Conglomerate.—Consolidated gravel. Children should be led to an appreciation of this point by a careful comparison of the forms of the pebbles in the gravel and conglomerate. The conglomerate seems to contain a larger proportion of fine material than ordinary gravel. But this is because the gravel is usually, as with our specimen, taken from the surface of the beach, where, of course, the pebbles are clean and separate; but if it had remained there to be covered by a subsequently deposited layer, enough fine stuff would have been sifted into the holes to fill them. And in the finished gravel, just as in the conglomerate, the pebbles are usually closely packed, with just sufficient sand and clay, or paste, as the material in which the pebbles are imbedded is called, to fill the interstices. The paste is usually similar in composition to the pebbles, with this difference: hard materials predominate in the pebbles and soft in the paste.
Stratified rocks generally show the stratification in parallel lines or bands differing in color, composition, etc.; but nothing like this can be detected in our specimens of conglomerate; and the question might be asked, How do we know that this is a stratified rock? In answer, it can be said that our hand-specimens appear unstratified simply because the rock is so coarse; but when we look at large masses, and especially when we see it in place in the quarry, that parallel arrangement of the material which we call stratification is usually very evident; and we often see precisely the same thing in gravel banks. It is, however, wholly unnecessary that we should see the stratification in order to know certainly that this is a stratified or aqueous rock, because the forms of the pebbles show very plainly that they have been fashioned and deposited by moving water; and we have in the smallest specimen proof positive that our conglomerate is a consolidated sea-beach.
Conglomerate shows the same variations in composition and texture as gravel; it may be composed of almost any kind of material in pebbles of almost any size. We recognize two principal varieties of conglomerate based on the forms of the pebbles; if, as is usual, these are well rounded and water-worn, the rock is true pudding-stone (specimen 29); but, if they are angular, or show but little wear, it is called breccia.
(2) Arenaceous Group.—The conglomerate group passes insensibly into the arenaceous group; for, from the coarsest gravel to the finest sand, the gradation is unbroken, and every sandstone is merely a conglomerate on a small scale.
Sand.—Like gravel, sand may be of almost any composition, but as a rule it is quartzose; quartz, on account of its hardness and the absence of cleavage, being better adapted than any other common mineral to form sand. Where the composition of a sand is not specified, a quartzose sand is always understood. By examining a typical sand with a lens, and noting the glassy appearance of the grains, and then testing their hardness on a piece of glass, which they will scratch as easily as quartz, the pupil is readily convinced that each grain is simply an angular fragment of quartz. Specimen 30.
Sandstone.—Consolidated sand. In proving this, children will notice first the granular or sandy appearance of the sandstone; and then, with the lens, that the grains in the sandstone have the same forms as the sand-grains. The stratification cannot be seen very distinctly in our hand-specimens, but in larger masses it is usually very plain, as may be observed in the blocks used for building, and still better in the quarries. However, even if the stratification were not visible to the eye, we could have no doubt that sandstone is a mechanically formed stratified rock; because the form of the grains, just as in the conglomerate, tells us that. Many sandstones, too, contain the fossil remains of plants and animals, and these are always regarded as affording positive proof that the rocks containing them belong to the aqueous or stratified series.
There are many varieties of sandstone depending upon differences in composition, texture, etc., but we have not space to notice them in detail. In sandstone, just as in sand, quartz is the predominant constituent, although we sometimes find varieties composed largely or entirely of feldspar, mica, calcite, or other minerals. Specimen 31 is an example of the architectural variety known as freestone, which is merely a fine-grained, light-colored, uniform sandstone, not very hard, and breaking with about equal freedom in all directions. The consolidation of sandstones is due chiefly to chemical action. The cementing materials are commonly either: ferruginous (iron oxides), giving red or brown sandstones; calcareous, forming soft sandstones, which effervesce with acid if the cement is abundant; or siliceous, making very strong, light-colored sandstones. Ferruginous sandstones are the most valuable for architectural purposes; for, while not excessively hard, they have a very durable cement. Siliceous sandstones are too hard; and the calcareous varieties crumble when exposed to the weather because the cement is soluble in water containing carbon dioxide, as all rain-water does. Specimen 32 is a good example of a ferruginous sandstone, and it is coarse enough so that we can see that each grain of quartz is coated with the red oxide of iron. The mica scales visible here and there in this specimen are interesting as showing that the grains are not necessarily all quartz; and it is important to observe that the mica was not made in the sandstone, but, like the quartz, has come from some older rock.
