Philosophical Transactions, 1834, pp. 584, 585.
1418. The fact, however, is, that disruptive discharge is favourable to itself. It is at the outset a case of tottering equilibrium: and if time be an element in discharge, in however minute a proportion (1436.), then the commencement of the act at any point favours its continuance and increase there, and portions of power will be discharged by a course which they would not otherwise have taken.
1419. The mere heating and expansion of the air itself by the first portion of electricity which passes, must have a great influence in producing this result.
1420. As to the result itself, we see its effect in every electric spark; for it is not the whole quantity which passes that determines the discharge, but merely that small portion of force which brings the deciding molecule (1370.) up to its maximum tension; then, when its forces are subverted and discharge begins, all the rest passes by the same course, from the influence of the favouring circumstances just referred to; and whether it be the electricity on a square inch, or a thousand square inches of charged glass, the discharge is complete. Hereafter we shall find the influence of this effect in the formation of brushes (1435.); and it is not impossible that we may trace it producing the jagged spark and the forked lightning.
* * * * *
1421. The characters of the electric spark in different gases vary, and the variation may be due simply to the effect of the heat evolved at the moment. But it may also be due to that specific relation of the particles and the electric forces which I have assumed as the basis of a theory of induction; the facts do not oppose such a view; and in that view the variation strengthens the argument for molecular action, as it would seem to show the influence of the latter in every part of the electrical effect (1423. 1454.).
1422. The appearances of the sparks in different gases have often been observed and recorded, but I think it not out of place to notice briefly the following results; they were obtained with balls of brass, (platina surfaces would have been better,) and at common pressures. In air, the sparks have that intense light and bluish colour which are so well known, and often have faint or dark parts in their course, when the quantity of electricity passing is not great. In nitrogen, they are very beautiful, having the same general appearance as in air, but have decidedly more colour of a bluish or purple character, and I thought were remarkably sonorous. In oxygen, the sparks were whiter than in air or nitrogen, and I think not so brilliant. In hydrogen, they had a very fine crimson colour, not due to its rarity, for the character passed away as the atmosphere was rarefied (1459.). Very little sound was produced in this gas; but that is a consequence of its physical condition. In carbonic acid gas, the colour was similar to that of the spark in air, but with a little green in it: the sparks were remarkably irregular in form, more so than in common air: they could also, under similar circumstances as to size of ball, &c., be obtained much longer than in air, the gas showing a singular readiness to cause the discharge in the form of spark. In muriatic acid gas, the spark was nearly white: it was always bright throughout, never presenting those dark parts which happen in air, nitrogen, and some other gases. The gas was dry, and during the whole experiment the surface of the glass globe within remained quite dry and bright. In coal gas, the spark was sometimes green, sometimes red, and occasionally one part was green and another red: black parts also occur very suddenly in the line of the spark, i.e. they are not connected by any dull part with bright portions, but the two seem to join directly one with the other.
See Van Marum's description of the Teylerian machine, vol. i. p. 112, and vol. ii. p. 196; also Ency. Britan., vol. vi., Article Electricity, pp. 505, 507.
Van Marum says they are about four times as large in hydrogen as in air. vol. i. p. 122.
Leslie. Cambridge Phil. Transactions, 267.
1423. These varieties of character impress my mind with a feeling, that they are due to a direct relation of the electric powers to the particles of the dielectric through which the discharge occurs, and are not the mere results of a casual ignition or a secondary kind of action of the electricity, upon the particles which it finds in its course and thrusts aside in its passage (1454.).
1424. The spark may be obtained in media which are far denser than air, as in oil of turpentine, olive oil, resin, glass, &c.: it may also be obtained in bodies which being denser likewise approximate to the condition of conductors, as spermaceti, water, &c. But in these cases, nothing occurs which, as far as I can perceive, is at all hostile to the general views I have endeavoured to advocate.
The electrical brush.
1425. The brush is the next form of disruptive discharge which I shall consider. There are many ways of obtaining it, or rather of exalting its characters; and all these ways illustrate the principles upon which it is produced. If an insulated conductor, connected with the positive conductor of an electrical machine, have a metal rod 0.3 of an inch in diameter projecting from it outwards from the machine, and terminating by a rounded end or a small ball, it will generally give good brushes; or, if the machine be not in good action, then many ways of assisting the formation of the brush can be resorted to; thus, the hand or any large conducting surface may be approached towards the termination to increase inductive force (1374.): or the termination may be smaller and of badly conducting matter, as wood: or sparks may be taken between the prime conductor of the machine and the secondary conductor to which the termination giving brushes belongs: or, which gives to the brushes exceedingly fine characters and great magnitude, the air around the termination may be rarefied more or less, either by heat or the air-pump; the former favourable circumstances being also continued.
1426. The brush when obtained by a powerful machine on a ball about 0.7 of an inch in diameter, at the end of a long brass rod attached to the positive prime conductor, had the general appearance as to form represented in fig. 117: a short conical bright part or root appeared at the middle part of the ball projecting directly from it, which, at a little distance from the ball, broke out suddenly into a wide brush of pale ramifications having a quivering motion, and being accompanied at the same time with a low dull chattering sound.
1427. At first the brush seems continuous, but Professor Wheatstone has shown that the whole phenomenon consists of successive intermitting discharges. If the eye be passed rapidly, not by a motion of the head, but of the eyeball itself, across the direction of the brush, by first looking steadfastly about 10° or 15° above, and then instantly as much below it, the general brush will be resolved into a number of individual brushes, standing in a row upon the line which the eye passed over; each elementary brush being the result of a single discharge, and the space between them representing both the time during which the eye was passing over that space, and that which elapsed between one discharge and another.
