitriol wherein Venus is prædominant, and having moistened it in your Mouth, or with fair water, rubb it upon a whetted knife, or any other bright piece of Steel or Iron, it will (as we have formerly told you) present'y stain the Steel with a Reddish colour, like that of Copper, the reason of which, we must not now stay to inquire.

Annotation I.

I presume you may have taken notice (Pyrophilus) that I have borrowed some of the Instances mention'd in this 47th Experiment, from the Laboratories of Chymists, and because in some (though very few) other passages of this Essay, I have likewise made use of Experiments mention'd also by some Spagyrical Writers, I think it not amiss to represent to you on this Occasion once for all, some things besides those which I intimated in the præamble of this present Experiment; For besides, that 'tis very allowable for a Writer to repeat an Experiment which he invented not, in case he improve it; And besides that many Experiments familiar to Chymists are unknown to the generality of Learned Men, who either never read Chymical processes, or never understood their meaning, or never durst believe them; besides these things, I say, I shall represent, That, as to the few Experiments I have borrowed from the Chymists, if they be very Vulgar, 'twould perhaps be difficult to ascribe each of them its own Author, and 'tis more than the generality of Chymists themselves can do: and if they be not of very known and familiar practise among them, unless the Authors wherein I found them had given me cause to believe, themselves had try'd them, I know not why I might not set them down, as a part of the Phænomena of Colours which I present you; Many things unanimously enough deliver'd as matters of fact by (I know not how many Chymical Writers) being not to be rely'd on, upon the single Authority of such Authors: For Instance, as some Spagyrists deliver (perhaps amongst several deceitful processes) that Saccarum Saturni with Spirit of Turpentine will afford a Balsom, so Beguinus and many more tell us, that the same Concrete (Saccarum Saturni) will yield an incomparably fragrant Spirit, and a pretty Quantity of two several Oyles, and yet since many have complain'd, as well as I have done, that they could find no such odoriferous, but rather an ill-sented Liquor, and scarce any oyl in their Distillation of that sweet Vitriol, a wary person would as little build any thing on what they say of the former Experiment, as upon what they averr of the later, and therefore I scrupled not to mention this Red Balsom of which I have not seen any, (but what I made) among my other experiments about redness.

Annot. II.

We have sometimes had the Curiosity to try what Colours Minerals, as Tinglass, Antimony, Spelter, &c. would yield in several Menstruums, nor have we forborn to try the Colours of stones, of which that famous one, (which Helmont calls Paracelsus's Ludus) though it be digg'd out of the Earth and seem a true stone, has afforded in Menstruums capable to dissolve so solid a stone, sometimes a Yellowish, sometimes a Red solution of both which I can show you. But though I have from Minerals obtain'd with several Menstruums very differing Colours, and some such as perhaps you would be surpriz'd to see drawn from such Bodies: yet I must now pass by the particulars, being desirous to put an End to this Treatise, before I put an end to your Patience and my own.

Annotation III.

And yet before I pass to the next Experiment, I must put you in mind, that the Colours of Metals may in many cases be further alter'd by imploying, either præcipitating Salts, or other convenient Substances to act upon their Solutions. Of this you may remember, that I have given you several Instances already, to which may be added such as these, That if Quicksilver be dissolv'd in Aqua fortis, and Præcipitated out of the Solution, either with water impregnated with Sea salt, or with the spirit of that Concrete, it falls to the Bottom in the form of a white powder, whereas if it be Præcipitated with an Alcaly, it will afford a Yellowish or tawny powder, and if there be no Præcipitation made, and the Menstruum be drawn off with a convenient fire, the corroded Mercury will remain in the bottom, in the form of a substance that may be made to appear of differing Colours by differing degrees of Heat; As I remember that lately having purposely abstracted Aqua fortis from some Quicksilver that we had dissolv'd in it, so that there remain'd a white Calx, exposing that to several degrees of Fire, and afterwards to a naked one, we obtain'd some new Colours, and at length the greatest part of the Calx lying at the Bottome of the Vial, and being brought partly to a Deep Yellow, and partly to a Red Colour, the rest appear'd elevated to the upper part and neck of the Vial, some in the form of a Reddish, and some of an Ash-Colour Sublimate. But of the differing Colours which by differing wayes and working of Quick Silver with Fire, and Saline Bodies, may be produc'd in Precipitates, I may elsewhere have occasion to take further notice. I also told you not long since, that if you corrode Quick-silver with Oyl of Vitriol instead of Aqua-fortis, and abstract the Menstruum, there will remain a White Calx which by the Affusion of Fair Water presently turns into a Lemmon Colour. And ev'n the Succedaneum to a Menstruum may sometimes serve the turn to change the Colours of a Metal. The lovely Red which Painters call Vermillion, is made of Mercury, which is of the Colour of Silver, and of Brimstone which is of Kin to that of Gold, Sublim'd up together in a certain proportion, as is vulgarly known to Spagyrists.