Quartzite.—This rock is simply an unusually hard sandstone. Now the hardness of any rock depends upon two things: (1) the hardness of the individual grains or particles; and (2) the firmness with which they are united one to another. Therefore, the hardest sandstones must be those in which grains of quartz are combined with an abundant siliceous cement; and that is precisely what we have in a typical quartzite, such as specimen 33. Quartzite is distinguished, in the hand-specimen, from ordinary quartz by its granular texture (compare specimens 15 and 33); and of course in large masses the stratification is an important distinguishing feature.
3. Argillaceous group.—Just as the conglomerate group shades off gradually into the arenaceous group, so we find it difficult to draw any sharp line of division between the arenaceous group and the argillaceous, but we pass from the largest pebble to the most minute clay-particle by an insensible gradation. For the sake of convenience, however, we draw the line at the limit of visibility, and say that in the true clay and slate the individual particles are invisible to the naked eye; in other words, these rocks have a perfectly compact texture, while the two preceding groups are characterized by a granular texture. Although clay, like sand and gravel, may be of almost any composition, yet it usually consists chiefly, often entirely, of the mineral kaolin. The reason for this is easily found. Quartz resists both mechanical and chemical forces, and is rarely reduced to an impalpable fineness; but all the other common minerals, such as feldspar, hornblende, mica, and calcite, on account of their cleavage and inferior hardness, are easily pulverized; but it is practically impossible that this should happen without their being broken up chemically at the same time. Decomposition follows disintegration; and, while calcite is completely dissolved and carried away, the other minerals are reduced, as we have seen, to impalpable hydrous silicates of aluminum, i.e., to kaolin. Hence, we find that the fragmental rocks are composed principally of two minerals, quartz and kaolin,—the former predominating in the conglomerate and arenaceous groups, and the latter in the argillaceous group.
Clay.—That kaolin is the basis of common clay is proved by the argillaceous odor, which is so characteristic of moist clay. Pure kaolin clay is white and impalpable, like China clay; but pure clays are the exception. They often become coarse and gritty by admixture with sand, forming loam; and they also usually contain more or less carbonaceous matter, which makes black clays; or more or less ferrous oxide, which makes blue clays; or more or less ferric oxide, which makes red, brown, and yellow clays. By mixing these coloring materials in various proportions, almost any tint may be explained. Clays are sometimes calcareous, from the presence of shells and shell-fragments or of pulverized limestone. These usually effervesce with acid, and are commonly known as marl. It is the calcareous material in a pulverulent and easily soluble condition that makes the marls valuable as soils.
Slate.—Consolidated clay. The compact texture and argillaceous odor are usually sufficient to prove this. To get the odor we need simply to breathe upon the specimen, and then smell of it. We find all degrees of induration in clay. It sometimes, as every one knows, becomes very hard by simple drying; but this is not slate, and no amount of mere drying will change clay into slate; for, when moistened with water, the dried clay is easily brought back to the plastic state. To make a good slate, the induration must be the result of pressure, aided probably to some extent by heat. True slate, then, is a permanently indurated clay which will not soak up and become soft when wet.
Slate is usually easily scratched with a knife, and it is distinguished from limestone by its non-effervescence with acid. As we should expect, it shows precisely the same varieties in color and composition as clay. A good assortment of colors is afforded by the roofing-slates. Specimen 34 is a typical slate, for it not only has a compact texture and argillaceous odor, but it is very distinctly stratified. The stratification is marked by alternating bands of slightly different colors, and is much finer and more regular than we usually observe in sandstone, and of course entirely unlike the stratification of conglomerate. These differences are characteristic. Some slates, however, are so homogeneous that the stratification is scarcely visible in small pieces. Thus the roofing-slates (specimen 35) rarely show the stratification; for it is an important fact that the thin layers into which this variety splits are entirely independent of the stratification. This is the structure known as slaty cleavage; it is not due to the stratification, but is developed in the slate subsequently to its deposition, by pressure. Some roofing-slates, known as ribbon-slates, show bands of color across the flat surfaces. These bands are the true bedding, and indicate the absolute want of conformity between this structure and the cleavage. Few rocks are richer in fossils than slate, and these prove that it is a stratified rock. Slate which splits easily into thin layers parallel with the bedding is known as shale.