Philosophical Transactions, 1834, p. 586.
1428. The single brushes could easily be separated to eight or ten times their own width, but were not at the same time extended, i.e. they did not become more indefinite in shape, but, on the contrary, less so, each being more distinct in form, ramification, and character, because of its separation from the others, in its effects upon the eye. Each, therefore, was instantaneous in its existence (1436.). Each had the conical root complete (1426.).
1429. On using a smaller ball, the general brush was smaller, and the sound, though weaker, more continuous. On resolving the brush into its elementary parts, as before, these were found to occur at much shorter intervals of time than in the former case, but still the discharge was intermitting.
1430. Employing a wire with a round end, the brush was still smaller, but, as before, separable into successive discharges. The sound, though feebler, was higher in pitch, being a distinct musical note.
1431. The sound is, in fact, due to the recurrence of the noise of each separate discharge, and these, happening at intervals nearly equal under ordinary circumstances, cause a definite note to be heard, which, rising in pitch with the increased rapidity and regularity of the intermitting discharges, gives a ready and accurate measure of the intervals, and so may be used in any case when the discharge is heard, even though the appearances may not be seen, to determine the element of time. So when, by bringing the hand towards a projecting rod or ball, the pitch of the tone produced by a brushy discharge increases, the effect informs us that we have increased the induction (1374.), and by that means increased the rapidity of the alternations of charge and discharge.
1432. By using wires with finer terminations, smaller brushes were obtained, until they could hardly be distinguished as brushes; but as long as sound was heard, the discharge could be ascertained by the eye to be intermitting; and when the sound ceased, the light became continuous as a glow (1359. 1405. 1526-1543.).
1433. To those not accustomed to use the eye in the manner I have described, or, in cases where the recurrence is too quick for any unassisted eye, the beautiful revolving mirror of Professor Wheatstone will be useful for such developments of condition as those mentioned above. Another excellent process is to produce the brush or other luminous phenomenon on the end of a rod held in the hand opposite to a charged positive or negative conductor, and then move the rod rapidly from side to side whilst the eye remains still. The successive discharges occur of course in different places, and the state of things before, at, and after a single coruscation or brush can be exceedingly well separated.
Philosophical Transactions, 1834, pp. 581, 585.
1434. The brush is in reality a discharge between a bad or a non-conductor and either a conductor or another non-conductor. Under common circumstances, the brush is a discharge between a conductor and air, and I conceive it to take place in something like the following manner. When the end of an electrified rod projects into the middle of a room, induction takes place between it and the walls of the room, across the dielectric, air; and the lines of inductive force accumulate upon the end in greater quantity than elsewhere, or the particles of air at the end of the rod are more highly polarized than those at any other part of the rod, for the reasons already given (1374.). The particles of air situated in sections across these lines of force are least polarized in the sections towards the walls and most polarized in those nearer to the end of the wires (1369.): thus, it may well happen, that a particle at the end of the wire is at a tension that will immediately terminate in discharge, whilst in those even only a few inches off, the tension is still beneath that point. But suppose the rod to be charged positively, a particle of air A, fig. 118, next it, being polarized, and having of course its negative force directed towards the rod and its positive force outwards; the instant that discharge takes place between the positive force of the particle of the rod opposite the air and the negative force of the particle of air towards the rod, the whole particle of air becomes positively electrified; and when, the next instant, the discharged part of the rod resumes its positive state by conduction from the surface of metal behind, it not only acts on the particles beyond A, by throwing A into a polarized state again, but A itself, because of its charged state, exerts a distinct inductive act towards these further particles, and the tension is consequently so much exalted between A and B, that discharge takes place there also, as well as again between the metal and A.
1435. In addition to this effect, it has been shown, that, the act of discharge having once commenced, the whole operation, like a case of unstable equilibrium, is hastened to a conclusion (1370. 1418.), the rest of the act being facilitated in its occurrence, and other electricity than that which caused the first necessary tension hurrying to the spot. When, therefore, disruptive discharge has once commenced at the root of a brush, the electric force which has been accumulating in the conductor attached to the rod, finds a more ready discharge there than elsewhere, and will at once follow the course marked out as it were for it, thus leaving the conductor in a partially discharged state, and the air about the end of the wire in a charged condition; and the time necessary for restoring the full charge of the conductor, and the dispersion of the charged air in a greater or smaller degree, by the joint forces of repulsion from the conductor and attraction towards the walls of the room, to which its inductive action is directed, is just that time which forms the interval between brush and brush (1420. 1427. 1431. 1447.).
1436. The words of this description are long, but there is nothing in the act or the forces on which it depends to prevent the discharge being instantaneous, as far as we can estimate and measure it. The consideration of time is, however, important in several points of view (1418.), and in reference to disruptive discharge, it seemed from theory far more probable that it might be detected in a brush than in a spark; for in a brush, the particles in the line through which the discharge passes are in very different states as to intensity, and the discharge is already complete in its act at the root of the brush, before the particles at the extremity of the ramifications have yet attained their maximum intensity.
1437. I consider brush discharge as probably a successive effect in this way. Discharge begins at the root (1426. 1553.), and, extending itself in succession to all parts of the single brush, continues to go on at the root and the previously formed parts until the whole brush is complete; then, by the fall in intensity and power at the conductor, it ceases at once in all parts, to be renewed, when that power has risen again to a sufficient degree. But in a spark, the particles in the line of discharge being, from the circumstances, nearly alike in their intensity of polarization, suffer discharge so nearly at the same moment as to make the time quite insensible to us.
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