EXPERIMENT XLVIII.

The third chief sort of the Adventitious Colours of Metals, is, that which is produc'd by associating them (especially when Calcin'd) with other fusible Bodies, and Principally Venice, and other fine Glass devoid of Colour.

I have formerly given you an Example, whereby it may appear, that a Metal may impart to Glass a Colour much differing from its own, when I told you, how with Silver, I had given Glass a lovely Golden Colour. And I shall now add, that I have Learn'd from one of the Chief Artificers that sells Painted Glass, that those of his Trade Colour it Yellow with a preparation of the Calx of Silver. Though having lately had occasion among other Tryals to mingle a few grains of Shell-silver (such as is imploy'd with the Pensil and Pen) with a convenient proportion of powder'd Crystal Glass, having kept them two or three hours in fusion, I was surpriz'd to find the Colliquated Mass to appear upon breaking the Crucible of a lovely Saphirine Blew, which made me suspect my Servant might have brought me a wrong Crucible, but he constantly affirm'd it to be the same wherein the Silver was put, and considerable Circumstances countenanc'd his Assertion, so that till I have opportunity to make farther Tryal, I cannot but suspect, either that Silver which is not (which is not very probable) brought to a perfect Fusion and Colliquation with Glass, may impart to it other Colours than when Neal'd upon it, or else (which is less unlikely) that though Silver Beaters usually chuse the finest Coyn they can get, as that which is most extensive under the Hammer, yet the Silver-leaves of which this Shel-silver was made, might retain so much Copper as to enable it to give the predominant tincture to the Glass.

For, I must proceed to tell you (Pyrophilus) as another instance of the Adventitious Colours of Metals, that which is something strange, Namely, That though Copper Calcin'd per se affords but a Dark and basely Colour'd Calx, yet the Glassmen do with it, as themselves inform me, Tinge their Glass green. And I remember, that when once we took some crude Copper, and by frequent Ignition quenching it in Water had reduc'd it to a Dark and Ill-colour'd Powder, and afterward kept it in Fusion in about a 100. times its weight of fine Glass, we had, though not a Green, yet a Blew colour'd Mass, which would perhaps have been Green, if we had hit right upon the Proportion of the Materials, and the Degree of Fire, and the Time wherein it ought to be kept in Fusion, so plentifully does that Metal abound in a Venerial Tincture, as Artists call it, and in so many wayes does it disclose that Richness. But though Copper do as we have said give somewhat near the like Colour to Glass, which it does to Aqua-fortis, yet it seems worth inquiry, whether those new Colours which Mineral Bodies disclose in melted Glass, proceed from the Coalition of the Corpuscles of the Mineral with the Particles of the Glass as such, or from the Action (excited or actuated by fire) of the Alcalizate Salt (which is a main Ingredient of Glass,) upon the Mineral Body, or from the concurrence of both these Causes, or else from any other. But to return to that which we were saying, we may observe that Putty made by calcining together a proportion of Tin and Lead, as it is it self a White Calx, so does it turn the Pitta di Crystallo (as the Glassmen call the matter of the Purer sort of Glass, wherewith it is Colliquated into a White Mass, which if it be opacous enough is employ'd, as we elsewhere declare, for White Amel. But of the Colours which the other Metals may be made to produce in Colourless Glass, and other Vitrifiable Bodies, that have native Colours of their own, I must leave you to inform your self upon Tryal, or at least must forbear to do it till another time, considering how many Annotations are to follow, upon what has in this and the two former Experiments been said already.

Annotation I.

When the Materials of Glass being melted with Calcin'd Tin, have compos'd a Mass Undiaphanous and White, this White Amel is as it were the Basis of all those fine Concretes that Goldsmiths and several Artificers imploy in the curious Art of Enamelling. For this White and Fusible substance will receive into it self, without spoyling them, the Colours of divers other Mineral substances, which like it will indure the fire.