Porcelainite.—This is clay or slate which has been baked or partially vitrified by heat so as to have the hardness and texture of porcelain.
2. CHEMICALLY AND ORGANICALLY FORMED ROCKS.—We have already learned that from a geological point of view the differences between chemical and organic deposition are not great, the process being essentially chemical in each case; and since the limestones and some other important rocks are deposited in both ways, it is evidently not only unnatural, but frequently impossible, to separate the chemically from the organically formed rocks. Unlike the fragmental rocks, the rocks of this division not only admit, but require, a chemical classification. This is natural because they are of chemical origin; and it is practicable because, with few exceptions, only one class of minerals is deposited at the same time in the same place,—a very convenient and important fact. Therefore our arrangement will be mineralogical, thus:—
(1) Coal Group. (2) Iron-ore Group. (3) Siliceous Group. (4) Calcareous Group. (5) Metamorphic Group (Silicates).
Most of the silicate rocks are mixed, i.e., are each composed of several minerals; but some silicate rocks and all the rocks of the other divisions are simple, each species consisting of a single mineral only.
(1) Coal Group.—These are entirely of organic origin, and include two allied series, which are always merely the more or less extensively transformed tissues of plants or animals; viz.:—
Coals and Bitumens.—At the first lesson we examined a sample of peat (specimen 8), and considered the general conditions of its formation, peat being in every instance simply partially decayed marsh vegetation. It was also stated that, as during the lapse of time the transformation becomes more complete, the peat is changed in succession to lignite, bituminous coal, anthracite, and graphite. The coals, indeed, make a very beautiful and perfect series, whether we consider the composition—there being a gradual, progressive change from the composition of ordinary woody fibre in the newest peat to the pure carbon in graphite,—or the degree of consolidation and mineralization—since there is a gradual passage from the light, porous peat, showing distinctly the vegetable forms, to the heavy crystalline graphite, bearing no trace of its vegetable origin. This relation is easily appreciated by a child, if a proper series of specimens is presented. The coals also make a chronological series, graphite and anthracite occurring only in the older formations, and lignite and peat in the newer, while bituminous coal is found in formations of intermediate age.
Bituminous coal is the typical, the representative coal; and from a good specimen of this variety we may learn two important facts:—
(1) That true coals, no less than peat, are of vegetable origin. To see this we must look at the flat or charcoal surfaces of the coal. These soil the fingers like charcoal, and usually show the vegetable forms distinctly.
(2) That coals are stratified rocks. These dirty charcoal surfaces always coincide with the stratification, being merely the successive layers of vegetation deposited and pressed together to build up the coal; and when we look at the edge of the specimen the stratification shows plainly enough.
The bitumens form a similar though less perfect series, beginning with the organic tissues, and ending, in the opinion of some of the best chemists and mineralogists, with diamond. In fact the coals and bitumens form two distinct but parallel series. The coals are exclusively of vegetable origin, while the bitumens are largely of animal origin. The organic tissues in which the two series originate are chemically similar,—the animal tissues, which produce the lighter forms of bitumen, however, containing more hydrogen and less carbon and oxygen than vegetable tissues; while the final terms, as just shown, are probably chemically identical, being pure carbon,—graphite for the coals and diamond for the bitumens; so that the entire process of change in each series is essentially carbonization, a gradual elimination of the gaseous elements, oxygen and hydrogen, until pure solid carbon alone remains.
The principal differences between the coals and bitumens are the following:—
Coals are rich in carbon, with some oxygen and little hydrogen.
Bitumens are rich in hydrogen, with some carbon and little or no oxygen.
Coals are entirely insoluble.
Bitumens are soluble in ether, benzole, turpentine, etc., and the solid forms are soluble in the more fluid, naphtha-like varieties.
Coals are never liquid, and cannot be melted or, with trifling exceptions, even softened by heat.
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