Section Ii.—of the Carbonic, Humic, and Ulmic Acids.

1. CARBONIC ACID.—If a few pieces of chalk or limestone be put into the bottom of a tumbler, and a little spirit of salt (muriatic acid) be poured upon them, a boiling up or effervescence will take place, and a gas will be given off, which will gradually collect and fill the tumbler; and when produced very rapidly, may even be seen to run over its edges. This gas is carbonic acid. It cannot be distinguished from common air by the eye; but if a taper be plunged into it, the flame will immediately be extinguished, while the gas remains unchanged. This kind of air is so heavy, that it may be poured from one vessel into another, and its presence recognised by the taper. It has also a peculiar odour, and is exceedingly suffocating, so that if a living animal be introduced into it, life immediately ceases. It is absorbed by water, a pint of water absorbing or dissolving a pint of the gas.

Carbonic acid exists in the atmosphere; it is given off from the lungs of all living animals while they breathe; it is also produced largely during the burning of wood, coal, and all other combustible bodies, so that an unceasing supply of this gas is poured into the air. Decaying animal and vegetable substances also give off this gas, and hence it is always present in greater or less abundance in the soil, and especially in such soils as are rich in vegetable matter. During the fermentation of malt liquors, or of the expressed juices of different fruits,—the apple, the pear, the grape, the gooseberry—it is produced, and the briskness of such fermented liquors is due to the escape of this gas. From the dung and compost heap it is also given off; and when put into the ground in a fermenting state, farm-yard manure affords a rich supply of carbonic acid to the young plant.

Carbonic acid consists of carbon and oxygen only, combined together in the proportion of 28 of the former to 72 of the latter, or 100 lbs. of carbonic acid contain 28 lbs. of carbon and 72 lbs. of oxygen.

2. HUMIC AND ULMIC ACIDS.—The soil always contains a portion of vegetable matter (called humus by some writers), and such matter is always added to it when it is manured from the farm-yard or the compost heap. During the decay of this vegetable matter, carbonic acid, as above stated, is given off in large quantity, but other substances are also formed at the same time. Among these are the two to which the names of humic and ulmic acids are respectively given. They both contain much carbon, are both capable of entering the roots of plants, and both, no doubt, in favourable circumstances, help to feed the plant.

If the common soda of the shops be dissolved in water, and a portion of a rich vegetable soil, or a bit of peat, be put into this solution, and the whole boiled, a brown liquid is obtained. If to this brown liquid, spirit of salt (muriatic acid) be added till it is sour to the taste, a brown flocky powder falls to the bottom. This brown substance is humic acid. But if in this process we use spirit of hartshorn (liquid ammonia), instead of the soda, ulmic acid is obtained.

These acids exist along with other substances in the rich brown liquor of the farm-yard, which is so often allowed to run to waste; they are also produced in greater or less quantity during the decay of the manure after it is mixed with the soil, and no doubt yield to the plant a portion of that supply of food which it must necessarily receive from the soil.